564 research outputs found
Ground state properties of ferromagnetic metal/conjugated polymer interfaces
We theoretically investigate the ground state properties of ferromagnetic
metal/conjugated polymer interfaces. The work is partially motivated by recent
experiments in which injection of spin polarized electrons from ferromagnetic
contacts into thin films of conjugated polymers was reported. We use a
one-dimensional nondegenerate Su-Schrieffer-Heeger (SSH) Hamiltonian to
describe the conjugated polymer and one-dimensional tight-binding models to
describe the ferromagnetic metal. We consider both a model for a conventional
ferromagnetic metal, in which there are no explicit structural degrees of
freedom, and a model for a half-metallic ferromagnetic colossal
magnetoresistance (CMR) oxide which has explicit structural degrees of freedom.
The Fermi energy of the magnetic metallic contact is adjusted to control the
degree of electron transfer into the polymer. We investigate electron charge
and spin transfer from the ferromagnetic metal to the organic polymer, and
structural relaxation near the interface. Bipolarons are the lowest energy
charge state in the bulk polymer for the nondegenerate SSH model Hamiltonian.
As a result electrons (or holes) transferred into the bulk of the polymer form
spinless bipolarons. However, there can be spin density in the polymer
localized near the interface.Comment: 7 figure
Dynamical study on polaron formation in a metal/polymer/metal structure
By considering a metal/polymer/metal structure within a tight-binding
one-dimensional model, we have investigated the polaron formation in the
presence of an electric field. When a sufficient voltage bias is applied to one
of the metal electrodes, an electron is injected into the polymer chain, then a
self-trapped polaron is formed at a few hundreds of femtoseconds while it moves
slowly under a weak electric field (not larger than V/cm).
At an electric field between V/cm and V/cm,
the polaron is still formed, since the injected electron is bounded between the
interface barriers for quite a long time. It is shown that the electric field
applied at the polymer chain reduces effectively the potential barrier in the
metal/polymer interface
Improving the Accuracy of a Two-Stage Algorithm in Evolutionary Product Unit Neural Networks for Classification by Means of Feature Selection
This paper introduces a methodology that improves the accuracy
of a two-stage algorithm in evolutionary product unit neural networks
for classification tasks by means of feature selection. A couple
of filters have been taken into consideration to try out the proposal.
The experimentation has been carried out on seven data sets from the
UCI repository that report test mean accuracy error rates about twenty
percent or above with reference classifiers such as C4.5 or 1-NN. The
study includes an overall empirical comparison between the models obtained
with and without feature selection. Also several classifiers have
been tested in order to illustrate the performance of the different filters
considered. The results have been contrasted with nonparametric statistical
tests and show that our proposal significantly improves the test
accuracy of the previous models for the considered data sets. Moreover,
the current proposal is much more efficient than a previous methodology
developed by us; lastly, the reduction percentage in the number of inputs
is above a fifty five, on average.MICYT TIN2007-68084-C02-02MICYT TIN2008-06681-C06-03Junta de AndalucĂa P08-TIC-374
Foreground removal from CMB temperature maps using an MLP neural network
One of the main obstacles in extracting the Cosmic Microwave Background (CMB)
signal from observations in the mm-submm range is the foreground contamination
by emission from galactic components: mainly synchrotron, free-free and thermal
dust emission. Due to the statistical nature of the intrinsic CMB signal it is
essential to minimize the systematic errors in the CMB temperature
determinations. Following the available knowledge of the spectral behavior of
the galactic foregrounds simple, power law-like spectra have been assumed. The
feasibility of using a simple neural network for extracting the CMB temperature
signal from the combined CMB and foreground signals has been investigated. As a
specific example, we have analysed simulated data, like that expected from the
ESA Planck Surveyor mission. A simple multilayer perceptron neural network with
2 hidden layers can provide temperature estimates, over more than 80 percent of
the sky, that are to a high degree uncorrelated with the foreground signals. A
single network will be able to cover the dynamic range of the Planck noise
level over the entire sky.Comment: Accepted for publication in Astrophysics and Space Scienc
Hydrodynamics of Spatially Ordered Superfluids
We derive the hydrodynamic equations for the supersolid and superhexatic
phases of a neutral two-dimensional Bose fluid. We find, assuming that the
normal part of the fluid is clamped to an underlying substrate, that both
phases can sustain third-sound modes and that in the supersolid phase there are
additional modes due to the superfluid motion of point defects (vacancies and
interstitials).Comment: 24 pages of ReVTeX and 7 uuencoded figures. Submitted for publication
in Phys. Rev.
