The NO-NO2 system at laboratory surfaces

Experiments on formation and excitation of NO2 and NO molecules at (and near) laboratory surfaces of varying degrees of characterization are reviewed. On some transition metals NO is desorbed in the B sub 2 pi state, from which it radiates the familiar beta (B yields x) bands. In contrast while an ONO intermediate is inferred from isotope interchange measurements on platinum, neither ground state nor excited NO2 has been found to be desorbed under the relatively limited number of laboratory conditions so far investigated

Surface-catalyzed recombination into excited electronic, vibrational, rotational, and kinetic energy states: A review

Laboratory experiments in which recombined CO, CO2, D2O, OH, N2, H2, and O2 molecules desorb from surfaces in excited internal and translational states are briefly reviewed. Unequilibrated distributions predominate from the principally catalytic metal substrates so far investigated. Mean kinetic energies have been observed up to approx. 3x, and in some cases less than, wall-thermal; the velocity distributions generally vary with emission angle, with non-Lambertian particle fluxes. The excitation state populations are found to depend on surface impurities, in an as yet unexplained way

Infrared emission from desorbed NO2(*) and NO(*)

Infrared photons from the radiative cascade accompany both the gas phase NO2 continuum chemiluminescence (which originates from its 2B2 and 2B1 states) and the NO beta bands. When these upper electronic states are excited by recombination/desorption at surfaces of low Earth orbiting spacecraft, similar IR emission spectrums will be observed. The principal NO2 features (other than the long wavelength tail of its electronic transitions) are the nu sub 3 fundamental sequence near 6.2 microns and nu sub 1 + nu sub 3 intercombination bands near 3.6 microns; NO would emit the delta v=1 and delta v=2 systems above 5.3 and 2.7 microns. Because of the long radiative lifetimes of the upper vibrational states, the infrared radiances in projections parallel to the vehicle surface (which we estimate) are substantially less than those of the visible and ultraviolet glows

Quantum Gravity as a Deformed Topological Quantum Field Theory

It is known that the Einstein-Hilbert action with a positive cosmological constant can be represented as a perturbation of the SO(4,1) BF theory by a symmetry-breaking term quadratic in the B field. Introducing fermionic matter generates additional terms in the action which are polynomial in the tetrads and the spin connection. We describe how to construct the generating functional in the spin foam formalism for a generic BF theory when the sources for the B and the gauge field are present. This functional can be used to obtain a path integral for General Relativity with matter as a perturbative series whose the lowest order term is a path integral for a topological gravity coupled to matter.Comment: 7 pages, talk presented at the QG05 conference, 12-16 September 2005, Cala Gonone, Ital

Electric field formulation for thin film magnetization problems

We derive a variational formulation for thin film magnetization problems in type-II superconductors written in terms of two variables, the electric field and the magnetization function. A numerical method, based on this formulation, makes it possible to accurately compute all variables of interest, including the electric field, for any value of the power in the power law current-voltage relation characterizing the superconducting material. For high power values we obtain a good approximation to the critical state model solution. Numerical simulation results are presented for simply and multiply connected films, and also for an inhomogeneous film.Comment: 15 p., submitte

Stabilization of aerodynamically excited turbomachinery with hydrodynamic journal bearings and supports

A method of analyzing the first mode stability and unbalance response of multimass flexible rotors is presented whereby the multimass system is modeled as an equivalent single mass modal model including the effects of rotor flexibility, general linearized hydrodynamic journal bearings, squeeze film bearing supports and rotor aerodynamic cross coupling. Expressions for optimum bearing and support damping are presented for both stability and unbalance response. The method is intended to be used as a preliminary design tool to quickly ascertain the effects of bearing and support changes on rotor-bearing system performance

Engineering analysis and design of a mechanism to simulate a sonic boom

Mechanism simulating vibrational and acoustic properties of sonic boom

Hidden innovation in the construction and property sectors

The construction and property industries have a poor reputation for innovation. Indeed, this reputation appears to be backed by official statistics which projects these industries as being devoid of innovative activity. However, the reputation is undeserved. Official statistics misrepresent the extent and nature of innovation in these sectors. A closer analysis reveals that much of the innovation that exists in the sector is hidden from conventional measures. By its nature therefore, it is difficult to measure the precise extent of this innovation and disaggregate it from general improvement. This opaqueness strengthens the need for policymakers, practitioners and researchers within, amongst others, the surveying sector to go beyond the visible spectrum of innovation and design and implement appropriate policies, knowledge bases and practices which engage and leverage the hitherto hidden aspects of innovation