Branching Transport Model of Alkali-Halide Scintillators

We measure the time dependence of the scintillator light-emission pulses in NaI(Tl) crystals at different temperatures, after activation by gamma rays. We confirm that there are two main nonexponential components to the time decay and find that their amplitude ratio shows Arrhenius temperature dependence. We explain these nonexponential components as arising from two competing mechanisms of carrier transport to the Tl activation levels. The total light output of the NaI(Tl) detectors shows a linear temperature dependence explained by our model

Surface Adsorption Properties of Peptides Produced by Non-optimum pH Pepsinolysis of Proteins: A Combined Experimental and Self-Consistent-Field Calculation Study

Hypothesis Partial hydrolysis of large molecular weight (Mw), highly aggregated plant proteins is frequently used to improve their solubility. However, if this hydrolysis is extensive, random or nonselective, it is unlikely to improve functional properties such as surface activity, emulsion, or foam-stabilising capacity. Experiments and simulation Soy protein isolate (SPI) was hydrolysed by pepsin under optimal (pH 2.1) and non-optimal (pH 4.7) conditions. The surface activity and emulsion stabilising capacity of the resultant peptides were measured and compared. The colloidal interactions between a pair of emulsion droplets were modelled via Self-Consistent-Field Calculations (SCFC). Findings Hydrolysis at pH 2.1 and 4.7 resulted in a considerable increase in measured surface activity compared to the native (non-hydrolysed) SPI, but the hydrolysate from pH 2.1 was not as good an emulsion stabiliser as the hydrolysate (particularly the fraction Mw > 10 kDa) at pH 4.7. Furthermore, peptide analysis of the latter suggested it was dominated by a fragment of one of the major soy proteins β-conglycinin, with Mw ≈ 25 kDa. SCFC calculations confirmed that interactions mediated by adsorbed layers of this peptide point to it being an excellent emulsion stabiliser

The Effect of Radiation Pressure on the Equilibrium Points in the Generalised Photogravitational Restricted Three Body Problem

The existence of equilibrium points and the effect of radiation pressure have been discussed numerically. The problem is generalized by considering bigger primary as a source of radiation and small primary as an oblate spheroid. We have also discussed the Poynting-Robertson(P-R) effect which is caused due to radiation pressure. It is found that the collinear points $L_1,L_2,L_3$ deviate from the axis joining the two primaries, while the triangular points $L_4,L_5$ are not symmetrical due to radiation pressure. We have seen that $L_1,L_2,L_3$ are linearly unstable while $L_4,L_5$ are conditionally stable in the sense of Lyapunov when P-R effect is not considered. We have found that the effect of radiation pressure reduces the linear stability zones while P-R effect induces an instability in the sense of Lyapunov

Nonlinear Stability in the Generalised Photogravitational Restricted Three Body Problem with Poynting-Robertson Drag

The Nonlinear stability of triangular equilibrium points has been discussed in the generalised photogravitational restricted three body problem with Poynting-Robertson drag. The problem is generalised in the sense that smaller primary is supposed to be an oblate spheroid. The bigger primary is considered as radiating. We have performed first and second order normalization of the Hamiltonian of the problem. We have applied KAM theorem to examine the condition of non-linear stability. We have found three critical mass ratios. Finally we conclude that triangular points are stable in the nonlinear sense except three critical mass ratios at which KAM theorem fails.Comment: Including Poynting-Robertson Drag the triangular equilibrium points are stable in the nonlinear sense except three critical mass ratios at which KAM theorem fail

Fabrication and lubrication performance of sustainable Pickering‐like water‐in‐water emulsions using plant protein microgels

Aqueous multiphasic systems have attracted a great deal of interest recently owing to the growing demands of sustainability for the development of stable “oil-free” emulsions, often complicated by their limited stability against droplet coarsening. Although particles may provide ultrastability to water-in-water (W/W) emulsions formed in phase-separating polymer systems, the need for lubrication in such W/W emulsions presents an important challenge for their use in diverse applications. Herein, W/W Pickering emulsions were stabilized by sustainable plant protein (pea)-based microgels (PPM) using starch and xanthan gum as the biopolymers to generate the W/W phase separating droplet structures. The lubricity of these systems was compared with that of parallel systems stabilized by animal (whey) protein microgels (WPM). New results reveal that PPM are more soft and adhesive than WPM and outperform the latter in boundary lubrication performance, in striking contrast to the behavior of the non-microgelled pea or whey proteins. Furthermore, the PPM tend to stabilize a different, less spherical type of W/W droplet than the WPM that may explain the lower friction observed in PPM-stabilized systems. The novel approach of fabricating W/W emulsions stabilized by sustainable microgels opens up new solutions in designing aqueous lubricants for future nutritional and biomedical applications

