Magnetic excitations in vanadium spinels

We study magnetic excitations in vanadium spinel oxides AV$_2$O$_4$ (A=Zn, Mg, Cd) using two models: first one is a superexchange model for vanadium S=1 spins, second one includes in addition spin-orbit coupling, and crystal anisotropy. We show that the experimentally observed magnetic ordering can be obtained in both models, however the orbital ordering is different with and without spin-orbit coupling and crystal anisotropy. We demonstrate that this difference strongly affects the spin-wave excitation spectrum above the magnetically ordered state, and argue that the neutron measurement of such dispersion is a way to distinguish between the two possible orbital orderings in AV$_2$O$_4$.Comment: accepted in Phys. Rev.

Non-resonant inelastic x-ray scattering involving excitonic excitations

In a recent publication Larson \textit{et al.} reported remarkably clear $d$-$d$ excitations for NiO and CoO measured with x-ray energies well below the transition metal $K$ edge. In this letter we demonstrate that we can obtain an accurate quantitative description based on a local many body approach. We find that the magnitude of $\vec{q}$ can be tuned for maximum sensitivity for dipole, quadrupole, etc. excitations. We also find that the direction of $\vec{q}$ with respect to the crystal axes can be used as an equivalent to polarization similar to electron energy loss spectroscopy, allowing for a determination of the local symmetry of the initial and final state based on selection rules. This method is more generally applicable and combined with the high resolution available, could be a powerful tool for the study of local distortions and symmetries in transition metal compounds including also buried interfaces

Local electronic structure of Fe2+^{2+} impurities in MgO thin films: Temperature-dependent soft x-ray absorption spectroscopy study

We report on the local electronic structure of Fe impurities in MgO thin films. Using soft x-ray absorption spectroscopy (XAS) we verified that the Fe impurities are all in the 2+ valence state. The fine details in the line shape of the Fe $L_{2,3}$ edges provide direct evidence for the presence of a dynamical Jahn-Teller distortion. We are able to determine the magnitude of the effective $D_{4h}$ crystal field energies. We also observed a strong temperature dependence in the spectra which we can attribute to the thermal population of low-lying excited states that are present due to the spin-orbit coupling in the Fe 3d. Using this Fe$^{2+}$ impurity system as an example, we show that an accurate measurement of the orbital moment in Fe$_3$O$_4$ will provide a direct estimate for the effective local low-symmetry crystal fields on the Fe$^{2+}$ sites, important for the theoretical modeling of the formation of orbital ordering

Local electronic structure and magnetic properties of LaMn0.5Co0.5O3 studied by x-ray absorption and magnetic circular dichroism spectroscopy

We have studied the local electronic structure of LaMn0.5Co0.5O3 using soft-x-ray absorption spectroscopy at the Co-L_3,2 and Mn-L_3,2 edges. We found a high-spin Co^{2+}--Mn^{4+} valence state for samples with the optimal Curie temperature. We discovered that samples with lower Curie temperatures contain low-spin nonmagnetic Co^{3+} ions. Using soft-x-ray magnetic circular dichroism we established that the Co^{2+} and Mn^{4+} ions are ferromagnetically aligned. We revealed also that the Co^{2+} ions have a large orbital moment: m_orb/m_spin ~ 0.47. Together with model calculations, this suggests the presence of a large magnetocrystalline anisotropy in the material and predicts a non-trivial temperature dependence for the magnetic susceptibility.Comment: 8 pages, 7 figure

Congenital disorder of glycosylation type Id (CDG Id): phenotypic, biochemical and molecular characterization of a new patient

Summary: Congenital disorders of glycosylation (CDG) are a family of multisystem inherited disorders caused by defects in the biosynthesis of N- or O-glycans. Among the many different subtypes of CDG, the defect of a mannosyltransferase encoded by the human ALG3 gene (chromosome 3q27) is known to cause CDG Id. Six patients with CDG Id have been described in the literature so far. We further delineate the clinical, biochemical, neuroradiological and molecular features of CDG Id by reporting an additional patient bearing a novel missense mutation in the ALG3 gene. All patients with CDG Id display a slowly progressive encephalopathy with microcephaly, severe psychomotor retardation and epileptic seizures. They also share some typical dysmorphic features but they do not present the multisystem involvement observed in other CDG syndromes or any biological marker abnormalities. Unusually marked osteopenia is a feature in some patients and may remain undiagnosed until revealed by pathological fractures. Serum transferrin screening for CDG should be extended to all patients with encephalopathy of unknown origin, even in the absence of multisystem involvemen

Wilson-Polchinski exact renormalization group equation for O(N) systems: Leading and next-to-leading orders in the derivative expansion

