Angle-resolved photoelectron spectrometry studies of the autoionization of the 2s22p 2P triply excited state of atomic lithium: experimental results and R-matrix calculations

We have measured the angle-resolved energy dependence of the electrons emitted over the energy range of the triply excited 2s22p2P lithium resonance using synchrotron radiation. We have also calculated the behavior of the angular distribution parameter β using the R-matrix approximation. Experimental and theoretical results are in good agreement and show deep minima in the 1s2p1,3P ionic channels. The energy at which the minima occur does not coincide with the resonance energy, but is shifted towards higher energy

Trends in autoionization of Rydberg states converging to the 4s threshold in the Kr-Rb⁺-Sr²⁺ isoelectonic sequence: theory and experiment

We have measured the photoabsorption spectra of the Kr-like ions Rb+ and Sr2+ at photon energies corresponding to the excitation of 4s-np resonances using, the dual laser plasma photoabsorption technique. Dramatic changes in the line profiles, with increasing ionization and also proceeding along the Rydberg series of each ion, are observed and explained by the trends in 4s-transition amplitudes computed within a framework of configuration-interaction Pauli-Fock calculations. Total photoionization cross sections show very good agreement with relative absorption data extracted from the measured spectra

High resolution measurements of partial photoionization cross sections in hollow lithium: a critical comparison with advanced many-body calculations

Photoelectron data for hollow lithium states obtained with unprecedented high spectral resolution and sensitivity are presented. A critical comparison is made with the most recent theoretical results. Partial cross sections are measured providing the first definitive test of advanced ab initio calculations for this highly excited four-body atomic system

Triple differential cross section of rare gas atoms in different low energy kinematics

Triple differential cross sections have been measured for the electron-impact ionization of rare gases in two coplanar geometries. Results are presented for 20 eV excess energy with respect to ionization threshold for ionization of helium, neon and argon. These enable us to investigate the target dependence of triple differential cross section angular-distributions. For ionization of helium, we compare our absolute measurements with the convergent close coupling calculations whereas, for ionization of neon and argon, the comparison is made with the distorted wave Born approximation calculations. Additional measurements carried out on argon near threshold are also presented

Stability of ZnMgO oxide in a weak alkaline solution

International audienceZinc oxide (ZnO) is a chemical compound of great interest used, for example, as photocatalyst in the purification of wastewater or polluted air. However, neither dissolution, nor photo-dissolution of ZnO is negligible: indeed, both processes reduce significantly the efficiency of photocatalysis and then lead to a secondary pollution by free Zn2+ . In the present study, the stability of ZnMgO thin films in weak alkaline solution is investigated. We demonstrates that the replacement of Zn2+ ion with Mg2+ ion results in the production of a Zn0.84Mg0.16O solid solution, whose stability is higher than that of the ZnO sample. This alloy, thus, constitutes an alternative to the use of ZnO in photocatalysis applications. To gain more insights into the higher resistance of such alloys to the dissolution process, X-Ray photoelectron spectroscopy measurements were performed. They highlighted the role of OH group adsorption in the experimentally observed enhancement of ZnMgO stability

Stability of ZnMgO oxide in a weak alkaline solution

International audienceZinc oxide (ZnO) is a chemical compound of great interest used, for example, as photocatalyst in the purification of wastewater or polluted air. However, neither dissolution, nor photo-dissolution of ZnO is negligible: indeed, both processes reduce significantly the efficiency of photocatalysis and then lead to a secondary pollution by free Zn2+ . In the present study, the stability of ZnMgO thin films in weak alkaline solution is investigated. We demonstrates that the replacement of Zn2+ ion with Mg2+ ion results in the production of a Zn0.84Mg0.16O solid solution, whose stability is higher than that of the ZnO sample. This alloy, thus, constitutes an alternative to the use of ZnO in photocatalysis applications. To gain more insights into the higher resistance of such alloys to the dissolution process, X-Ray photoelectron spectroscopy measurements were performed. They highlighted the role of OH group adsorption in the experimentally observed enhancement of ZnMgO stability

Angle-dependent postcollisional interaction and interference effects in resonant double photoionization of neon RID G-7348-2011

The resonant double photoionization of Ne has been studied via an electron-electron coincidence experiment. A complete set of measurements was performed at different mutual angles when the photoelectron and Auger-electron pairs have nearly equal energy. The overall experimental energy resolution, narrower than the natural linewidth of the intermediate state, has allowed us to observe interference effects due to the indistinguishability of the two electrons. The observed energy and angular distribution exhibit a strong interplay of postcollisional interaction and interference effects. Calculations based on the model developed by Sheinerman and Schmidt [J. Phys. B 30, 1677 (1997)] describe the main trend of the experimental observations

Study of the magnetization behavior of ferromagnetic nanowire array: Existence of growth defects revealed by micromagnetic simulations

International audienceHigh aspect ratio nanowires were electrodeposited in nanoporous anodic alumina template by a potentiostatic method. The angular dependence of the coercive field and remanence magnetization extracted from magnetometry measurements are compared with micromagnetic simulations. Inclusion of magnetostatic interactions between Ni nanowires in simulations is required to explain some of the properties of the magnetization reversal. However, it is not sufficient to reproduce fully the angular dependence of the coercive field. Due to the polycrystalline nature of nanowires and thus to the presence of grain boundaries, defects are included in simulations. A good agreement between theory and experiment is then clearly highlighted, in particular in the nanowire easy axis direction. The achieved results allow a description of several experimental data published in the literature and consequently to get a better understanding of reversal mechanisms that operate in such nanowire arrays. A complementary study of composite nanowire array is successfully performed to prove the adequacy of the simulations method to describe the magnetic properties of nanowire array