A Bishop-Phelps-Bollobas Type Theorem for uniform algegras
This paper is devoted to showing that Asplund operators with range in a uniform Banach algebra have
the BishopÂżPhelpsÂżBollobas property, i.e., they are approximated by norm attaining Asplund operators
at the same time that a point where the approximated operator almost attains its norm is approximated
by a point at which the approximating operator attains it. To prove this result we use the weak*-to-norm
fragmentability of weak*-compact subsets of the dual of Asplund spaces and we need to observe a Urysohn type result producing peak complex-valued functions in uniform algebras that are small outside a given open set and whose image is inside a Stolz region.This research was partially supported by MEC and FEDER projects MTM2008-05396 and MTM2011-25377. The research of the second author was also partially supported by Generalitat Valenciana (GV/2010/036), and by Universidad Politecnica de Valencia (project PAID-06-09-2829).Cascales, B.; Guirao SĂĄnchez, AJ.; Kadets, V. (2013). A Bishop-Phelps-Bollobas Type Theorem for uniform algegras. Advances in Mathematics. 240:370-382. https://doi.org/10.1016/j.aim.2013.03.005S37038224
Elastic electron deuteron scattering with consistent meson exchange and relativistic contributions of leading order
The influence of relativistic contributions to elastic electron deuteron
scattering is studied systematically at low and intermediate momentum transfers
( fm). In a -expansion, all leading order
relativistic -exchange contributions consistent with the Bonn OBEPQ models
are included. In addition, static heavy meson exchange currents including boost
terms and lowest order -currents are considered. Sizeable
effects from the various relativistic two-body contributions, mainly from
-exchange, have been found in form factors, structure functions and the
tensor polarization . Furthermore, static properties, viz. magnetic
dipole and charge quadrupole moments and the mean square charge radius are
evaluated.Comment: 15 pages Latex including 5 figures, final version accepted for
publication in Phys.Rev.C Details of changes: (i) The notation of the curves
in Figs. 1 and 2 have been clarified with respect to left and right panels.
(ii) In Figs. 3 and 4 an experimental point for T_20 has been added and a
corresponding reference [48] (iii) At the end of the text we have added a
paragraph concerning the quality of the Bonn OBEPQ potential
Optical application and measurement of torque on microparticles of isotropic nonabsorbing material
We show how it is possible to controllably rotate or align microscopic
particles of isotropic nonabsorbing material in a TEM00 Gaussian beam trap,
with simultaneous measurement of the applied torque using purely optical means.
This is a simple and general method of rotation, requiring only that the
particle is elongated along one direction. Thus, this method can be used to
rotate or align a wide range of naturally occurring particles. The ability to
measure the applied torque enables the use of this method as a quantitative
tool--the rotational equivalent of optical tweezers based force measurement. As
well as being of particular value for the rotation of biological specimens,
this method is also suitable for the development of optically-driven
micromachines.Comment: 8 pages, 6 figure
HRâpQCT measures of bone microarchitecture predict fracture : systematic review and metaâanalysis
HRâpQCT is a nonâinvasive imaging modality for assessing volumetric bone mineral density (vBMD) and microarchitecture of cancellous and cortical bone. The objective was to (i) assess fractureâassociated differences in HRâpQCT bone parameters and (ii) to determine if HRâpQCT is sufficiently precise to reliably detect these differences in individuals. We systematically identified 40 studies that used HRâpQCT (39/40 used XtremeCT scanners) to assess 1291â3253 and 3389â10,687 individuals with and without fractures, respectively, ranging in age from 10.9 to 84.7âyears with no comorbid conditions. Parameters describing radial and tibial bone density, microarchitecture, and strength were extracted and percentage differences between fracture and control subjects were estimated using a random effects metaâanalysis. An additional metaâanalysis of shortâterm in vivo reproducibility of bone parameters assessed by XtremeCT was conducted to determine whether fractureâassociated differences exceeded the least significant change (LSC) required to discern measured differences from precision error. Radial and tibial HRâpQCT parameters, including failure load, were significantly altered in fracture subjects, with differences ranging from â2.6% (95% CI: â3.4 to â1.9) in radial cortical vBMD to â12.6% (95% CI: â15.0 to â10.3) in radial trabecular vBMD. Fractureâassociated differences reported by prospective studies were consistent with those from retrospective studies, indicating that HRâpQCT can predict incident fracture. Assessment of study quality, heterogeneity and publication biases verified the validity of these findings. Finally, we demonstrated that fractureâassociated deficits in total and trabecular vBMD, and certain tibial cortical parameters, can be reliably discerned from HRâpQCTârelated precision error and can be used to detect fractureâassociated differences in individual patients. Although differences in other HRâpQCT measures, including failure load, were significantly associated with fracture, improved reproducibility is needed to ensure reliable individual crossâsectional screening and longitudinal monitoring. In conclusion, our study supports the use of HRâpQCT in clinical fracture prediction
Rapid scalable processing of tin oxide transport layers for perovskite solar cells
The development of scalable deposition methods for perovskite solar cell materials is critical to enable the commercialization of this nascent technology. Herein, we investigate the use and processing of nanoparticle SnO2 films as electron transport layers in perovskite solar cells and develop deposition methods for ultrasonic spray coating and slot-die coating, leading to photovoltaic device efficiencies over 19%. The effects of postprocessing treatments (thermal annealing, UV ozone, and O2 plasma) are then probed using structural and spectroscopic techniques to characterize the nature of the np-SnO2/perovskite interface. We show that a brief âhot air flowâ method can be used to replace extended thermal annealing, confirming that this approach is compatible with high-throughput processing. Our results highlight the importance of interface management to minimize nonradiative losses and provide a deeper understanding of the processing requirements for large-area deposition of nanoparticle metal oxides
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