142 research outputs found
Mode-coupling theory for structural and conformational dynamics of polymer melts
A mode-coupling theory for dense polymeric systems is developed which
unifyingly incorporates the segmental cage effect relevant for structural
slowing down and polymer chain conformational degrees of freedom. An ideal
glass transition of polymer melts is predicted which becomes molecular-weight
independent for large molecules. The theory provides a microscopic
justification for the use of the Rouse theory in polymer melts, and the results
for Rouse-mode correlators and mean-squared displacements are in good agreement
with computer simulation results.Comment: 4 pages, 3 figures, Phys. Rev. Lett. in pres
Probing the interface magnetism in the FeMn/NiFe exchange bias system using magnetic second harmonic generation
Second harmonic generation magneto-optic Kerr effect (SHMOKE) experiments,
sensitive to buried interfaces, were performed on a polycrystalline NiFe/FeMn
bilayer in which areas with different exchange bias fields were prepared using
5 KeV He ion irradiation. Both reversible and irreversible uncompensated spins
are found in the antiferromagnetic layer close to the interface with the
ferromagnetic layer. The SHMOKE hysteresis loop shows the same exchange bias
field as obtained from standard magnetometry. We demonstrate that the exchange
bias effect is controlled by pinned uncompensated spins in the
antiferromagnetic layer.Comment: submitted to Phys. Rev. Let
Theory for the excitation spectrum of High-T$_c superconductors : quasiparticle dispersion and shadows of the Fermi surface
Using a new method for the solution of the FLEX-equations, which allows the
determination of the self energy of the Hubbard
model on the real frequency axis, we calculate the doping dependence of the
quasi-particle excitations of High-T superconductors. We obtain new results
for the shadows of the Fermi surface, their dependence on the deformation of
the quasi particle dispersion, an anomalous -dependence of and a related violation of the Luttinger theorem.
This sheds new light on the influence of short range magnetic order on the low
energy excitations and its significance for photoemission experiments.Comment: 4 pages (REVTeX) with 3 figure
The mean-squared displacement of a molecule moving in a glassy system
The mean-squared displacement (MSD) of a hard sphere and of a dumbbell
molecule consisting of two fused hard spheres immersed in a dense hard-sphere
system is calculated within the mode-coupling theory for ideal liquid-glass
transitions. It is proven that the velocity correlator, which is the second
time derivative of the MSD, is the negative of a completely monotone function
for times within the structural-relaxation regime. The MSD is found to exhibit
a large time interval for structural relaxation prior to the onset of the
-process which cannot be described by the asymptotic formulas for the
mode-coupling-theory-bifurcation dynamics. The -process for molecules
with a large elongation is shown to exhibit an anomalously wide cross-over
interval between the end of the von-Schweidler decay and the beginning of
normal diffusion. The diffusivity of the molecule is predicted to vary
non-monotonically as function of its elongation.Comment: 18 pages, 12 figures, Phys. Rev. E, in prin
Phonon anomalies at the valence transition of SmS : An inelasticX-ray scattering study under pressure
The phonon dispersion curve of SmS under pressure was studied by inelastic
x-ray scattering around the pressure-induced valence transition. A significant
softening of the longitudinal acoustic modes propagating along the [111]
direction was observed spanning a wide region from
() up to the zone boundary as
SmS becomes metallic. The largest softening occurs at the zone boundary and
stays stable up to the highest measured pressure of 80 kbar while a gradual
hardening of the low modes simultaneously appears. This phonon spectrum
indicates favorable conditions for the emergence of pressure-induced
superconductivity in SmS.Comment: 4 pages, 3 figure
Theory for phonon-induced superconductivity in MgB
We analyze superonductivity in MgB observed below K resulting
from electron-phonon coupling involving a mode at meV and
most importantly the in-plane B-B vibration at
meV. The quasiparticles originating from - and -states couple
strongly to the low-frequency mode and the -vibrations respectively.
Using two-band Eliashberg theory, and , we calculate the gap functions (,
).
Our results provide an explanation of recent tunneling experiments.
We get .Comment: revised version, accepted for publication in PR
Nanoscale Mechanical Drumming Visualized by 4D Electron Microscopy
With four-dimensional (4D) electron microscopy, we report in situ imaging of the mechanical drumming of a nanoscale material. The single crystal graphite film is found to exhibit global resonance motion that is fully reversible and follows the same evolution after each initiating stress pulse. At early times, the motion appears âchaoticâ showing the different mechanical modes present over the micron scale. At longer time, the motion of the thin film collapses into a well-defined fundamental frequency of 1.08 MHz, a behavior reminiscent of mode locking; the mechanical motion damps out after âŒ200 ÎŒs and the oscillation has a âcavityâ quality factor of 150. The resonance time is determined by the stiffness of the material, and for the 75 nm thick and 40 ÎŒm square specimen used here we determined Youngâs modulus to be 1.0 TPa for the in-plane stressâstrain profile. Because of its real-time dimension, this 4D microscopy should have applications in the study of these and other types of materials structures
Simulation study of Non-ergodicity Transitions: Gelation in Colloidal Systems with Short Range Attractions
Computer simulations were used to study the gel transition occurring in
colloidal systems with short range attractions. A colloid-polymer mixture was
modelled and the results were compared with mode coupling theory expectations
and with the results for other systems (hard spheres and Lennard Jones). The
self-intermediate scattering function and the mean squared displacement were
used as the main dynamical quantities. Two different colloid packing fractions
have been studied. For the lower packing fraction, -scaling holds and
the wave-vector analysis of the correlation function shows that gelation is a
regular non-ergodicity transition within MCT. The leading mechanism for this
novel non-ergodicity transition is identified as bond formation caused by the
short range attraction. The time scale and diffusion coefficient also show
qualitatively the expected behaviour, although different exponents are found
for the power-law divergences of these two quantities. The non-Gaussian
parameter was also studied and very large correction to Gaussian behaviour
found. The system with higher colloid packing fraction shows indications of a
nearby high-order singularity, causing -scaling to fail, but the
general expectations for non-ergodicity transitions still hold.Comment: 13 pages, 15 figure
Anisotropic Local Stress and Particle Hopping in a Deeply Supercooled Liquid
The origin of the microscopic motions that lead to stress relaxation in
deeply supercooled liquid remains unclear. We show that in such a liquid the
stress relaxation is locally anisotropic which can serve as the driving force
for the hopping of the system on its free energy surface. However, not all
hopping are equally effective in relaxing the local stress, suggesting that
diffusion can decouple from viscosity even at local level. On the other hand,
orientational relaxation is found to be always coupled to stress relaxation.Comment: 4 pages, 3 figure
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