63 research outputs found
Size Dependence Of Lateral Diffusion In Model Cell Membranes Using Fluorescently Labelled Probe Molecules
Abstract Not Available
Examination of Water Phase Transitions in Black Spruce by Magnetic Resonance and Magnetic Resonance Imaging
This study examines the phase transitions of water in wood by magnetic resonance and magnetic resonance imaging. The goal was to observe and understand the behavior of water below 0°C in wood. The species studied, black spruce (Picea mariana Mill.), presented one abrupt phase change that occurred at about -3°C, which was attributed to the phase transition of free water. A more diffuse change occurred below -60°C, which was attributed to a phase transition of bound water. A recently developed portable unilateral magnetic resonance instrument is demonstrated as a powerful tool in the study of water in wood. This portable magnet used a bulk spin-spin relaxation time measurement that quantifies observable bound and free water in wood. Imaging was used to verify the unilateral magnetic resonance results and to better understand realistic freeze-thaw behavior of log samples in the field. A ring boundary behavior during the thawing process was observed, and likewise there were differences in the thawing behaviors of heartwood and sapwood samples
Magnetic Resonance Imaging of Water Concentration in Low Moisture Content Wood
A new magnetic resonance imaging (MRI) technique, termed SPRITE (Single Point Ramped Imaging with T1 Enhancement) permits visualization of water content in previously inaccessible wood fiber systems. We demonstrate the superiority of SPRITE methods, in comparison to conventional MRI methods, for studying fluid content in low water content wood materials. SPRITE and conventional MRI images were acquired from four species of wood, equilibrated at multiple moisture content levels. Both methods were also used to examine relative moisture content during forced drying of a white ash wood sample
Using phase interference to characterize dynamic propertiesâa review of constant gradient, portable magnetic resonance methods
Spatially resolved motion-sensitized magnetic resonance (MR) is a powerful tool for studying the dynamic properties of materials. Traditional methods involve using large, expensive equipment to create images of sample displacement by measuring the spatially resolved MR signal response to time-varying magnetic field gradients. In these systems, both the sample and the stress applicator are typically positioned inside a magnet bore. Portable MR instruments with constant gradients are more accessible, with fewer limitations on sample size, and they can be used in industrial settings to study samples under deformation or flow. We propose a view in which the well-controlled sensitive region of a magnet array acts as an integrator, with the velocity distribution leading to phase interference in the detected signal, which encodes information on the sampleâs dynamic properties. For example, in laminar flows of Newtonian and non-Newtonian fluids, the velocity distribution can be determined analytically and used to extract the fluidâs dynamic properties from the MR signal magnitude and/or phase. This review covers general procedures, practical considerations, and examples of applications in dynamic mechanical analysis and fluid rheology (viscoelastic deformation, laminar pipe flows, and Couette flows). Given that these techniques are relatively uncommon in the broader magnetic resonance community, this review is intended for both advanced NMR users and a more general physics/engineering audience interested in rheological applications of NMR
Exponential Capillary Pressure Functions in Sedimentary Rocks
The Brooks-Corey power-law capillary pressure model is commonly imposed on core analysis data without verifying the validity of its underlying assumptions. The Brooks-Corey model, originally developed to model the pressure head during the drainage of soil, is only valid at low wetting phase saturations. However, such models are often applied in petroleum production simulations and may lead to erroneous recovery factors when the saturation range of interest is far from the end points. We demonstrate that exponential models work much better for capillary pressure compared to the Brooks-Corey model over a wide saturation range. Mercury injection porosimetry, petrographic image analysis, and magnetic resonance studies suggest that the pore and throat size distribution in many rocks are log-normally distributed. This fact was previously employed to calculate the capillary pressure function as a function of saturation for pore size distributions described by atruncated log-normal distribution. Employing a Taylor series expansion, we simplify the random fractal capillary pressure model of Hunt to Pc = exp(a â bS), where S is the wetting phase saturation, and a and b characteristic of the porous medium. An extensive dataset of seventeen centrifuge capillary pressure measurements were used in this research to demonstrate the merit of the new method. For both sandstones and carbonates, the logarithm of capillary pressure showed a linear relationship with saturation as observed by magnetic resonance imaging centrifuge capillary pressure measurements over a wide saturation range. This work demonstrates that: (a) in semi-log plots of capillary pressure as a function of saturation, capillary pressurewill vary linearly over a wide saturation range, (b) such a plot as described in (a) will show the uni-or bimodal pore size distribution of the rock, (c) the exponential capillary pressure function simpliïŹes analytical modelsthat use the capillary pressure function, for example oil recovery models for fractured reservoirs
