Novel Sb−SnO2 Electrode with Ti3+ Self-Doped Urchin-Like Rutile TiO2 Nanoclusters as the Interlayer for the Effective Degradation of Dye Pollutants

Stable and efficient SnO2 electrodes are very promising for effectively degrading refractory organic pollutants in wastewater treatment. In this regard, we firstly prepared Ti3+ self-doped urchin-like rutile TiO2 nanoclusters (TiO2-xNCs) on a Ti mesh substrate by hydrothermal and electroreduction to serve as an interlayer for the deposition of Sb−SnO2. The TiO2-xNCs/Sb−SnO2 anode exhibited a high oxygen evolution potential (2.63 V vs. SCE) and strong ⋅OH generation ability for the enhanced amount of absorbed oxygen species. Thus, the degradation results demonstrated its good rhodamine B (RhB), methylene blue (MB), alizarin yellow R (AYR), and methyl orange (MO) removal performance, with the rate constant increased 5.0, 1.9, 1.9, and 4.7 times, respectively, compared to the control Sb−SnO2 electrode. RhB and AYR degradation mechanisms are also proposed based on the results of high-performance liquid chromatography coupled with mass spectrometry and quenching experiments. More importantly, this unique rutile interlayer prolonged the anode lifetime sixfold, given its good lattice match with SnO2 and the three-dimensional concave–convex structure. Consequently, this work paves a new way for designing the crystal form and structure of the interlayers to obtain efficient and stable SnO2 electrodes for addressing dye wastewater problems

Mechanisms of Creativity Differences Between Art and Non-art Majors: A Voxel-Based Morphometry Study

Creativity is considered the ability to generate new ideas or behaviors, an ability that have diverse expressions in different human groups, such as painters and non-painters. Art major students require more creative activities than non-art students do. In this study, we plan to explore the figural creativity abilities of art major students and whether these students exhibited higher figural creativity scores and why their brain structure of gray matter are lower which may benefit from their professional training relative to non-art majors. Therefore, in this study, we use voxel-based morphometry (VBM) to identify different behavioral and brain mechanisms between art major students and non-art major students by using the figural Torrance Test of Creative Thinking. Our results showed that the TTCT-figural (TTCT-F) scores of art majors were higher than those of non-art majors. The TTCT-F score of art major students and practicing and study time have positive correlations which means art major’s figural creativity score benefit from there art professional training in some degree. Subsequently, the interaction analysis revealed that the TTCT-figural scores of art majors and non-majors exhibited significant correlations with the gray matter volumes (GMV) of the left anterior cingulate cortex (ACC) and the left medial frontal gyrus (MFG). While the simple slope analysis showed that art majors, compared with non-art majors, exhibited a marginal significantly positive association with the left ACC and MFG, non-art majors exhibited a significantly negative association with the left ACC and MFG. Overall, our study revealed that people who major in artistic work are more likely to possess enhanced figural creative skills relative to non-artistic people. These results indicated that professional artistic programs or training may increase creativity skills via reorganized intercortical connections

Library open 24/7: A study of user needs and library management concerns

Facing competition from Web-based information service development, academic librarians need to find ways to attract more users to the physical library buildings. This study investigated user needs and library management concerns for a 24/7 service through two surveys: 1) User feedback survey at Seton Hall University Library, and 2) Survey of Academic Library Deans and Directors in the USA. Based on these two surveys, the paper not only discussed the current status of libraries open 24/7 in the USA and showed the demographics of users of the 24/7 service at Seton Hall University, it also stated reasons to use the 24/7 service. In addition, the paper revealed library management concerns of the 24/7 service. Three implications, which have been guided by Scott Bennett's theory of learning commons for planning library space, were drawn from the findings in this paper.</p

Initial Evaluation of Provincial-Level Environmental Risks from the Perspective of Human Settlements

This study introduces risk theory of environmental science into human settlement science using 2004–2013 statistics, remote sensing data, and thematic maps. The entropy weight method and risk-index model are both used to study the characteristics of the time course and spatial pattern of human settlement risk in 31 provincial regions in China. In addition, influential mechanisms of vulnerability, functionality, stress, and adaptability on environmental risks are analyzed. Three primary results are obtained. First, for temporal characteristics, environmental risks of human settlements increased significantly from 2003 to 2012. The year 2006 marked both a sudden change and the cut-off point after which human settlements in China experienced qualitative changes and new risks. Second, for spatial characteristics, the risk index of human settlements decreased gradually from the southwestern to the northeastern, northwestern, and northern parts of China. The risk index of human settlement spaces differed significantly, with obvious block aggregation of spatial-distribution characteristics. Third, for relevant factor characteristics, between 2003 and 2012, the temporal change in vulnerability is relatively stable, with a slight increase in functionality and a slight decrease in adaptability. Spatially, Qinghai, Tibet, southwestern China, Guangdong, Guangxi, Beijing, and Tianjin had relatively high vulnerability in human settlements; Beijing, Tianjin, Jiangsu, and Zhejiang had the best functionality; Hunan and Sichuan had relatively high stress; and Guangdong, Jiangsu, and Zhejiang had relatively stronger adaptability. Further consideration and discussion are required on the environmental risks for different social groups and at different geographical scales, as well as on the uncertainty and long-term features of environmental risks in addition to environmental justice issues

