Dispersion strengthening in vanadium microalloyed steels processed by simulated thin slab casting and direct charging: Part I - Processing parameters, mechanical properties and microstructure

A study simulating thin slab continuous casting followed by direct charging into an equalisation furnace has been undertaken based on six low carbon (0.06wt-%) vanadium microalloyed steels. Mechanical and impact test data showed properties were similar or better than those obtained from similar microalloyed conventional thick cast as rolled slabs. The dispersion plus dislocation strengthening was estimated to be in the range 80-250MPa.A detailed TEM/EELS analysis of the dispersion sized sub-15nm particles showed that in all the steels, they were essentially nitrides with little crystalline carbon detected. In the Steels V-Nb, V-Ti and V-Nb-Ti, mixed transition metal nitrides were present. Modelling of equilibrium precipitates in these steels, based on a modified version of ChemSage, predicted that only vanadium rich nitrides would precipitate in austenite but that the C/N ratio would increase through the two phase field and in ferrite. The experimental analytical data clearly points to the thin slab direct charging process, which has substantially higher cooling rates than conventional casting, nucleating non-equilibrium particles in ferrite which are close to stoichiometric nitrides. These did not coarsen during the final stages of processing, but retained their highly stable average size of ~7nm resulting in substantial dispersion strengthening. The results are considered in conjunction with pertinent published literature

Centrifuge Health Monitoring of the 50gTon beam centrifuge at the University of Sheffield

In order to fully understand scientific test data it is crucial that we first understand the back-ground centrifuge operational environment and its variation with time and centrifugal acceleration. For exam-ple, changes in ambient air temperature or relative humidity in the centrifuge chamber during operation can have a significant impact on the evaporation levels of water from the surface of a clay model. It is vital to un-derstand these temporal changes in order to mitigate drying out of the soil surface as this would have a detrimental impact on model performance. This paper details the development of a centrifuge health monitoring system capable of measuring environmental parameters over natural seasonal variations of the laboratory environment but also during test conditions. The results of a series of preliminary tests of different duration, acceleration and configuration are discussed to demonstrate the significant changes that occur in the scientific environment during operation

From spin coating to roll-to-roll: investigating the challenge of upscaling lead halide perovskite solar cells

Spin coating, typically used to achieve nanometre thick films, is the established method for depositing perovskite precursors at lab scale for use in solar cells. This study investigates the dynamics of spin coating perovskite. By combining experimental measurement with a semi-empirical model the evaporation rate of the dimethylformamide solvent during the spin coating of a mixed lead halide precursor is determined to be 1.2 × 10 –8 m/s. When K-bar coating the same precursor the solvent does not significantly evaporate during the deposition process and when this film is crystallised on a hot plate a rough film results which gives a power conversion efficiency (PCE) of less than 2%. By increasing the airflow of the K-bar coated perovskite film during crystallisation to 2.7 × 10 –4 m/s the PCE increases significantly to 8.5% through an improvement in short-circuit current and fill factor

Playing to learn: Learning to TALK

‘We love the fact she can learn through play, because she is learning but not realising, and she doesn’t feel pressurised to learn’ (Parent of a child with neurodiverse developmental disorders [NDD]). Engaging children with NDD in meaningful learning can be challenging and exacerbated when children are neither motivated nor equipped with skills to facilitate engagement. Communication barriers hinder learning and children with NDD need extra support to develop language skills. This action research promoted communication competence through structured interventions, consolidated through play. Findings confirmed that progression in spontaneous communication and interaction interrelates with creative play. An innovative structured teaching approach, including video-modelling, was devised, Total Augmented Language and Key Skills (TALKS). This research affirms that by changing conditions in learning environments to an integrated teaching model, Connectivity and adopting TALKS, enhances a whole school approach to communication competence for children with NDD

The impact of deep-sea fisheries and implementation of the UNGA Resolutions 61/105 and 64/72. Report of an international scientific workshop

The scientific workshop to review fisheries management, held in Lisbon in May 2011, brought together 22 scientists and fisheries experts from around the world to consider the United Nations General Assembly (UNGA) resolutions on high seas bottom fisheries: what progress has been made and what the outstanding issues are. This report summarises the workshop conclusions, identifying examples of good practice and making recommendations in areas where it was agreed that the current management measures fall short of their target

Evolution of precipitates, in particular cruciform and cuboid particles, during simulated direct charging of thin slab cast vanadium microalloyed steels