Monitoring gas hydrate formation with magnetic resonance imaging in a metallic core holder
Methane hydrate deposits world-wide are promising sources of natural gas. Magnetic Resonance Imaging (MRI) has proven useful in previous studies of hydrate formation. In the present work, methane hydrate formation in a water saturated sand pack was investigated employing an MRI-compatible metallic core holder at low magnetic ïŹeld with a suite of advanced MRI methods developed at the UNB MRI Centre. The new MRI methods are intended to permit observation and quantiïŹcation of residual ïŹuids in the pore space as hydrate forms. Hydrate formation occurred in the water-saturated sand at 1500 psi and 4 °C. The core holder has a maximum working pressure of 4000 psi between -28 and 80 °C. The heat-exchange jacket enclosing the core holder enabled very precise control of the sample temperature. A pure phase encode MRI technique, SPRITE, and a bulk T1-T2 MR method provided high quality measurements of pore ïŹuid saturation. Rapid 1D SPRITE MRI measurements time resolved the disappearance of pore water and hence the growth of hydrate in the sand pack. 3D Ï-EPI images conïŹrmed that the residual water was inhomogeneously distributed along the sand pack. Bulk T1-T2 measurements discriminated residual water from the pore gas during the hydrate formation. A recently published local T1-T2 method helped discriminate bulk gas from the residual ïŹuids in the sample. Hydrate formation commenced within two hours of gas supply. Hydrate formed throughout the sand pack, but maximum hydrate was observed at the interface between the gas pressure head and the sand pack. This irregular pattern of hydrate formation became more uniform over 24 hours. The rate of hydrate formation was greatest in the ïŹrst two hours of reaction. An SE-SPI T2 map showed the T2 distribution changed considerably in space and time as hydrate formation continued. Changes in the T2 distribution are interpreted as pore level changes in residual water content and environment
Recommended from our members
Genome-Wide Association of Body Fat Distribution in African Ancestry Populations Suggests New Loci
Central obesity, measured by waist circumference (WC) or waist-hip ratio (WHR), is a marker of body fat distribution. Although obesity disproportionately affects minority populations, few studies have conducted genome-wide association study (GWAS) of fat distribution among those of predominantly African ancestry (AA). We performed GWAS of WC and WHR, adjusted and unadjusted for BMI, in up to 33,591 and 27,350 AA individuals, respectively. We identified loci associated with fat distribution in AA individuals using meta-analyses of GWA results for WC and WHR (stage 1). Overall, 25 SNPs with single genomic control (GC)-corrected p-values<5.0Ă10â6 were followed-up (stage 2) in AA with WC and with WHR. Additionally, we interrogated genomic regions of previously identified European ancestry (EA) WHR loci among AA. In joint analysis of association results including both Stage 1 and 2 cohorts, 2 SNPs demonstrated association, rs2075064 at LHX2, pâ=â2.24Ă10â8 for WC-adjusted-for-BMI, and rs6931262 at RREB1, pâ=â2.48Ă10â8 for WHR-adjusted-for-BMI. However, neither signal was genome-wide significant after double GC-correction (LHX2: pâ=â6.5Ă10â8; RREB1: pâ=â5.7Ă10â8). Six of fourteen previously reported loci for waist in EA populations were significant (p<0.05 divided by the number of independent SNPs within the region) in AA studied here (TBX15-WARS2, GRB14, ADAMTS9, LY86, RSPO3, ITPR2-SSPN). Further, we observed associations with metabolic traits: rs13389219 at GRB14 associated with HDL-cholesterol, triglycerides, and fasting insulin, and rs13060013 at ADAMTS9 with HDL-cholesterol and fasting insulin. Finally, we observed nominal evidence for sexual dimorphism, with stronger results in AA women at the GRB14 locus (p for interactionâ=â0.02). In conclusion, we identified two suggestive loci associated with fat distribution in AA populations in addition to confirming 6 loci previously identified in populations of EA. These findings reinforce the concept that there are fat distribution loci that are independent of generalized adiposity
An assessment of non-wetting phase relative permeability in water-wet sandstones based on quantitative MRI of capillary end effects
Permeability mapping in naturally heterogeneous sandstone cores by magnetization prepared centric-scan sprite
Permeability mapping in porous media by magnetization prepared centric-scan SPRITE
The ability of porous media to transmit fluids is commonly referred to as permeability. The concept of permeability is central for hydrocarbon recovery from petroleum reservoirs and for studies of groundwater flow in aquifers. Spatially resolved measurements of permeability are of great significance for fluid dynamics studies. A convenient concept of local Darcy’s law is suggested for parallel flow systems. The product of porosity and mean velocity images in the plane across the average flow direction is directly proportional to permeability. Single Point Ramped Imaging with T 1 Enhancement (SPRITE) permits reliable quantification of local fluid content and flow in porous media. It is particularly advantageous for reservoir rocks characterized by fast magnetic relaxation of a saturating fluid. Velocity encoding using the Cotts pulsed field gradient scheme improves the accuracy of measured flow parameters. The method is illustrated through measurements of 2D permeability maps in a capillary bundle, glass bead packs and composite sandstone samples
- âŠ