With a view to study the convergence properties of the derivative expansion of the exact renormalization group (RG) equation, I explicitly study the leading and next-to-leading orders of this expansion applied to the Wilson-Polchinski equation in the case of the $N$-vector model with the symmetry $\mathrm{O}(N)$. As a test, the critical exponents $$ and $\nu$ as well as the subcritical exponent $\omega$ (and higher ones) are estimated in three dimensions for values of $N$ ranging from 1 to 20. I compare the results with the corresponding estimates obtained in preceding studies or treatments of other $\mathrm{O}(N)$ exact RG equations at second order. The possibility of varying $N$ allows to size up the derivative expansion method. The values obtained from the resummation of high orders of perturbative field theory are used as standards to illustrate the eventual convergence in each case. A peculiar attention is drawn on the preservation (or not) of the reparametrisation invariance.Comment: Dedicated to Lothar Sch\"afer on the occasion of his 60th birthday. Final versio

Immune phenotypes and checkpoint molecule expression of clonally expanded lymph node-infiltrating T cells in classical Hodgkin lymphoma

Lymph node-infiltrating T cells have been of particular interest in classical Hodgkin lymphoma (cHL). High rates of complete therapeutic responses to antibody-mediated immune checkpoint blockade, even in relapsed/refractory patients, suggest the existence of a T cell-dominated, antigen-experienced, functionally inhibited and lymphoma-directed immune microenvironment. We asked whether clonally expanded T cells (1) were detectable in cHL lymph nodes, (2) showed characteristic immune phenotypes, and (3) were inhibited by immune checkpoint molecule expression. We applied high-dimensional FACS index sorting and single cell T cell receptor αβ sequencing to lymph node-infiltrating T cells from 10 treatment-naïve patients. T cells were predominantly CD4(+) and showed memory differentiation. Expression of classical immune checkpoint molecules (CTLA-4, PD-1, TIM-3) was generally low (< 12.0% of T cells) and not different between CD4(+) and CD8(+) T cells. Degrees of clonal T cell expansion varied between patients (range: 1-18 expanded clones per patient) and was almost exclusively restricted to CD8(+) T cells. Clonally expanded T cells showed non-naïve phenotypes and low checkpoint molecule expression similar to non-expanded T cells. Our data suggest that the therapeutic effects of immune checkpoint blockade require mechanisms in addition to dis-inhibition of pre-existing lymphoma-directed T cell responses. Future studies on immune checkpoint blockade-associated effects will identify molecular T cell targets, address dynamic aspects of cell compositions over time, and extend their focus beyond lymph node-infiltrating T cells

Threshold electronic structure at the oxygen K edge of 3d transition metal oxides: a configuration interaction approach

It has been generally accepted that the threshold structure observed in the oxygen K edge X-ray absorption spectrum in 3d transition metal oxides represents the electronic structure of the 3d transition metal. There is, however, no consensus about the correct description. We present an interpretation, which includes both ground state hybridization and electron correlation. It is based on a configuration interaction cluster calculation using a MO6 cluster. The oxygen K edge spectrum is calculated by annihilating a ligand hole in the ground state and is compared to calculations representing inverse photoemission experiments in which a 3d transition metal electron is added. Clear differences are observed related to the amount of ligand hole created in the ground state. Two "rules" connected to this are discussed. Comparison with experimental data of some early transition metal compounds is made and shows that this simple cluster approach explains the experimental features quite well.Comment: 10 pages, submitted to Phys. Rev. B, tried to make a better PS file

X-ray emission from magnetized neutron star atmospheres at low mass accretion rates. I. Phase-averaged spectrum

Recent observations of X-ray pulsars at low luminosities allow, for the first time, to compare theoretical models for the emission from highly magnetized neutron star atmospheres at low mass accretion rates ($\dot{M} \lesssim 10^{15}$ g s$^{-1}$) with the broadband X-ray data. The purpose of this paper is to investigate the spectral formation in the neutron star atmosphere at low $\dot{M}$ and to conduct a parameter study of physical properties of the emitting region. We obtain the structure of the static atmosphere, assuming that Coulomb collisions are the dominant deceleration process. The upper part of the atmosphere is strongly heated by the braking plasma, reaching temperatures of 30-40 keV, while its denser isothermal interior is much cooler (~2 keV). We numerically solve the polarized radiative transfer in the atmosphere with magnetic Compton scattering, free-free processes, and non-thermal cyclotron emission due to possible collisional excitations of electrons. The strongly polarized emitted spectrum has a double-hump shape that is observed in low-luminosity X-ray pulsars. A low-energy "thermal" component is dominated by extraordinary photons that can leave the atmosphere from deeper layers due to their long mean free path at soft energies. We find that a high-energy component is formed due to resonant Comptonization in the heated non-isothermal part of the atmosphere even in the absence of collisional excitations. The latter, however, affect the ratio of the two components. A strong cyclotron line originates from the optically thin, uppermost zone. A fit of the model to NuSTAR and Swift/XRT observations of GX 304-1 provides an accurate description of the data with reasonable parameters. The model can thus reproduce the characteristic double-hump spectrum observed in low-luminosity X-ray pulsars and provides insights into spectral formation.Comment: 18 pages, 10 figures, A&A accepte