348 research outputs found
Random laser from engineered nanostructures obtained by surface tension driven lithography
The random laser emission from the functionalized thienyl-S,S-dioxide
quinquethiophene (T5OCx) in confined patterns with different shapes is
demonstrated. Functional patterning of the light emitter organic material in
well defined features is obtained by spontaneous molecular self-assembly guided
by surface tension driven (STD) lithography. Such controlled supramolecular
nano-aggregates act as scattering centers allowing the fabrication of
one-component organic lasers with no external resonator and with desired shape
and efficiency. Atomic force microscopy shows that different geometric pattern
with different supramolecular organization obtained by the lithographic process
tailors the coherent emission properties by controlling the distribution and
the size of the random scatterers
Experimental evidence of replica symmetry breaking in random lasers
Spin-glass theory is one of the leading paradigms of complex physics and
describes condensed matter, neural networks and biological systems, ultracold
atoms, random photonics, and many other research fields. According to this
theory, identical systems under identical conditions may reach different states
and provide different values for observable quantities. This effect is known as
Replica Symmetry Breaking and is revealed by the shape of the probability
distribution function of an order parameter named the Parisi overlap. However,
a direct experimental evidence in any field of research is still missing. Here
we investigate pulse-to-pulse fluctuations in random lasers, we introduce and
measure the analogue of the Parisi overlap in independent experimental
realizations of the same disordered sample, and we find that the distribution
function yields evidence of a transition to a glassy light phase compatible
with a replica symmetry breaking.Comment: 10 pages, 5 figure
Bicolor Electroluminescent Pixels from Single Active Molecular Material
We report on the fabrication of the first bicolor micropixelated OLED from a single molecular material using a single-step bottom up procedure, The implementation of a deposition technique, based on a spatial-switch and con formational-sensitive STD surface-tension-driven lithography, has allowed us to exploit the spontaneous supramolecular properties and the conformational flexibility of a conjugated thiophene-based material, 6-bis-(50-hexyl-[2, 20]bithiophen-5-yl)-3, 5-dimethyl-dithieno[3, 2-b: 20, 30-d]-thiophene (DTT7Me). The existence of two regularly alternating emitting regions on a micrometer scale allows obtaining electroluminescent emission at two different wavelengths from a single material
Amplified spontaneous emission and efficient tunable laser emission from a substituted thiophene-based oligomer
We investigated gain and lasing in spin-coated films of a soluble substituted oligothiophene. With increasing excitation power, the photoluminescence spectra show a clear line narrowing due to amplified spontaneous emission. We measure a low threshold (20 μJ cm−2) for line narrowing and a large gain cross section (6×10−16 cm2), indicating that this molecule is a promising active material for organic solid-state lasers. As a demonstrator, we realize a transverse electromagnetic (TEM00) single-mode laser with tunable emission from the yellow to the red (a range of 37 nm), with a pump threshold as low as 18 μJ cm−2 and efficiency of 1.9%. These results are among the best so far reported for organic lasers
Efficient second harmonic generation from thin films of V-shaped benzo[b]thiophene based molecules
We have designed an original approach for efficient Second Harmonic Generation of tailored V-shape benzo[b]thiophene molecular systems enabling versatile and flexible one-step, dry and technologically friendly thin film processing. The designed moieties show χ(2) values at least as high as the reference LiNbO3 single crystal, without poling processing and matching the constrains of integrated optical configuration for nonlinear optical devices. This may open the way to a new class of organic materials exploitable for photonic applications
Photoluminescence efficiency of Substituted Quaterthiophene Crystals
none8The photoluminescence (PL) efficiency of substituted α-conjugated quaterthiophene crystals shows marked differences depending on crystal packing and molecular geometry. This effect is studied by evaluating the role of the intermolecular interactions and the effects of the single molecule conformation on the intersystem crossing (ISC) rate. The comparison of these calculations with absolute quantum efficiency measurements and with the experimental temperature dependence of the PL decay time, indicates that the differences in PL efficiency are not inherent to crystal packing effects but they are determined by the ISC rate.G.GIGLI; F.DELLA SALA; M.LOMASCOLO; M.ANNI; G.BARBARELLA; A.DI CARLO; P.LUGLI; R. CINGOLANIGigli, Giuseppe; F., DELLA SALA; M., Lomascolo; Anni, Marco; G., Barbarella; A., DI CARLO; P., Lugli; Cingolani, Robert
New light-emitting functionalized oligothiophenes
We present a new class of highly photo and electroluminescent oligomers based on the presence of one inner thienyl-S,S-dioxide unit as the luminophore. The light emission frequency of the new compounds, which are characterized by greater electron affinities than the corresponding oligomers bearing an unmodified thienyl ring, was tuned over the entire visible range by changing the nature of the alkyl or aryl groups attached in the α- and/or in the β-positions of the thienyl-S,S-dioxide moiety. A few aspects of the solid state supramolecular organization of the new compounds are reported
Bicolor Pixels from a Single Active Molecular Material by Surface-Tension-Driven Depositionâ€
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Solid-state supramolecular organization, established directly from powder diffraction data, and photoluminescence efficiency of rigid-core oligothiophene-S,S-dioxides.
The "rigid-core" material 3,5-dimethyl-2,3'-bis(3-methylthiophene)-dithieno[3,2-b:',3'−d]thiophene-4,4-dioxide (DTTOMe4) has the highest photoluminescence ever reported for thiophene-based molecule..
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