3,344 research outputs found

    Near-infrared polarimetric observations of the afterglow of GRB 000301C

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    Based on near-infrared polarimetric observations we constrain the degree of linear polarization of the afterglow light of GRB 000301C to less than 30% 1.8 days after the burst.Comment: To appear in: Proc. 20th Texas Symposium on Relativistic Astrophysics, eds. J. C. Wheeler and H. Marte

    Mid-infrared observations of the SGR 1900+14 error box

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    We report on mid-infrared observations of the compact stellar cluster located in the proximity of SGR 1900+14, and the radio/X-ray position of this soft-gamma repeater. Observations were performed in May and June of 2001 when the bursting source was in an active state. At the known radio and X-ray position of the SGR we did not detect transient mid-IR activity, although the observations were performed only hours before and after an outburst in the high-energy band.Comment: 4 pages, 3 figures, to appear in "Gamma-Ray Burst and Afterglow Astronomy 2001", Woods Hole; 5-9 Nov, 200

    In Situ Diffuse Reflectance IR Spectroscopic Investigation of n-Butane Isomerization on Promoted Sulfated Zirconia Catalysts

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    Introduction Sulfated zirconia (SZ) is an attractive catalyst for low temperature butane isomerization [1]. Its activity can be improved by 1–2 orders of magnitude through addition of promoters such as iron or manganese in cationic form [2,3]. The state of these promoters has been characterized, and depending on the method of preparation, a major fraction is found to form a solid solution with zirconia [4]. It has been proposed that promoters facilitate reaction initiation via oxidative dehydrogenation to butenes, which may be converted into the reaction carriers, viz. carbenium ions. Only indirect evidence such as better activity after activation in oxidizing than in inert atmosphere has been presented [5]. Reaction profiles recorded under moderate reaction conditions (e.g. 323 K, 1 kPa n-butane) show an induction period and zero conversion in the extrapolation to zero time on stream. Either the catalyst becomes active only in the feed, or intermediates accumulate on the surface. We have focused on manganese as a promoter and have used in situ diffuse reflectance IR spectroscopy (DRIFTS) to reveal the effects of activation or regeneration in inert gas or O2, and to monitor the events during the induction period. References 1. Hino, M., Arata, K., J. Am. Chem. Soc. 101, 6439 (1979). 2. Hsu, C.-Y., Heimbuch, C.R., Armes, C.T., Gates, B.C., Chem. Commun. 1645 (1992). 3. Lange, F.C., Cheung, T.-K., Gates, B.C., Catal. Lett. 41, 95 (1996). 4. Jentoft, F.C., Hahn, A., Kröhnert, J., Lorenz, G., Jentoft, R.E., Ressler, T., Wild, U., Schlögl, R., J. Catal. 224, 124 (2004). 5. Wan, K.T., Khouw, C.B., Davis, M.E., J. Catal. 158, 311 (1996)

    The Balance Between Reactivity and Stability of Modified Oxide Surfaces Illustrated by the Behavior of Sulfated Zirconia Catalysts

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    The stability of a series of sulfated zirconia catalysts, promoted with up to 2 wt% iron or manganese, in their calcined state was investigated. Phase composition, nature of surface sulfate species, degree of hydroxylation, and butane isomerization activity changed during aging over months in various atmospheres and during milling. The metastability of small oxide particles is discussed, including literature data on alumina, titania and other oxides. Catalytically active fractions of a material easily transition into more stable, less active forms

    On the Hopf algebra structure of the AdS/CFT S-matrix

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    We formulate the Hopf algebra underlying the su(2|2) worldsheet S-matrix of the AdS_5 x S^5 string in the AdS/CFT correspondence. For this we extend the previous construction in the su(1|2) subsector due to Janik to the full algebra by specifying the action of the coproduct and the antipode on the remaining generators. The nontriviality of the coproduct is determined by length-changing effects and results in an unusual central braiding. As an application we explicitly determine the antiparticle representation by means of the established antipode.Comment: 12 pages, no figures, minor changes, typos corrected, comments and references added, v3: three references adde
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