Laser diagnostics for characterization of sprays formed by a collapsing non-equilibrium bubble

In this paper, we investigate the use of laser diagnostic tools for in-plane imaging of bubble induced spray using a laser sheet and Mie scattering technique. A perspex plate of thickness 10 mm with a hole of diameter 1 mm in the center is placed in the middle of a glass tank filled with water such that the top surface of the plate coincides with the water surface. A bubble is created just below the hole using a low-voltage spark circuit such that it expands against the hole. This leads to the formation of two jets which impact leading to a spray and break-up into droplets. The spray evolution is observed using a laser sheet directed in a plane through the center of the hole. The illuminated plane is imaged using a high-speed camera based on the Mie scattering from glass beads suspended in the liquid. Results show that Mie scattering technique has potential in studying bubble-induced sprays with applications such as in fuel sprays, drug-delivery etc, and also for validation of numerical codes. We present results from our ongoing experiments in this paper

Crop Residue Burning in Northern India: Increasing Threat to Greater India

Crop residue burning (CRB) is a recurring problem, during October–November, in the northwestern regions (Punjab, Haryana, and western Uttar Pradesh) of India. The emissions from the CRB source regions spread in all directions through long-range transport mechanisms, depending upon the meteorological conditions. In recent years, numerous studies have been carried out dealing with the impact of CRB on the air quality of Delhi and surrounding areas, especially in the Indo-Gangetic Basin (also referred to as Indo-Gangetic Plain). In this paper, we present detailed analysis using both satellite- and ground-based sources, which show an increasing impact of CRB over the eastern parts of the Indo-Gangetic Basin and also over parts of central and southern India. The increasing trends of finer black carbon particles and greenhouse gases have accelerated since the year 2010 onward, which is confirmed by the observation of different wavelength dependent aerosol properties. Our study shows an increased risk to ambient air quality and an increased spatiotemporal extent of pollutants in recent years, from CRB, which could be a severe health threat to the population of these regions

Simulation of aerosol optical properties over a tropical urban site in India using a global model and its comparison with ground measurements

Aerosols have great impacts on atmospheric environment, human health, and earth's climate. Therefore, information on their spatial and temporal distribution is of paramount importance. Despite numerous studies have examined the variation and trends of BC and AOD over India, only very few have focused on their spatial distribution or even correlating the observations with model simulations. In the present study, a three-dimensional aerosol transport-radiation model coupled with a general circulation model. SPRINTARS, simulated atmospheric aerosol distributions including BC and aerosol optical properties, i.e., aerosol optical thickness (AOT), Ångström Exponent (AE), and single scattering albedo (SSA). The simulated results are compared with both BC measurements by aethalometer and aerosol optical properties measured by ground-based skyradiometer and by satellite sensor, MODIS/Terra over Hyderabad, which is a tropical urban area of India, for the year 2008. The simulated AOT and AE in Hyderabad are found to be comparable to ground-based measured ones. The simulated SSA tends to be higher than the ground-based measurements. Both these comparisons of aerosol optical properties between the simulations with different emission inventories and the measurements indicate that, firstly the model uncertainties derived from aerosol emission inventory cannot explain the gaps between the simulations and the measurements and secondly the vertical transport of BC and the treatment of BC-containing particles can be the main issue in the global model to solve the gap

Influence of continental advection on aerosol characteristics over Bay of Bengal (BoB) in winter: results from W-ICARB cruise experiment

The transport of aerosols and pollutants from continental India to the adjoining oceanic areas is a major topic of concern and several experimental campaigns have been conducted over the region focusing on aerosol characteristics and their climate implications. The present study analyzes the spectral aerosol optical depth (AOD) variations over Bay of Bengal (BoB) during Winter-Integrated Campaign for Aerosols, gases and Radiation Budget (W-ICARB) from 27 December 2008 to 30 January 2009 and investigates the influence of the adjoining landmass to the marine aerosol field. High AOD₅₀₀ values (>0.7) occurred over northern BoB due to outflow of aerosols and pollutants from the densely populated Indo-Gangetic Plains (IGP); low AOD₅₀₀ (0.1–0.2) was observed in central and southern BoB, far away from the mainland. The Angstrom exponent "α" was observed to be high (>1.2) near coastal waters, indicating relative abundance of accumulation-mode continental aerosols. On the other hand, over southern BoB its values dropped below ~0.7. National Center for Environmental Prediction (NCEP) reanalysis data on winds at 850 and 700 hPa, along with air-mass trajectories calculated using Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model, suggested transport of continental aerosols from central and northern India over the BoB. On the other hand, when the ship was crossing the eastern BoB, the aerosol loading was strongly affected by air-masses originating from Southeast Asia, causing an increase in AOD and α. Biomass-burning episodes over the region played an important role in the observed aerosol properties. Terra/Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) AOD₅₅₀ and cruise measured AOD₅₅₀ showed good agreement (<I>R</I>² = 0.86 and 0.77, respectively) over BoB, exhibiting similar AOD and α spatio-temporal variation

