Brushite mineralised Scots pine (Pinus sylvestris L.) sapwood – revealing mineral crystallization withina wood matrix by in situ XRD

Dicalcium phosphate dihydrate (CaHPO4·2H2O, DCPD, brushite) crystals were synthesised within Scots pine sapwood via a wet-chemistry route from aqueous solutions of Ca(CH3COO)2 and NH4H2PO4 salts. SEM/EDS analysis was used to assess the saturation of the wood cell lumina and cell wall as well as morphological features and elemental composition of the co-precipitated mineral. Brushite mineral crystallization and crystallite growth within the wood matrix was studied by in situ XRD. The chemical composition of the mineral before and after the dissolution was evaluated using FTIR spectroscopy. The overall impact of brushite on the thermal behaviour of wood was studied by TGA/DSC and TGA/DTA/MS analysis under oxidative and pyrolytic conditions. Bending and compression strength perpendicular and parallel to the fibre directions as well as bending strengths in longitudinal and transverse directions of the mineralised wood were also evaluated. Results indicate the viability of the wet-chemistry processing route for wood reinforcement with crystalline calcium phosphate (CaP)-based minerals, and imply a potential in producing hybrid bio-based materials that could be attractive in the construction sector as an environmentally friendly building material.Validerad;2023;Nivå 2;2023-02-16 (hanlid);Funder:  FCT/MEC (PIDDAC) (UIDB/50011/2020,UIDP/50011/2020, LA/P/0006/2020)</p

Generation of a single UV pulse from a near-IR pulse burst

Date of Conference: 25-29 June 2017 in Munich, GermanySummary form only given. High harmonic generation (HHG) requires high peak-power laser sources. Most of the well-known high peak power lasers are operating in the near-IR wavelength region. Recently it was demonstrated that HHG can be effectively phase matched in the soft X-ray region by using very high intensity UV lasers and multiply charged ions [1]. High average and high peak power UV sources operating around and below 280 nm are required for many other applications, such as ablation in ophthalmology, materials processing and photoelectron spectroscopy. Due to lack of ultrafast high peak power lasers operating in UV, generation of ultrashort UV pulses is possible by up-converting frequency of near-IR laser. This can be done by cascaded harmonic generation in nonlinear crystals with efficiency higher than 40% [2]. However, to obtain high pulse energies in UV region, high energy IR pump is necessary. This becomes increasingly difficult for femtosecond laser pulses because of the optical damage problem in CPA systems. Very high pulse stretching rates in the CPA become unfeasible due to the limited size of dispersive optics. Alternatively, the intensity in the laser cavity can be decreased by using a pulse burst which effectively increases the pulse duration. Therefore, this approach is also suitable for increasing energy throughput in fiber delivery and fiber post compression schemes [3]. © 2017 IEEE

Multi-millijoule Few-Optical-Cycle Pulses in Mid-IR: Scaling Power, Energy and Wavelength

We discuss prospects of the generation of high power mid-IR pulses by analyzing soliton self-compression of multi-mJ 4-μm pulses and the development of few-optical-cycle 6-μm optical parametric amplifier. Scalability of pump lasers is addressed