4,143 research outputs found
Binding branched and linear DNA structures: from isolated clusters to fully bonded gels
The proper design of DNA sequences allows for the formation of well defined
supramolecular units with controlled interactions via a consecution of
self-assembling processes. Here, we benefit from the controlled DNA
self-assembly to experimentally realize particles with well defined valence,
namely tetravalent nanostars (A) and bivalent chains (B). We specifically focus
on the case in which A particles can only bind to B particles, via
appropriately designed sticky-end sequences. Hence AA and BB bonds are not
allowed. Such a binary mixture system reproduces with DNA-based particles the
physics of poly-functional condensation, with an exquisite control over the
bonding process, tuned by the ratio, r, between B and A units and by the
temperature, T. We report dynamic light scattering experiments in a window of
Ts ranging from 10{\deg}C to 55{\deg}C and an interval of r around the
percolation transition to quantify the decay of the density correlation for the
different cases. At low T, when all possible bonds are formed, the system
behaves as a fully bonded network, as a percolating gel and as a cluster fluid
depending on the selected r.Comment: 15 pages, 11 figure
Shear flow effects on phase separation of entangled polymer blends
We introduce an entanglement model mixing rule for stress relaxation in a polymer blend to a modified Cahn-Hilliard equation of motion for concentration fluctuations in the presence of shear flow. Such an approach predicts both shear-induced mixing and demixing, depending on the relative relaxation times and plateau moduli of the two components
Dynamic crossover scaling in polymer solutions
The crossover region in the phase diagram of polymer solutions, in the regime
above the overlap concentration, is explored by Brownian Dynamics simulations,
to map out the universal crossover scaling functions for the gyration radius
and the single-chain diffusion constant. Scaling considerations, our simulation
results, and recently reported data on the polymer contribution to the
viscosity obtained from rheological measurements on DNA systems, support the
assumption that there are simple relations between these functions, such that
they can be inferred from one another.Comment: 4 pages, 6 figures, 1 Table. Revised version to appear in Physical
Review Letters. Includes supplemental material
Random walk approach to the d-dimensional disordered Lorentz gas
A correlated random walk approach to diffusion is applied to the disordered
nonoverlapping Lorentz gas. By invoking the Lu-Torquato theory for chord-length
distributions in random media [J. Chem. Phys. 98, 6472 (1993)], an analytic
expression for the diffusion constant in arbitrary number of dimensions d is
obtained. The result corresponds to an Enskog-like correction to the Boltzmann
prediction, being exact in the dilute limit, and better or nearly exact in
comparison to renormalized kinetic theory predictions for all allowed densities
in d=2,3. Extensive numerical simulations were also performed to elucidate the
role of the approximations involved.Comment: 5 pages, 5 figure
Polymer translocation out of confined environments
We consider the dynamics of polymer translocation out of confined
environments. Analytic scaling arguments lead to the prediction that the
translocation time scales like for translocation out of a planar
confinement between two walls with separation into a 3D environment, and
for translocation out of two strips with separation
into a 2D environment. Here, is the chain length, and
are the Flory exponents in 3D and 2D, and is the scaling exponent of
translocation velocity with , whose value for the present choice of
parameters is based on Langevin dynamics simulations. These
scaling exponents improve on earlier predictions.Comment: 5 pages, 5 figures. To appear in Phys. Rev.
Scattering solutions in a network of thin fibers: small diameter asymptotics
Small diameter asymptotics is obtained for scattering solutions in a network
of thin fibers. The asymptotics is expressed in terms of solutions of related
problems on the limiting quantum graph. We calculate the Lagrangian gluing
conditions at vertices for the problems on the limiting graph. If the frequency
of the incident wave is above the bottom of the absolutely continuous spectrum,
the gluing conditions are formulated in terms of the scattering data for each
individual junction of the network
Role of friction-induced torque in stick-slip motion
We present a minimal quasistatic 1D model describing the kinematics of the
transition from static friction to stick-slip motion of a linear elastic block
on a rigid plane. We show how the kinematics of both the precursors to
frictional sliding and the periodic stick-slip motion are controlled by the
amount of friction-induced torque at the interface. Our model provides a
general framework to understand and relate a series of recent experimental
observations, in particular the nucleation location of micro-slip instabilities
and the build up of an asymmetric field of real contact area.Comment: 6 pages, 5 figure
Boundary conditions associated with the Painlev\'e III' and V evaluations of some random matrix averages
In a previous work a random matrix average for the Laguerre unitary ensemble,
generalising the generating function for the probability that an interval at the hard edge contains eigenvalues, was evaluated in terms of
a Painlev\'e V transcendent in -form. However the boundary conditions
for the corresponding differential equation were not specified for the full
parameter space. Here this task is accomplished in general, and the obtained
functional form is compared against the most general small behaviour of
the Painlev\'e V equation in -form known from the work of Jimbo. An
analogous study is carried out for the the hard edge scaling limit of the
random matrix average, which we have previously evaluated in terms of a
Painlev\'e \IIId transcendent in -form. An application of the latter
result is given to the rapid evaluation of a Hankel determinant appearing in a
recent work of Conrey, Rubinstein and Snaith relating to the derivative of the
Riemann zeta function
Effects of differential mobility on biased diffusion of two species
Using simulations and a simple mean-field theory, we investigate jamming
transitions in a two-species lattice gas under non-equilibrium steady-state
conditions. The two types of particles diffuse with different mobilities on a
square lattice, subject to an excluded volume constraint and biased in opposite
directions. Varying filling fraction, differential mobility, and drive, we map
out the phase diagram, identifying first order and continuous transitions
between a free-flowing disordered and a spatially inhomogeneous jammed phase.
Ordered structures are observed to drift, with a characteristic velocity, in
the direction of the more mobile species.Comment: 15 pages, 4 figure
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