Linear Stability of Triangular Equilibrium Points in the Generalized Photogravitational Restricted Three Body Problem with Poynting-Robertson Drag

In this paper we have examined the linear stability of triangular equilibrium points in the generalised photogravitational restricted three body problem with Poynting-Robertson drag. We have found the position of triangular equilibrium points of our problem. The problem is generalised in the sense that smaller primary is supposed to be an oblate spheroid. The bigger primary is considered as radiating. The equations of motion are affected by radiation pressure force, oblateness and P-R drag. All classical results involving photogravitational and oblateness in restricted three body problem may be verified from this result. With the help of characteristic equation, we discussed the stability. Finally we conclude that triangular equilibrium points are unstable.Comment: accepted for publication in Journal of Dynamical Systems & Geometric Theories Vol. 4, Number 1 (2006

Geochemical analysis of bulk marine sediment by Inductively Coupled Plasma–Atomic Emission Spectroscopy on board the JOIDES Resolution

Geochemical analyses on board the JOIDES Resolution have been enhanced with the addition of a Jobin-Yvon Ultrace inductively coupled plasma-atomic emission spectrometer (ICP-AES) as an upgrade from the previous X-ray fluorescence facility. During Leg 199, we sought to both challenge and utilize the capabilities of the ICP-AES in order to provide an extensive bulk-sediment geochemical database during the cruise. These near real-time analyses were then used to help characterize the recovered sedimentary sequences, calculate mass accumulation rates of the different sedimentary components, and assist with cruise and postcruise sampling requests. The general procedures, sample preparation techniques, and basic protocol for ICP-AES analyses on board ship are outlined by Murray et al. (2000) in Ocean Drilling Program Tech Note, 29. We expand on those concepts and offer suggestions for ICP-AES methodology, calibration by standard reference materials, data reduction procedures, and challenges that are specific to the analysis of bulk-sediment samples. During Leg 199, we employed an extensive bulk-sediment analytical program of ~600 samples of varying lithologies, thereby providing several opportunities for refinement of techniques. We also discuss some difficulties and challenges that were faced and suggest how to alleviate such occurrences for sedimentary chemical analyses during future legs

Heat kernel regularization of the effective action for stochastic reaction-diffusion equations

The presence of fluctuations and non-linear interactions can lead to scale dependence in the parameters appearing in stochastic differential equations. Stochastic dynamics can be formulated in terms of functional integrals. In this paper we apply the heat kernel method to study the short distance renormalizability of a stochastic (polynomial) reaction-diffusion equation with real additive noise. We calculate the one-loop {\emph{effective action}} and its ultraviolet scale dependent divergences. We show that for white noise a polynomial reaction-diffusion equation is one-loop {\emph{finite}} in $d=0$ and $d=1$, and is one-loop renormalizable in $d=2$ and $d=3$ space dimensions. We obtain the one-loop renormalization group equations and find they run with scale only in $d=2$.Comment: 21 pages, uses ReV-TeX 3.

Electronic structure, phase stability and chemical bonding in Th2_2Al and Th2_2AlH4_4

We present the results of theoretical investigation on the electronic structure, bonding nature and ground state properties of Th$_2$Al and Th$_2$AlH$_4$ using generalized-gradient-corrected first-principles full-potential density-functional calculations. Th$_2$AlH$_4$ has been reported to violate the "2 \AA rule" of H-H separation in hydrides. From our total energy as well as force-minimization calculations, we found a shortest H-H separation of 1.95 {\AA} in accordance with recent high resolution powder neutron diffraction experiments. When the Th$_2$Al matrix is hydrogenated, the volume expansion is highly anisotropic, which is quite opposite to other hydrides having the same crystal structure. The bonding nature of these materials are analyzed from the density of states, crystal-orbital Hamiltonian population and valence-charge-density analyses. Our calculation predicts different nature of bonding for the H atoms along $a$ and $c$. The strongest bonding in Th$_2$AlH$_4$ is between Th and H along $c$ which form dumb-bell shaped H-Th-H subunits. Due to this strong covalent interaction there is very small amount of electrons present between H atoms along $c$ which makes repulsive interaction between the H atoms smaller and this is the precise reason why the 2 {\AA} rule is violated. The large difference in the interatomic distances between the interstitial region where one can accommodate H in the $ac$ and $ab$ planes along with the strong covalent interaction between Th and H are the main reasons for highly anisotropic volume expansion on hydrogenation of Th$_2$Al.Comment: 14 pages, 9 figure