Aerosol climatology: on the discrimination of aerosol types over four AERONET sites

International audienceAerosols have a significant regional and global effect on climate, which is about equal in magnitude but opposite in sign to that of greenhouse gases. Nevertheless, the aerosol climatic effect changes strongly with space and time because of the large variability of aerosol physical and optical properties, which is due to the variety of their sources, which are natural, and anthropogenic, and their dependence on the prevailing meteorological and atmospheric conditions. Characterization of aerosol properties is of major importance for the assessment of their role for climate. In the present study, 3-year AErosol RObotic NETwork (AERONET) data from ground-based sunphotometer measurements are used to establish climatologies of aerosol optical depth (AOD) and Ångström exponent ? in several key locations of the world, characteristic of different atmospheric environments. Using daily mean values of AOD at 500 nm (AOD500) and Ångström exponent at the pair of wavelengths 440 and 870 nm (? 440?870), a discrimination of the different aerosol types occurring in each location is achieved. For this discrimination, appropriate thresholds for AOD500 and ? 440?870 are applied. The discrimination of aerosol types in each location is made on an annual and seasonal basis. It is shown that a single aerosol type in a given location can exist only under specific conditions (e.g. intense forest fires or dust outbreaks), while the presence of well-mixed aerosols is the accustomed situation. Background clean aerosol conditions (AOD500<0.06) are mostly found over remote oceanic surfaces occurring on average in ~56.7% of total cases, while this situation is quite rare over land (occurrence of 3.8?13.7%). Our analysis indicates that these percentages change significantly from season to season. The spectral dependence of AOD exhibits large differences between the examined locations, while it exhibits a strong annual cycle

Spatial patterns of vegetation phenology metrics and related climatic controls of eight contrasting forest types in India – analysis from remote sensing datasets

Summary Leaf phenology describes the seasonal cycle of leaf functioning and is essential for understanding the interactions between the biosphere, the climate and the atmosphere. In this study, we characterized the spatial patterns in phenological variations in eight contrasting forest types in an Indian region using coarse resolution NOAA AVHRR satellite data. The onset, offset and growing season length for different forest types has been estimated using normalized difference vegetation index (NDVI). Further, the relationship between NDVI and climatic parameters has been assessed to determine which climatic variable (temperature or precipitation) best explain variation in NDVI. In addition, we also assessed how quickly and over what time periods does NDVI respond to different precipitation events. Our results suggested strong spatial variability in NDVI metrics for different forest types. Among the eight forest types, tropical dry deciduous forests showed lowest values for summed NDVI (SNDVI), averaged NDVI (ANDVI) and integrated NDVI (I-NDVI), while the tropical wet evergreen forests of Arunachal Pradesh had highest values. Within the different evergreen forest types, SNDVI, ANDVI and INDVI were highest for tropical wet evergreen forests, followed by tropical evergreen forests, tropical semi-evergreen forests and were least for tropical dry evergreen forests. Differences in the amplitude of NDVI were quite distinct for evergreen forests compared to deciduous ones and mixed deciduous forests. Although, all the evergreen forests studied had a similar growing season length of 270 days, the onset and offset dates were quite different. Response of vegetative greenness to climatic variability appeared to vary with vegetation characteristics and forest types. Linear correlations between mean monthly NDVI and temperature were found to yield negative relationships in contrast to precipitation, which showed a significant positive response to vegetation greenness. The correlations improved much for different forest types when the log of cumulative rainfall was correlated against mean monthly NDVI. Of the eight forest types, the NDVI for six forest types was positively correlated with the logarithm of cumulative rainfall that was summed for 3-4 months. Overall, this study identifies precipitation as a major control for vegetation greenness in tropical forests, more so than temperature

Extremely large anthropogenic-aerosol contribution to total aerosol load over the Bay of Bengal during winter season

Ship-borne observations of spectral aerosol optical depth (AOD) have been carried out over the entire Bay of Bengal (BoB) as part of the W-ICARB cruise campaign during the period 27 December 2008–30 January 2009. The results reveal a pronounced temporal and spatial variability in the optical characteristics of aerosols mainly due to anthropogenic emissions and their dispersion controlled by local meteorology. The highest aerosol amount, with mean AOD&lt;sub&gt;500&lt;/sub&gt;&gt;0.4, being even above 1.0 on specific days, is found close to the coastal regions in the western and northern parts of BoB. In these regions the Ångström exponent is also found to be high (~1.2–1.25) indicating transport of strong anthropogenic emissions from continental regions, while very high AOD&lt;sub&gt;500&lt;/sub&gt; (0.39&amp;plusmn;0.07) and &amp;alpha;&lt;sub&gt;380–870&lt;/sub&gt; values (1.27&amp;plusmn;0.09) are found over the eastern BoB. Except from the large &amp;alpha;&lt;sub&gt;380–870&lt;/sub&gt; values, an indication of strong fine-mode dominance is also observed from the AOD curvature, which is negative in the vast majority of the cases, suggesting dominance of an anthropogenic-pollution aerosol type. On the other hand, clean maritime conditions are rather rare over the region, while the aerosol types are further examined through a classification scheme based on the relationship between α and &lt;i&gt;d&lt;/i&gt;&amp;alpha;. It was found that even for the same α values the fine-mode dominance is larger for higher AODs showing the strong continental influence over the marine environment of BoB. Furthermore, there is also an evidence of aerosol-size growth under more turbid conditions indicative of coagulation and/or humidification over specific BoB regions. The results obtained using OPAC model show significant fraction of soot aerosols (~6 %–8 %) over the eastern and northwestern BoB, while coarse-mode sea salt particles are found to dominate in the southern parts of BoB

