The oxidation of Ni-rich Ni-Al intermetallics

The oxidation of Ni-Al intermetallic alloys in the beta-NiAl phase field and in the two phase beta-NiAl/gamma'-Ni3Al phase field has been studied between 1000 and 1400 C. The stoichiometric beta-NiAl alloy doped with Zr was superior to other alloy compositions under cyclic and isothermal oxidation. The isothermal growth rates did not increase monotonically as the alloy Al content was decreased. The characteristically ridged alpha-Al2O3 scale morphology, consisting of cells of thin, textured oxide with thick growth ridges at cell boundaries, forms on oxidized beta-NiAl alloys. The correlation of scale features with isothermal growth rates indicates a predominant grain boundary diffusion growth mechanism. The 1200 C cyclic oxidation resistance decreases near the lower end of the beta-NiAl phase field

The Physical, Social, and Cultural Determinants of Obesity: An Empirical Study of the U.S.

During the past three decades, levels of excess weight and obesity have risen significantly in the United States. The reasons are physical, economical and sociological. The second half of the twentieth century is characterized by changes in the diets and levels of activity in the American society. Recent studies that focus on simple explanations that are based on a few determinants or classes of determinants are inadequate in explaining the recent rise in obesity. Cross-sectional and time series data are analyzed with a variety of statistical techniques. This paper empirically examines the factors correlated with the drastic increase in excess weight in the United States. Demographic characteristics (e.g., race and gender) and income level are significantly related to obesity. Controlling for these factors, energy expenditure in physical exercise are also linked to obesity. This study suggests that policies that merely target on food consumption and physical exercise levels are likely to be inadequate. Successful policies will have to produce specific messages that are relevant for distinct cultural, racial, gender, and income groups. Examples of such group-specific messages are provided.I0, D1, J2, Health Economics and Policy,

From non-Hermitian effective operators to large-scale no-core shell model calculations for light nuclei

No-core shell model (NCSM) calculations using ab initio effective interactions are very successful in reproducing experimental nuclear spectra. The main theoretical approach is the use of effective operators, which include correlations left out by the truncation of the model space to a numerically tractable size. We review recent applications of the effective operator approach, within a NCSM framework, to the renormalization of the nucleon-nucleon interaction, as well as scalar and tensor operators.Comment: To be submited to J. Phys. A, special issue on "The Physics of Non-Hermitian Operators

Vascular Plants of the Truelove Inlet Region, Devon Island

Ninety-three species of vascular plants are recorded from a 16 sq. mile coastal lowland on the northern coast of Devon Island, Northwest Territories. The following taxa are apparently new records for Devon Island: Cystopteris fragilis, Woodsia alpina, Equisetum variegatum, Poa alpigena, Carex amblyorhyncha, Draba oblongata, Saxifraga tenuis, Epilobium arcticum, Hippuris vulgaris, Pedicularis lanata, Puccinellia vaginata var. paradoxa. These additions bring the total known flora of Devon Island to 115 species. The Truelove flora is part of the High Arctic biogeographic element of the Canadian Arctic Archipelago. However, a distinct element of species of more southerly distribution is present probably due to the moderating influence of the lowland environment

Factors contributing to fecal incontinence in older people and outcome of routine management in home, hospital and nursing home settings

Objective: Fecal loading, cognitive impairment, loose stools, functional disability, comorbidity and anorectal incontinence are recognized as factors contributing to loss of fecal continence in older adults. The objective of this project was to assess the relative distribution of these factors in a variety of settings along with the outcome of usual management. Methods: One hundred and twenty adults aged 65 years and over with fecal incontinence recruited by convenience sampling from four different settings were studied. They were either living at home or in a nursing home or receiving care on an acute or rehabilitation elderly care ward. A structured questionnaire was used to elicit which factors associated with fecal incontinence were present from subjects who had given written informed consent or for whom assent for inclusion in the study had been obtained. Results: Fecal loading (Homes 6 [20%]; Acute care wards 17 [57%]; Rehabilitation wards 19 [63%]; Nursing homes 21 [70%]) and functional disability (Homes 5 [17%]; Acute care wards 25 [83%]; Rehabilitation wards 25 [83%]; Nursing homes 20 [67%]) were significantly more prevalent in the hospital and nursing home settings than in those living at home (P < 0.01). Loose stools were more prevalent in the hospital setting than in the other settings (Homes 11 [37%]; Acute care wards 20 [67%]; Rehabilitation wards 17 [57%]; Nursing homes 6 [20%]) (P < 0.01). Cognitive impairment was significantly more common in the nursing home than in the other settings (Nursing homes 26 [87%], Homes 5 [17%], Acute care wards 13 [43%], Rehabilitation wards 14 [47%]) (P < 0.01). Loose stools were the most prevalent factor present at baseline in 13 of the 19 (68%) subjects whose fecal incontinence had resolved at 3 months. Conclusion: The distribution of the factors contributing to fecal incontinence in older people living at home differs from those cared for in nursing home and hospital wards settings. These differences need to be borne in mind when assessing people in different settings. Management appears to result in a cure for those who are not significantly disabled with loose stools as a cause for their fecal incontinence, but this would need to be confirmed by further research