Assessing the Distribution of Urban Green Spaces and its Anisotropic Cooling Distance on Urban Heat Island Pattern in Baotou, China

An essential part of urban natural systems, urban green spaces play a crucial role in mitigating the urban heat island effect (UHI). The UHI effect refers to the phenomenon where the temperature within a city is higher than that of the surrounding rural areas. The effects of the spatial composition and configuration of urban green spaces on urban land surface temperature (LST) have recently been documented. However, few studies have examined the effects of the directionality and distribution of green spaces on LST. In this study, we used a landscape index to describe the change in pattern of heat island intensity for the city of Baotou, China. We then used a semi-variable function and nearest neighbor algorithm to analyze the cooling effects of green spaces. We found that: (1) the cooling distance of an urban green space was not only influenced by its size, vegetation cover, and shape, but also showed anisotropy. In general, the larger the area of the urban green space and the higher the value of Normalized Difference Vegetation Index (NDVI; a measure of plant photosynthetic activity), the larger the cooling distance within a certain threshold. Green spaces with more regular shapes displayed higher LST mitigation; however, the cooling distance was directional, and cooling effects depended on the semi-major axis and semi-minor axis of the green space. (2) The distribution of the urban green space within the landscape played a key role in mitigating the UHI effect. Within a certain area, the cooling effect of green spaces that are evenly distributed was greater than that which was associated with either green spaces that were large in area or where greens spaces were aggregated in the landscape. Therefore, within urban areas, where space is limited, urban planning should account for green spaces that are relatively scattered and evenly distributed to maximize cooling effects. The results of this study have key implications for sustainable urban planning and development; to mitigate urban heat island effects it is important to not only increase canopy cover or the size of urban green spaces, but also to optimize their spatial configuration

Density and diversity of OpenStreetMap road networks in China

OpenStreetMap is a geographic information platform designed to provide real-time updates and user-generated content related to its freely available global map, and it is one of the most widely used examples of volunteered geographic information, a technique associated with so-called neogeography. This paper, based on the data from China’s OpenStreetMap road network in May 2014, taking 340 prefecture-level cities in China as its study area, presents the geometric-related (road density) and attribute-related (type diversity) spatial patterns of the OpenStreetMap road network, and explores their relationship. The results are as follows. (1) The distribution of OpenStreetMap road density in Shenzhen, Shanghai, Hong Kong, and Macao predominantly obeys a “positive skewness distribution”. OpenStreetMap data for eastern China shows a higher overall and circular structure. In central China, there are noticeable discrepancies in the road density, whereas in western China, the road density is low. (2) The OpenStreetMap road diversity shows a normal distribution. The spatial pattern for the so-called “Hu Huanyong line” was broken by the effect of diplomatic and strategic factors, showing a high diversity along the peripheral border, coastal cities, and core inland cites. (3) China’s OpenStreetMap is partitioned into four parts according to road density and diversity: high density and high diversity; low density and low diversity; high density and low diversity; and low density high diversity. (4) The OpenStreetMap geographical information-collection process and mechanism were analyzed, demonstrating that the road density reflects the preponderance of traffic in the real world. OpenStreetMap road diversity reflects the road-related geographic information demand and value, and it also reflects the interests of users toward to OpenStreetMap geographical information

Characterization of different substituted carboxymethyl starch microgels and their interactions with lysozyme.

A carboxymethyl starch (CMS) microgel system was prepared for the control of uptaking and releasing proteins (lysozyme). The physicochemical properties of microgels in various degrees of substitution (DS) were determined by thermal gravimetric analysis (TGA), swelling degree, and rheological analysis. The microgel particle size mostly ranged from 25 µm to 45 µm. The result obtained from the TGA studies indicated that carboxymethylation decreased the thermal stability of starch, but crosslinking increased the thermal stability of CMS. The CMS microgels showed typical pH sensitivity, and the swelling degree of microgel increased with the increasing of DS and pH, because of the large amounts of carboxyl group ionization. The samples (2.25%) could behave as viscoelastic solids since the storage modulus was larger than the loss modulus over the entire frequency range. The protein uptake increased with increasing pH and DS at low salt concentration. The optimal pH shifted to lower pH with increasing ionic strength. The saturated protein uptake decreased with increasing ionic strength at each pH. The protein was easily released from the microgel with high pH and high salt concentration