Impact of diesel vehicular emissions on ambient black carbon concentration at an urban location in India

Vehicular emissions in the urban areas are known to contribute significantly to aerosol black carbon (BC) loading to the atmosphere. Quantification of BC emissions is important from the climate research point of view, as the BC aerosols strongly absorb solar radiation. A case study has been carried out in an urban area, Hyderabad, to assess the impact of emissions associated with truck transport on ambient BC concentration. The study was carried out during the recent nationwide truck strike of April 2003. The results indicate a significant reduction in the BC loading associated with withdrawal of the trucks. The decrease was gradual, while the recovery was almost immediate

Characteristics of spectral aerosol optical depths over India during ICARB

Spectral aerosol optical depth (AOD) measurements, carried out regularly from a network of observatories spread over the Indian mainland and adjoining islands in the Bay of Bengal and Arabian Sea, are used to examine the spatio-temporal and spectral variations during the period of ICARB (March to May 2006). The AODs and the derived Angstrom parameters showed considerable variations across India during the above period. While at the southern peninsular stations the AODs decreased towards May after a peak in April, in the north Indian regions they increased continuously from March to May. The Angstrom coefficients suggested enhanced coarse mode loading in the north Indian regions, compared to southern India. Nevertheless, as months progressed from March to May, the dominance of coarse mode aerosols increased in the columnar aerosol size spectrum over the entire Indian mainland, maintaining the regional distinctiveness. Compared to the above, the island stations showed considerably low AODs, so too the northeastern station Dibrugarh, indicating the prevalence of cleaner environment. Long-range transport of aerosols from the adjoining regions leads to remarkable changes in the magnitude of the AODs and their wavelength dependencies during March to May. HYSPLIT back-trajectory analysis shows that enhanced long-range transport of aerosols, particularly from the west Asia and northwest coastal India, contributed significantly to the enhancement of AOD and in the flattening of the spectra over entire regions; if it is the peninsular regions and the island Minicoy are more impacted in April, the north Indian regions including the Indo Gangetic Plain get affected the most during May, with the AODs soaring as high as 1.0 at 500 nm. Over the islands, the Angstrom exponent (α) remained significantly lower (~1) over the Arabian Sea compared to Bay of Bengal (BoB) (~1.4) as revealed by the data respectively from Minicoy and Port Blair. Occurrences of higher values of α, showing dominance of accumulation mode aerosols, over BoB are associated well with the advection, above the boundary layer, of fine particles from the east Asian region during March and April. The change in the airmass to marine in May results in a rapid decrease in α over the BoB

Fluorophore tagged mixed ligand copper(II) complexes: synthesis, structural characterization, protein binding, DNA cleavage and anticancer activity

Two fluorophore tagged copper(II) complexes Cu(phen)(L)(ClO4)(2)] (1) and Cu(bpy)(L)(H2O)(ClO4)](ClO4) (2), (where L=2-amino-1H-benzode]isoquinoline-1,3-(2H)dione (L), phen=1,10-phenanthroline and bpy=2,2 `-bipyridine) have been synthesized and structurally characterized. Structures of the copper complexes 1 and 2 were confirmed by single-crystal X-ray structure determination. The coordination geometry around the copper center of complexes 1 and 2 is distorted octahedral. The plasmid DNA cleavage activity of the complexes has been investigated by agarose gel electrophoresis and the study reveals that both the complexes have high plasmid DNA photo-cleavage activity. The binding interaction ability of the metal complexes with bovine serum albumin (BSA) was investigated using fluorescence spectroscopy. The cytotoxicity of the complexes has been evaluated by MTT (3-4,5-dimethylthiazole-2-yl]-2,5-diphenyltetrazolium bromide) assay against A549 (adenocarcinoma human alveolar basal epithelial cells) and MCF-7 (breast cancer cell line) cell lines in comparison with cis-platin. Complexes 1 and 2 have exhibited better cytotoxic activity than cis-platin against A549 and MCF-7 cell lines. The cellular uptake study and localization of the complexes within the cells have been investigated by fluorescence microscopy. The cell staining and flow cytometry experiments suggest that complexes induce an apoptotic mode of cell death