Oxidation Behavior of Binary Niobium Alloys

This investigation concludes a study to determine the effects of up to 25 atomic percent of 55 alloying additions on the oxidation characteristics of niobium. The alloys were evaluated by oxidizing in an air atmosphere for 4 hours at 1000 C and 2 hours at 1200 C. Titanium and chromium improved oxidation resistance at both evaluation conditions. Vanadium and aluminum improved oxidation resistance at 1000 C, even though the V scale tended to liquefy and the Al specimens became brittle and the scale powdery. Copper, cobalt, iron, and iridium improved oxidation resistance at 1200 C. Other investigations report tungsten and molybdenum are protective up to about 1000 C, and tantalum at 1100 C. The most important factor influencing the rate of oxidation was the ion size of the alloy additions. Ions slightly smaller than the Nb(5+) ion are soluble in the oxide lattice and tend to lower the compressive stresses in the bulk scale that lead to cracking. The solubility of the alloying addition also depends on the valence to some extent. All of the elements mentioned that improve the oxidation resistance of Nb fit this size criterion with the possible exception of Al, whose extremely small size in large concentrations would probably lead to the formation of a powdery scale. Maintenance of a crack-free bulk scale for as long as possible may contribute to the formation of a dark subscale that ultimately is rate- controlling in the oxidation process. The platinum-group metals, especially Ir, appear to protect by entrapment of the finely dispersed alloying element by the incoming Nb2O5 metal-oxide interface. This inert metallic Ir when alloyed in a sufficient amount with Yb appears to give a ductile phase dispersed in the brittle oxide. This scale would then flow more easily to relieve the large compressive stresses to delay cracking. Complex oxide formation (which both Ti and Zr tend to initiate) and valence effects, which probably change the vacancy concentration in the scale, are masked by the overriding tendency for a porous scale

Zincate-free, electroless nickel deposition on aluminum bond pads

A zincate-free electroless nickel deposition on aluminum bond pads is investigated. A three-step, etch, rinse, and electroless plating, is demonstrated for deposition on aluminum bond pads patterned with polyimide. The chemicals used are compatible with this dielectric material. The deposition has been achieved with good selectivity, uniformity, and deposition rate at 40 × 40   μ m aluminum bond pads. The adhesion and contact resistance were also determined and improved through anneals in the range 200-400°C for 1 h. The optimized condition for adhesion and contact resistance was an anneal at 400°C. The combination of a nickel hypophosphite reducing agent and the additives used leads to an active plating bath in the early stages of deposition, by comparison with commercial solutions, and hence, good coverage of the aluminum bond pad using the simplified process

Fully reconfigurable coherent optical vector-matrix multiplication

Optics is a promising platform in which to help realise the next generation of fast, parallel and energy-efficient computation. We demonstrate a reconfigurable free-space optical multiplier that is capable of over 3000 computations in parallel, using spatial light modulators with a pixel resolution of only 340x340. This enables vector-matrix multiplication and parallel vector-vector multiplication with vector size of up to 56. Our design is the first to simultaneously support optical implementation of reconfigurable, large-size and real-valued linear algebraic operations. Such an optical multiplier can serve as a building block of special-purpose optical processors such as optical neural networks and optical Ising machines.Comment: 4 pages, 4 figure

A colorimetric CMOS-based platform for rapid total serum cholesterol quantification

Elevated cholesterol levels are associated with a greater risk of developing cardiovascular disease and other illnesses, making it a prime candidate for detection on a disposable biosensor for rapid point of care diagnostics. One of the methods to quantify cholesterol levels in human blood serum uses an optically mediated enzyme assay and a bench top spectrophotometer. The bulkiness and power hungry nature of the equipment limits its usage to laboratories. Here, we present a new disposable sensing platform that is based on a complementary metal oxide semiconductor process for total cholesterol quantification in pure blood serum. The platform that we implemented comprises readily mass-manufacturable components that exploit colorimetric changes of cholesterol oxidase and cholesterol esterase reactions. We have shown that our quantification results are comparable to that obtained by a bench top spectrophotometer. Using the implemented device, we have measured cholesterol concentration in human blood serum as low as 29 μM with a limit of detection at 13 μM, which is approximately 400 times lower than average physiological range, implying that our device also has the potential to be used for applications that require greater sensitivity

An Analysis of the Long-Term Salinity Patterns in the Louisiana Coastal Zone

Saltwater intrusion is believed to be one of the greatest threats to Louisiana\u27s fishery and wildlife resources. The Louisiana Department of Wildlife and Fisheries has maintained salinity recording stations throughout the state\u27s coastal marshes since the 1960\u27s. We applied several different analytical approaches to the salinity data from 17 stations to determine whether this data base could be used to detect and quantity long-term salinity trends in coastal Louisiana. We did not detect a large-scale, consistent trend over time in coastal salinities across the state. Problems that hindered the detection of long-term trends included short periods of record and the placement of the recording stations in salt and brackish marsh areas, where we would not expect to find great changes in salinity. For the data to be useful in monitoring salinity trends in coastal marshes, especially with respect to saltwater intrusion, stations should be added in fresh and intermediate marshes. In addition, the relationships our study revealed between short- and long-term data indicate that records covering less than a decade are insufficient to denote long-term salinity changes, barring some major modification of the hydrologic regime