81 research outputs found
Sulfur-Directed Olefin Oxidations: Observation of Divergent Reaction Mechanisms in the Palladium-Mediated Acetoxylation of Unsaturated Thioacetals
The Pd-mediated oxidation of unsaturated thioacetals gives either allyl or vinyl esters, depending on the substrate structure. We report the characterization of a range of sulfur-stabilized palladium intermediates via a combined computational and experimental NMR approach, demonstrating that the oxidation proceeds via two divergent reaction mechanisms. We were also able to synthesize an unusual sigma-bound Pd complex, via acetoxypalladation of an unsaturated dithiane, which was characterized by X-ray crystallography
Research and teaching in Civil Engineering 1991/92 - 1992/93
Godkänd; 1992; 20160516 (elfgren)</p
Institutionen för Anläggningsteknik - Verksamhetsberättelse 1985/86
Godkänd; 1986; 20160516 (elfgren
Institutionen för Anläggningsteknik. Verksamhetsberättelse 1986/87
Godkänd; 1987; 20160516 (elfgren
Research and teaching in Civil Engineering 1991/92 - 1992/93
Godkänd; 1992; 20160516 (elfgren)</p
Institutionen för Anläggningsteknik. Verksamhetsberättelse 1987/88
Godkänd; 1988; 20160516 (elfgren
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