19 research outputs found
Synchrotron radiation from a charge moving along a helical orbit inside a dielectric cylinder
The radiation emitted by a charged particle moving along a helical orbit
inside a dielectric cylinder immersed into a homogeneous medium is
investigated. Expressions are derived for the electromagnetic potentials,
electric and magnetic fields, and for the spectral-angular distribution of
radiation in the exterior medium. It is shown that under the Cherenkov
condition for dielectric permittivity of the cylinder and the velocity of the
particle image on the cylinder surface, strong narrow peaks are present in the
angular distribution for the number of radiated quanta. At these peaks the
radiated energy exceeds the corresponding quantity for a homogeneous medium by
some orders of magnitude. The results of numerical calculations for the angular
distribution of radiated quanta are presented and they are compared with the
corresponding quantities for radiation in a homogeneous medium. The special
case of relativistic charged particle motion along the direction of the
cylinder axis with non-relativistic transverse velocity (helical undulator) is
considered in detail. Various regimes for the undulator parameter are
discussed. It is shown that the presence of the cylinder can increase
essentially the radiation intensity.Comment: 18 pages, 8 EPS figure
Multipole electron-density modelling of synchrotron powder diffraction data: the case of diamond
International audienceAccurate structure factors are extracted from synchrotron powder diffraction data measured on crystalline diamond based on a novel multipole model division of overlapping reflection intensities. The approach limits the spherical-atom bias in structure factors extracted from overlapping powder data using conventional spherical-atom Rietveld refinement. The structure factors are subsequently used for multipole electron-density modelling, and both the structure factors and the derived density are compared with results from ab initio theoretical calculations. Overall, excellent agreement is obtained between experiment and theory, and the study therefore demonstrates that synchrotron powder diffraction can indeed provide accurate structure-factor values based on data measured in minutes with limited sample preparation. Thus, potential systematic errors such as extinction and twinning commonly encountered in single-crystal studies of small-unit-cell inorganic structures can be overcome with synchrotron powder diffraction. It is shown that the standard Hansen-Coppens multipole model is not flexible enough to fit the static theoretical structure factors, whereas fitting of thermally smeared structure factors has much lower residuals. If thermally smeared structure factors (experimental or theoretical) are fitted with a slightly wrong radial model (s2p2 instead of sp3) the radial scaling parameters ('[kappa]' parameters) are found to be inadequate and the 'error' is absorbed into the atomic displacement parameter. This directly exposes a correlation between electron density and thermal parameters even for a light atom such as carbon, and it also underlines that in organic systems proper deconvolution of thermal motion is important for obtaining correct static electron densities