A study has been undertaken of four vanadium based steels which have been processed by a simulated direct charging route using processing parameters typical of thin slab casting, where the cast product has a thickness of 50 to 80mm ( in this study 50 mm) and is fed directly to a furnace to equalise the microstructure prior to rolling. In the direct charging process, cooling rates are faster, equalisation times shorter and the amount of deformation introduced during rolling less than in conventional practice. Samples in this study were quenched after casting, after equalisation, after 4th rolling pass and after coiling, to follow the evolution of microstructure. The mechanical and toughness properties and the microstructural features might be expected to differ from equivalent steels, which have undergone conventional processing. The four low carbon steels (~0.06wt%) which were studied contained 0.1wt%V (V-N), 0.1wt%V and 0.010wt%Ti (V-Ti), 0.1wt%V and 0.03wt%Nb (V-Nb), and 0.1wt%V, 0.03wt%Nb and 0.007wt%Ti (V-Nb-Ti). Steels V-N and V-Ti contained around 0.02wt% N, while the other two contained about 0.01wt%N. The as-cast steels were heated at three equalising temperatures of 1050C, 1100C or 1200C and held for 30-60 minutes prior to rolling. Optical microscopy and analytical electron microscopy, including parallel electron energy loss spectroscopy (PEELS), were used to characterise the precipitates. In the as-cast condition, dendrites and plates were found. Cuboid particles were seen at this stage in Steel V-Ti, but they appeared only in the other steels after equalization. In addition, in the final product of all the steels, fine particles were seen, but it was only in the two titanium steels that cruciform precipitates were present. PEELS analysis showed that the dendrites, plates, cuboids, cruciforms and fine precipitates were essentially nitrides. The two Ti steels had better toughness than the other steels but inferior lower yield stress values. This was thought to be, in part, due to the formation of cruciform precipitates in austenite, thereby removing nitrogen and the microalloying elements which would have been expected to precipitate in ferrite as dispersion hardening particles

Navigating the emergence of brand meaning in service ecosystems

Purpose – The purpose of this paper is to clarify how brand meaning evolves as an emergent property through the cocreation processes of stakeholders on multiple levels of a brand’s service ecosystem. This provides new insight into the intersection between brands, consumers and society, and emphasizes the institutionally situated nature of brand meaning cocreation processes. It further lays a holistic foundation for a much-needed discussion on purpose-driven branding. Design/methodology/approach – Combining the ecosystem perspective of branding with the concept of social emergence allows clarification of brand meaning cocreation at different levels of aggregation. Emergence means collective phenomena – like social structures, concepts, preferences, states, mechanisms, laws and brand meaning – manifest from the interactions of individuals. Drawing on Sawyer’s (2005) social emergence perspective, the authors propose a processual multi-level framework to explore brand meaning emergence. Findings – Our framework spans five levels of brand meaning emergence: individual (e.g. employees and customers); interactional (e.g. where work teams or friend groups interact); relational (e.g. where internal and external actors meet); strategic (e.g. markets and strategic alliances); and systemic (e.g. regulators, NGOs and society). It acknowledges that brand positioning is an inherently co-creative process of negotiating value propositions and aligning behaviors and beliefs among broad sets of actors, as opposed to a firm-centric task. Originality/value – Service research has only recently embraced a macro–micro perspective of branding processes. This paper extends that perspective by paying attention to the nested service ecosystems in which brand meaning emerges and the degree to which this process can (and cannot) be navigated by individual actors.Jonathan J. Baker, Julia A. Fehrer, Roderick J. Brodi

Population overlap and habitat segregation in wintering Black-tailed Godwits Limosa limosa

Distinct breeding populations of migratory species may overlap both spatially and temporally, but differ in patterns of habitat use. This has important implications for population monitoring and conservation. To quantify the extent to which two distinct breeding populations of a migratory shorebird, the Black-tailed Godwit Limosa limosa, overlap spatially, temporally and in their use of different habitats during winter. We use mid-winter counts between 1990 and 2001 to identify the most important sites in Iberia for Black-tailed Godwits. Monthly surveys of estuarine mudflats and rice-fields at one major site, the Tejo estuary in Portugal in 2005-2007, together with detailed tracking of colour-ringed individuals, are used to explore patterns of habitat use and segregation of the Icelandic subspecies L. l. islandica and the nominate continental subspecies L. l. limosa. In the period 1990-2001, over 66 000 Black-tailed Godwits were counted on average in Iberia during mid-winter (January), of which 80% occurred at just four sites: Tejo and Sado lower basins in Portugal, and Coto Dontildeana and Ebro Delta in Spain. Icelandic Black-tailed Godwits are present throughout the winter and forage primarily in estuarine habitats. Continental Black-tailed Godwits are present from December to March and primarily use rice-fields. Iberia supports about 30% of the Icelandic population in winter and most of the continental population during spring passage. While the Icelandic population is currently increasing, the continental population is declining rapidly. Although the estuarine habitats used by Icelandic godwits are largely protected as Natura 2000 sites, the habitat segregation means that conservation actions for the decreasing numbers of continental godwits should focus on protection of rice-fields and re-establishment of freshwater wetlands