Low temperature phase diagram and critical behaviour of the four-state chiral clock model

The low temperature behaviour of the four-state chiral clock ($CC_4$) model is reexamined using a systematic low temperature series expansion of the free energy. Previously obtained results for the low temperature phases are corrected and the low temperature phase diagram is derived. In addition, the phase transition from the modulated region to the high temperature paraphase is shown to belong to the universality class of the 3d-XY model.Comment: 17 pages in ioplppt style, 3 figure

A Bayesian framework for verification and recalibration of ensemble forecasts: How uncertain is NAO predictability?

Predictability estimates of ensemble prediction systems are uncertain due to limited numbers of past forecasts and observations. To account for such uncertainty, this paper proposes a Bayesian inferential framework that provides a simple 6-parameter representation of ensemble forecasting systems and the corresponding observations. The framework is probabilistic, and thus allows for quantifying uncertainty in predictability measures such as correlation skill and signal-to-noise ratios. It also provides a natural way to produce recalibrated probabilistic predictions from uncalibrated ensembles forecasts. The framework is used to address important questions concerning the skill of winter hindcasts of the North Atlantic Oscillation for 1992-2011 issued by the Met Office GloSea5 climate prediction system. Although there is much uncertainty in the correlation between ensemble mean and observations, there is strong evidence of skill: the 95% credible interval of the correlation coefficient of [0.19,0.68] does not overlap zero. There is also strong evidence that the forecasts are not exchangeable with the observations: With over 99% certainty, the signal-to-noise ratio of the forecasts is smaller than the signal-to-noise ratio of the observations, which suggests that raw forecasts should not be taken as representative scenarios of the observations. Forecast recalibration is thus required, which can be coherently addressed within the proposed framework.Comment: 36 pages, 10 figure

Strong Resonance of Light in a Cantor Set

The propagation of an electromagnetic wave in a one-dimensional fractal object, the Cantor set, is studied. The transfer matrix of the wave amplitude is formulated and its renormalization transformation is analyzed. The focus is on resonant states in the Cantor set. In Cantor sets of higher generations, some of the resonant states closely approach the real axis of the wave number, leaving between them a wide region free of resonant states. As a result, wide regions of nearly total reflection appear with sharp peaks of the transmission coefficient beside them. It is also revealed that the electromagnetic wave is strongly enhanced and localized in the cavity of the Cantor set near the resonant frequency. The enhancement factor of the wave amplitude at the resonant frequency is approximately $6/|\eta_\mathrm{r}|$, where $\eta_\mathrm{r}$ is the imaginary part of the corresponding resonant eigenvalue. For example, a resonant state of the lifetime $\tau_\mathrm{r}=4.3$ms and of the enhancement factor $M=7.8\times10^7$ is found at the resonant frequency $\omega_\mathrm{r}=367$GHz for the Cantor set of the fourth generation of length L=10cm made of a medium of the dielectric constant $\epsilon=10$.Comment: 20 pages, 11 figures, to be published in Journal of the Physical Society of Japa

Localization of shadow poles by complex scaling

Through numerical examples we show that the complex scaling method is suited to explore the pole structure in multichannel scattering problems. All poles lying on the multisheeted Riemann energy surface, including shadow poles, can be revealed and the Riemann sheets on which they reside can be identified.Comment: 6 pages, Latex with Revtex, 3 figures (not included) available on reques

An orthogonal biocatalytic approach for the safe generation and use of HCN in a multistep continuous preparation of chiral O-acetylcyanohydrins

An enantioselective preparation of O-acetylcyanohydrins has been accomplished by a three-step telescoped continuous process. The modular components enabled accurate control of two sequential biotransformations, safe handling of an in situ generated hazardous gas, and in-line stabilization of products. This method proved to be advantageous over the batch protocols in terms of reaction time (40 vs 345 min) and ease of operation, opening up access to reactions which have often been neglected due to safety concerns.We gratefully acknowledge the Deutsche Forschungsgemeinschaft (DFG) within the research training group GRK 1166 “Biocatalysis in non-conventional media (BioNoCo)”, and the EPSRC (Award Nos. EP/K009494/1 and EP/K039520/1)This is the final version of the article. It first appeared from Georg Thieme Verlag KG via http://dx.doi.org/10.1055/s-0035-156064

Anisotropic Coarsening: Grain Shapes and Nonuniversal Persistence

We solve a coarsening system with small but arbitrary anisotropic surface tension and interface mobility. The resulting size-dependent growth shapes are significantly different from equilibrium microcrystallites, and have a distribution of grain sizes different from isotropic theories. As an application of our results, we show that the persistence decay exponent depends on anisotropy and hence is nonuniversal.Comment: 4 pages (revtex), 2 eps figure

Hadronic Parity Violation and Inelastic Electron-Deuteron Scattering

We compute contributions to the parity-violating (PV) inelastic electron-deuteron scattering asymmetry arising from hadronic PV. While hadronic PV effects can be relatively important in PV threshold electro- disintegration, we find that they are highly suppressed at quasielastic kinematics. The interpretation of the PV quasielastic asymmetry is, thus, largely unaffected by hadronic PV.Comment: 27 pages, 13 figures, uses REVTeX and BibTe

Mobility promotes and jeopardizes biodiversity in rock-paper-scissors games

Biodiversity is essential to the viability of ecological systems. Species diversity in ecosystems is promoted by cyclic, non-hierarchical interactions among competing populations. Such non-transitive relations lead to an evolution with central features represented by the `rock-paper-scissors' game, where rock crushes scissors, scissors cut paper, and paper wraps rock. In combination with spatial dispersal of static populations, this type of competition results in the stable coexistence of all species and the long-term maintenance of biodiversity. However, population mobility is a central feature of real ecosystems: animals migrate, bacteria run and tumble. Here, we observe a critical influence of mobility on species diversity. When mobility exceeds a certain value, biodiversity is jeopardized and lost. In contrast, below this critical threshold all subpopulations coexist and an entanglement of travelling spiral waves forms in the course of temporal evolution. We establish that this phenomenon is robust, it does not depend on the details of cyclic competition or spatial environment. These findings have important implications for maintenance and evolution of ecological systems and are relevant for the formation and propagation of patterns in excitable media, such as chemical kinetics or epidemic outbreaks.Comment: Final submitted version; the printed version can be found at http://dx.doi.org/10.1038/nature06095 Supplementary movies are available at http://www.theorie.physik.uni-muenchen.de/lsfrey/images_content/movie1.AVI and http://www.theorie.physik.uni-muenchen.de/lsfrey/images_content/movie2.AV

Canonical Solution of Classical Magnetic Models with Long-Range Couplings

We study the canonical solution of a family of classical $n-vector$ spin models on a generic $d$-dimensional lattice; the couplings between two spins decay as the inverse of their distance raised to the power $\alpha$, with $\alpha<d$. The control of the thermodynamic limit requires the introduction of a rescaling factor in the potential energy, which makes the model extensive but not additive. A detailed analysis of the asymptotic spectral properties of the matrix of couplings was necessary to justify the saddle point method applied to the integration of functions depending on a diverging number of variables. The properties of a class of functions related to the modified Bessel functions had to be investigated. For given $n$, and for any $\alpha$, $d$ and lattice geometry, the solution is equivalent to that of the $\alpha=0$ model, where the dimensionality $d$ and the geometry of the lattice are irrelevant.Comment: Submitted for publication in Journal of Statistical Physic