Asymptotics of Relativistic Spin Networks

The stationary phase technique is used to calculate asymptotic formulae for SO(4) Relativistic Spin Networks. For the tetrahedral spin network this gives the square of the Ponzano-Regge asymptotic formula for the SU(2) 6j symbol. For the 4-simplex (10j-symbol) the asymptotic formula is compared with numerical calculations of the Spin Network evaluation. Finally we discuss the asymptotics of the SO(3,1) 10j-symbol.Comment: 31 pages, latex. v3: minor clarification

Holonomy observables in Ponzano-Regge type state sum models

We study observables on group elements in the Ponzano-Regge model. We show that these observables have a natural interpretation in terms of Feynman diagrams on a sphere and contrast them to the well studied observables on the spin labels. We elucidate this interpretation by showing how they arise from the no-gravity limit of the Turaev-Viro model and Chern-Simons theory.Comment: 15 pages, 2 figure

The application of Rapid Appraisal of Agricultural Innovation Systems (RAAIS) to agricultural adaptation to climate change in Kazakhstan: a critical evaluation

Place-based social, cultural, institutional and political dynamics not only influence the innovation capacity of agricultural systems, but also the willingness of relevant actors to be involved in participatory research processes, and the dynamics of their participation. This paper critically discusses the modification and application of one particular participatory approach to agricultural systems analysis (Rapid Appraisal of Agricultural Innovation Systems [RAAIS]) to agricultural adaptation in Southeast Kazakhstan. We consider the overall effectiveness of the method as a research tool, practical issues in the implementation of workshops, definition of and selection of participant groups, as well as the questions of participation and empowerment within the workshops themselves. We find that although RAAIS is adaptable to alternative theoretical frameworks, its implementation in different socio-cultural and political contexts may require more consideration than is apparent in previous discussions. In particular, the appropriate training of workshop organisers is of crucial importance to the success of this methodology. These findings will be useful to those adapting participatory research methods to different research topics and contexts more broadly

Supramolecular hierarchy among halogen and hydrogen bond donors in light-induced surface patterning

Halogen bonding, a noncovalent interaction possessing several unique features compared to the more familiar hydrogen bonding, is emerging as a powerful tool in functional materials design. Herein, we unambiguously show that one of these characteristic features, namely high directionality, renders halogen bonding the interaction of choice when developing azobenzene-containing supramolecular polymers for light-induced surface patterning. The study is conducted by using an extensive library of azobenzene molecules that differ only in terms of the bond-donor unit. We introduce a new tetrafluorophenol-containing azobenzene photoswitch capable of forming strong hydrogen bonds, and show that an iodoethynyl-containing azobenzene comes out on top of the supramolecular hierarchy to provide unprecedented photoinduced surface patterning efficiency. Specifically, the iodoethynyl motif seems highly promising in future development of polymeric optical and photoactive materials driven by halogen bonding

Time-resolved PhotoEmission Spectroscopy on a Metal/Ferroelectric Heterostructure

In thin film ferroelectric capacitor the chemical and electronic structure of the electrode/FE interface can play a crucial role in determining the kinetics of polarization switching. We investigate the electronic structure of a Pt/BaTiO3/SrTiO3:Nb capacitor using time-resolved photoemission spectroscopy. The chemical, electronic and depth sensitivity of core level photoemission is used to probe the transient response of different parts of the upper electrode/ferroelectric interface to voltage pulse induced polarization reversal. The linear response of the electronic structure agrees quantitatively with a simple RC circuit model. The non-linear response due to the polarization switch is demonstrated by the time-resolved response of the characteristic core levels of the electrode and the ferroelectric. Adjustment of the RC circuit model allows a first estimation of the Pt/BTO interface capacitance. The experiment shows the interface capacitance is at least 100 times higher than the bulk capacitance of the BTO film, in qualitative agreement with theoretical predictions from the literature.Comment: 7 pages, 10 figures. Submitted to Phys. Rev.

Critical dynamics of diluted relaxational models coupled to a conserved density (diluted model C)

We consider the influence of quenched disorder on the relaxational critical dynamics of a system characterized by a non-conserved order parameter coupled to the diffusive dynamics of a conserved scalar density (model C). Disorder leads to model A critical dynamics in the asymptotics, however it is the effective critical behavior which is often observed in experiments and in computer simulations and this is described by the full set of dynamical equations of diluted model C. Indeed different scenarios of effective critical behavior are predicted.Comment: 4 pages, 5 figure

Interface Electronic Structure in a Metal/Ferroelectric Heterostructure under Applied Bias

The effective barrier height between an electrode and a ferroelectric (FE) depends on both macroscopic electrical properties and microscopic chemical and electronic structure. The behavior of a prototypical electrode/FE/electrode structure, Pt/BaTiO3/Nb-doped SrTiO3, under in-situ bias voltage is investigated using X-Ray Photoelectron Spectroscopy. The full band alignment is measured and is supported by transport measurements. Barrier heights depend on interface chemistry and on the FE polarization. A differential response of the core levels to applied bias as a function of the polarization state is observed, consistent with Callen charge variations near the interface.Comment: 9 pages, 8 figures. Submitted to Phys. Rev.

On the Expansions in Spin Foam Cosmology

We discuss the expansions used in spin foam cosmology. We point out that already at the one vertex level arbitrarily complicated amplitudes contribute, and discuss the geometric asymptotics of the five simplest ones. We discuss what type of consistency conditions would be required to control the expansion. We show that the factorisation of the amplitude originally considered is best interpreted in topological terms. We then consider the next higher term in the graph expansion. We demonstrate the tension between the truncation to small graphs and going to the homogeneous sector, and conclude that it is necessary to truncate the dynamics as well.Comment: 17 pages, 4 figures, published versio

Conditional probabilities in Ponzano-Regge minisuperspace

We examine the Hartle-Hawking no-boundary initial state for the Ponzano-Regge formulation of gravity in three dimensions. We consider the behavior of conditional probabilities and expectation values for geometrical quantities in this initial state for a simple minisuperspace model consisting of a two-parameter set of anisotropic geometries on a 2-sphere boundary. We find dependence on the cutoff used in the construction of Ponzano-Regge amplitudes for expectation values of edge lengths. However, these expectation values are cutoff independent when computed in certain, but not all, conditional probability distributions. Conditions that yield cutoff independent expectation values are those that constrain the boundary geometry to a finite range of edge lengths. We argue that such conditions have a correspondence to fixing a range of local time, as classically associated with the area of a surface for spatially closed cosmologies. Thus these results may hint at how classical spacetime emerges from quantum amplitudes.Comment: 26 pages including 10 figures, some reorganization in the presentation of results, expanded discussion of results in the context of 2+1 gravity in the Witten variables, 3 new reference

Atomic Properties of Lu+^+

Singly ionised Lutetium has recently been suggested as a potential clock candidate. Here we report a joint experimental and theoretical investigation of \ce{Lu^+}. Measurements relevant to practical clock operation are made and compared to atomic structure calculations. Calculations of scalar and tensor polarizabilities for clock states over a range of wavelengths are also given. These results will be useful for future work with this clock candidate.Comment: 12 pages, 5 figure