276 research outputs found
Single-photon single ionization of W ions: experiment and theory
Experimental and theoretical results are reported for photoionization of
Ta-like (W) tungsten ions. Absolute cross sections were measured in the
energy range 16 to 245 eV employing the photon-ion merged-beam setup at the
Advanced Light Source in Berkeley. Detailed photon-energy scans at 100 meV
bandwidth were performed in the 16 to 108 eV range. In addition, the cross
section was scanned at 50 meV resolution in regions where fine resonance
structures could be observed. Theoretical results were obtained from a
Dirac-Coulomb R-matrix approach. Photoionization cross section calculations
were performed for singly ionized atomic tungsten ions in their , =1/2, ground level and the associated
excited metastable levels with =3/2, 5/2, 7/2 and 9/2. Since the ion beams
used in the experiments must be expected to contain long-lived excited states
also from excited configurations, additional cross-section calculations were
performed for the second-lowest term, 5d^5 \; ^6{\rm S}_{J}, =5/2, and for
the F term, 5d^3 6s^2 \; ^4{\rm F}_{J}, with = 3/2, 5/2, 7/2 and 9/2.
Given the complexity of the electronic structure of W the calculations
reproduce the main features of the experimental cross section quite well.Comment: 23 pages, 7 figures, 1 table: Accepted for publication in J. Phys. B:
At. Mol. & Opt. Phy
High-resolution C 1s photoelectron spectra of methane
The C 1s partial photoionization cross section and photoelectron angular distribution of methane (CH4) have been measured with high-energy resolution between threshold and 385 eV photon energy. From the analysis of the vibrational fine structure on the C 1sâ1 photoelectron line a vibrational energy of 396±2 meV and an equilibrium bond length of 1.039(±0.001) Ă
for the CH+4 ion have been determined. The lifetime broadening was found to be 83(±10) meV. The weak feature in the photoabsorption cross section just above threshold does not influence the vibrational fine structure in a way typical for a shape resonance. We therefore suggest that it is due to doubly excited states of the type C (1s)â1(Val)â1(Ryd)1a(Ryd)1b, an assignment which is supported by recent Auger decay studies. Measurements of the shakeup structure revealed six satellite lines, one of which increases strongly in intensity at threshold, thus pointing to the existence of a conjugate shakeup process
Crystallographic and magnetic identification of secondary phase in orientated Bi5Fe0.5Co0.5Ti3O15 ceramics
Oxide materials which exhibit both ferroelectricity
and ferromagnetism are of great interest for sensors and memory
applications. Layered bismuth titanates with an Aurivillius
structure, (BiFeO3)nBi4Ti3O12, can possess ferroelectric and
ferromagnetic order parameters simultaneously. It has recently
been demonstrated that one such example,
Bi5Fe0.5Co0.5Ti3O15,where n = 1 with half the Fe3+ sites substituted
by Co3+ ions, exhibits both ferroelectric and ferromagnetic
properties at room temperature. Here we report the fabrication
of highly-oriented polycrystalline ceramics of this material,
prepared via molten salt synthesis and uniaxial pressing of high
aspect ratio platelets. Electron backscatter images showed that
there is a secondary phase within the ceramic matrix which is
rich in cobalt and iron, hence this secondary phase could
contribute in the main phase ferromagnetic property. The
concentration of the secondary phase obtained from secondary
electron microscopy is estimated at less than 2.5 %, below the
detection limit of XRD. TEM was used to identify the
crystallographic structure of the secondary phase, which was
shown to be cobalt ferrite, CoFe2O4. It is inferred from the data
that the resultant ferromagnetic response identified using VSM
measurements was due to the presence of the minor secondary
phase. The Remanent magnetization at room temperature was
Mr â 76 memu/g which dropped down to almost zero (Mr â 0.8
memu/g) at 460 oC, far lower than the anticipated for CoFe2O4
Signatures of Spin Glass Freezing in NiO Nanoparticles
We present a detailed study of the magnetic properties of sol-gel prepared
nickel oxide nanoparticles of different sizes. We report various measurements
such as frequency, field and temperature dependence of ac susceptibility,
temperature and field dependence of dc magnetization and time decay of
thermoremanent magnetization. Our results and analysis show that the system
behaves as a spin glass.Comment: 8 pages, 9 figure
Simultaneous ambient pressure X-ray photoelectron spectroscopy and grazing incidence X-ray scattering in gas environments
We have developed an experimental system to simultaneously observe surface
structure, morphology, composition, chemical state, and chemical activity for
samples in gas phase environments. This is accomplished by simultaneously
measuring X-ray photoelectron spectroscopy (XPS) and grazing incidence X-ray
scattering (GIXS) in gas pressures as high as the multi-Torr regime, while also
recording mass spectrometry. Scattering patterns reflect near-surface sample
structures from the nano- to the meso-scale. The grazing incidence geometry
provides tunable depth sensitivity while scattered X-rays are detected across a
broad range of angles using a newly designed pivoting-UHV-manipulator for
detector positioning. At the same time, XPS and mass spectrometry can be
measured, all from the same sample spot and in ambient conditions. To
demonstrate the capabilities of this system, we measured the chemical state,
composition, and structure of Ag-behenate on a Si(001) wafer in vacuum and in
O atmosphere at various temperatures. These simultaneous structural,
chemical, and gas phase product probes enable detailed insights into the
interplay between structure and chemical state for samples in gas phase
environments. The compact size of our pivoting-UHV-manipulator makes it
possible to retrofit this technique into existing spectroscopic instruments
installed at synchrotron beamlines. Because many synchrotron facilities are
planning or undergoing upgrades to diffraction limited storage rings with
transversely coherent beams, a newly emerging set of coherent X-ray scattering
experiments can greatly benefit from the concepts we present here.Comment: 21 pages, 4 figure
Probing the molecular environment using spin-resolved photoelectron spectroscopy.
Angle- and spin-resolved photoelectron spectroscopy with linearly and circularly polarized synchrotron radiation were used to study the electronic structure of model triatomic molecules, hydrogen sulfide, and carbonyl sulfide. The spin-polarization measurements of the molecular field split components of the S 2p photolines revealed a strong effect of the different molecular environments. The validity of simple atomic models to explain the results is discussed
- âŠ