1,748 research outputs found
K+ Ions Crosslinked Kappa-Carrageenan/Methylene Blue Composite Film. Part-1: Synthesis, Characterization and Application as Controlled Release Device for Photodynamic Therapy Application
K+ ions crosslinked (KC/MB) Methylene blue photosensitizer loaded composite film is prepared for photodynamic therapy (PDT) application as Photosensitizer released by composite film can conveniently be controlled by using different quantities of K+ ions and this application is based on dynamic interaction between light with suitable wavelength, photosensitizer and molecular oxygen, promoting the death of the target tissue or bacterial cells. In this work, the Methylene Blue (MB) loaded Carrageenan polymeric film was prepared by the method of direct addition of MB into pre-polymerization solution of Carrageenan (KC). This composite film and plain KC film were characterized by FTIR, XRD and SEM analysis. The characteristic peaks of MB photosensitizer were obtained in FTIR spectrum of composite film. The composite film KC/MB shows prominence of amorphous nature may be due to MB is present in very small quantity. The SEM analysis reveals that the composite film (KC/MB) having much more smooth surface texture throughout the film. Finally, the result of effect of variation in degree of crosslinking on amount of MB release is, as the amount of K+ ions used to crosslink the film increases, MB release decreases.  
Probing a ferromagnetic critical regime using nonlinear susceptibility
The second order para-ferromagnetic phase transition in a series of amorphous
alloys (Fe{_5}Co{_{50}}Ni{_{17-x}}Cr{_x}B{_{16}}Si{_{12}}) is investigated
using nonlinear susceptibility. A simple molecular field treatment for the
critical region shows that the third order suceptibility (chi{_3}) diverges on
both sides of the transition temperature, and changes sign at T{_C}. This
critical behaviour is observed experimentally in this series of amorphous
ferromagnets, and the related assymptotic critical exponents are calculated. It
is shown that using the proper scaling equations, all the exponents necessary
for a complete characterization of the phase transition can be determined using
linear and nonlinear susceptiblity measurements alone. Using meticulous
nonlinear susceptibility measurements, it is shown that at times chi{_3} can be
more sensitive than the linear susceptibility (chi{_1}) in unravelling the
magnetism of ferromagnetic spin systems. A new technique for accurately
determining T{_C} is discussed, which makes use of the functional form of
chi{_3} in the critical region.Comment: 11 Figures, Submitted to Physical Review
Accumulation of Arsenic and Fluoride in Lichen Pyxine cocoes (Sw.) Nyl., Growing in the Vicinity of Coal-based Thermal Power Plant at Raebareli, India
ABSTRACT: Levels of arsenic (As) and fluoride (F) were determined in an epiphytic lichen Pyxine cocoes (Sw.) Nyl., collected from the vicinity of coal based thermal power plant of Raebareli, India. Both the elements are abundant in lichen thallus, while their substratum contained negligible amount. The As ranged between 8.9±0.7 to 77.3±2.0 µg g-1 dry weight in thallus and 1.0±0.0 to 9.7±0.2 µg g-1 dry weight in substratum; whereas F ranged between 9.3±0.52 to 105.8±2.3 µg g-1 dry weight in thallus however, it not detected in the substratum. The quantities of As in thallus increased with decreasing distance from the power plant, but F showed an opposite trend. The distribution of As and F around the power plant showed positive correlation with distance in all directions with better dispersion in western side as indicated by the concentration coefficient (R2). The F accumulaiton patterns in lichens clearly indicate that the coal burning in power plant is the major contributor, and has its maximum levels on the down wind side. The analysis of variance and LSD indiacted that the As, F concentrations among lichen thallus is significant at p< 0.01% level. Key words: Bioaccumulation, Arsenic, Fluoride, Lichen, Thermal Power Plant Please Cite This Article As: R. Bajpai et al. 2010. Accumulation of Arsenic and Fluoride in Lichen Pyxine cocoes (Sw.) Nyl., Growing in the Vicinity of Coal-based Thermal Power Plant at Raebareli, India. J. Exp. Sci. 1(4):34-37
Development of a heating reactor for a continuous flow-through application in urea measurement
In most biochemical analyses, a flow-through heating arrangement is needed to reduce the reaction time or maintain a constant temperature. A rectangular reactor is described that is constructed of aluminium, is hollow inside and is filled with silicone oil. The glass coil through which the solution flows is immersed in the silicone oil. The heater, a Peltier-effect heat pump, on one side and the temperature sensor on the other side of the reactor body are embedded for heating and temperature control. The brief performance evaluation of the reactor is discussed by measuring the absorbance of urea concentration at different temperatures
Interface driven magnetoelectric effects in granular CrO2
Antiferromagnetic and magnetoelectric Cr2O3-surfaces strongly affect the
electronic properties in half metallic CrO2. We show the presence of a Cr2O3
surface layer on CrO3 grains by high-resolution transmission electron
microscopy. The effect of these surface layers is demonstrated by measurements
of the temperature variation of the magnetoelectric susceptibility. A major
observation is a sign change at about 100 K followed by a monotonic rise as a
function of temperature. These electric field induced moments in CrO3 are
correlated with the magnetoelectric susceptibility of pure Cr2O3. This study
indicates that it is important to take into account the magnetoelectric
character of thin surface layers of Cr2O3 in granular CrO2 for better
understanding the transport mechanism in this system. The observation of a
finite magnetoelectric susceptibility near room temperature may find utility in
device applications.Comment: Figure 1 with strongly reduced resolutio
A critical investigation of various subclasses of functions whose real part is bounded
In this paper we investigate various subclasses of univalent analytic
functions. We find that many of the subclasses introduced in the recent years are no more new and infact coincide with the class due to Jakubowski. We further study the generalised Jakubowski class of univalent functions and obtain a representational formula and use it in deriving the coefficient relations for this clas
A Brief Overview on Ferrite (Fe3O4) Based Polymeric Nanocomposites: Recent Developments and Challenges
In this article, we have mainly discussed about ferrite (Fe3O4) and its polymer based nanocomposites. Ferrite particles have become an important research material because of their vast applications in the field of biotechnology, magnetic resonance imaging (MRI), and data storage. It has been observed that ferrite Fe3O4 particles show best performance for size less than 10-30 nm. This happens due to the super paramagnetic nature of such particles. In super paramagnetic range these particles exhibit zero remanence or coercivity. Therefore, various properties of ferrite (Fe3O4) nanoparticles and its polymer nanocomposites are very much dependent on the size, and distribution of the particles in the polymeric matrix. Moreover, it has been also observed that the shape of the nanocrystals plays important role in the determination of their fundamental properties. These particles show instability over longer times due to the formation of agglomerates generated by high surface energies. Therefore, protection strategies such as grafting and coatings with silica/carbon or polymers have been developed to stabilize them chemically. Recently, silylation technique is mainly used for the modification of nanoparticles. Experimentally, it has been observed that nanocomposites composed of polymer matrices and ferrite showed substantial improvements in stiffness, fracture toughness, sensing ability (magnetic as well as electric), impact energy absorption, and electro-catalytic activities to bio-species
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