2,073 research outputs found

    Phase behaviour of a symmetrical binary fluid mixture in a field

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    Integral equation theory calculations within the mean spherical approximation (MSA) and grand canonical Monte Carlo (MC) simulations are employed to study the phase behaviour of a symmetrical binary fluid mixture in the presence of a field arising from unequal chemical potentials of the two particle species. Attention is focused on the case for which, in the absence of a field, the phase diagram exhibits a first order liquid-liquid transition in addition to the liquid-vapor transition. We find that in the presence of a field, two possible subtypes of phase behaviour can occur, these being distinguished by the relationship between the critical lines in the full phase diagram of temperature, density, and concentration. We present the detailed form of the respective phase diagrams as calculated from MSA and compare with results from the MC simulations, finding good overall agreement.Comment: 8 pages, 2 figure

    Lane-formation vs. cluster-formation in two dimensional square-shoulder systems: A genetic algorithm approach

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    Introducing genetic algorithms as a reliable and efficient tool to find ordered equilibrium structures, we predict minimum energy configurations of the square shoulder system for different values of corona width λ\lambda. Varying systematically the pressure for different values of λ\lambda we obtain complete sequences of minimum energy configurations which provide a deeper understanding of the system's strategies to arrange particles in an energetically optimized fashion, leading to the competing self-assembly scenarios of cluster-formation vs. lane-formation.Comment: 5 pages, 6 figure

    The Process of Schema Emergence: Assimilation, Deconstruction, Unitization and the Plurality of Analogies

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    Schemas are a central concept in strategy and organization theory. Yet, despite the importance of schemas, little is known about how they emerge. Our in-depth historical analysis of how groups in the life insurance industry developed their schema for the computer from 1945-1975 addresses this gap. We identify three key processes— assimilation, deconstruction, and unitization—that collectively explain and resolve an inherent tension related to schema emergence: how to make the unfamiliar familiar but conceptually distinct. We also find that each process relates to analogical transfer, but in a more pluralistic and dynamic way than the existing literature describes. Broadly, these findings have important implications for rganizational change and managerial cognition

    Phase behaviour of a symmetrical binary fluid mixture

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    We have investigated the phase behaviour of a symmetrical binary fluid mixture for the situation where the chemical potentials μ1\mu_1 and μ2\mu_2 of the two species differ. Attention is focused on the set of interparticle interaction strengths for which, when μ1=μ2\mu_1=\mu_2, the phase diagram exhibits both a liquid-vapor critical point and a tricritical point. The corresponding phase behaviour for the case μ1≠μ2\mu_1\ne\mu_2 is investigated via integral-equation theory calculations within the mean spherical approximation (MSA), and grand canonical Monte Carlo (GCMC) simulations. We find that two possible subtypes of phase behaviour can occur, these being distinguished by the relationship between the critical lines in the full phase diagram in the space of temperature, density, and concentration. We present the detailed form of the phase diagram for both subtypes and compare with the results from GCMC simulations, finding good overall agreement. The scenario via which one subtype evolves into the other, is also studied, revealing interesting features.Comment: 22 pages, 13 figure

    Characteristics of summer habitats of selected nongame birds in Missouri

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    December 1985--Cover."This study was funded principally through Research Agreements USDI-14-16-0008-2014 and USDI-FWS-14-15-0009-1556-1 between the U.S, Fish and Wildlife Service and the University of Missouri-Columbia"--Page v.Errata page inserted.Includes bibliographical references (pages 125-133)

    Assessment of processing technologies which may improve the nutritional composition of dairy products – Overview of progress

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    Among consumers there is a growing demand for food products with a natural nutritional-physiological advantage over comparable conventional products. As part of an EU funded project, ALP is examining the possible impact of processing on nutritionally valuable milk components, using the example of conjugated linoleic acids (CLA). The extent to which processing influences the CLA content of the end product was determined by literature research and own investigations of organic and conventional butter. Furthermore, new chemical, sensory-based and bio crystallization methods were evaluated by ALP and the University of Kassel to determine the oxidation stability of butter. In a further step the storage stability of CLA enriched and conventional butter was examined and the different methods will be compared. As a third objective a process for low-input CLA enrichment of milk fat (with a focus on alpine butter) has been developed. Since the process selected for the work is a physical enrichment process, it is accepted by international organic farming and food groups. Among the many benefits ascribed to CLA, it is believed to be an effective agent against cancer. The demand for foods with properties that promote human health is growing. The dairy industry has the opportunity to meet this demand by developing new dairy products with a nutritional-physiological function for the functional food market

    Allogeneic hematopoietic cell transplantation as curative therapy for patients with non-Hodgkin lymphoma: Increasingly successful application to older patients

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    AbstractNon-Hodgkin lymphoma (NHL) constitutes a collection of lymphoproliferative disorders with widely varying biological, histological, and clinical features. For the B cell NHLs, great progress has been made due to the addition of monoclonal antibodies and, more recently, other novel agents including B cell receptor signaling inhibitors, immunomodulatory agents, and proteasome inhibitors. Autologous hematopoietic cell transplantation (auto-HCT) offers the promise of cure or prolonged remission in some NHL patients. For some patients, however, auto-HCT may never be a viable option, whereas in others, the disease may progress despite auto-HCT. In those settings, allogeneic HCT (allo-HCT) offers the potential for cure. Over the past 10 to 15 years, considerable progress has been made in the implementation of allo-HCT, such that this approach now is a highly effective therapy for patients up to (and even beyond) age 75 years. Recent advances in conventional lymphoma therapy, peritransplantation supportive care, patient selection, and donor selection (including the use of alternative hematopoietic cell donors), has allowed broader application of allo-HCT to patients with NHL. As a result, an ever-increasing number of NHL patients over age 60 to 65 years stand to benefit from allo-HCT. In this review, we present data in support of the use of allo-HCT for patients with diffuse large B cell lymphoma, follicular lymphoma, and mantle cell lymphoma. These histologies account for a large majority of allo-HCTs performed for patients over age 60 in the United States. Where possible, we highlight available data in older patients. This body of literature strongly supports the concept that allo-HCT should be offered to fit patients well beyond age 65 and, accordingly, that this treatment should be covered by their insurance carriers

    Efficacy of an Online Native Snake Identification Search Engine for Public Use

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    Visual methods of species identification are used both in research and recreational contexts because they are inexpensive, non-invasive, and believed to be effective among uniquely identifiable individuals. We examined the ability of the general public to identify live snakes (Serpentes) that are native to the United States using an online snake identification search engine (SISE) produced by the North America Brown Tree Snake Control Team (NABTSCT) website, http://www.nabtsct.net. The SISE consisted of participants answering 7 descriptive questions concerning a snake and then reviewing photographs of snakes that matched that description. Using 3 species of snakes native to Texas, USA, 21% of 395 participants were able to correctly identify all of the snakes using the online SISE, 54% correctly identified 2 snakes, 18% correctly identified 1 snake, and only 7% could not identify any snakes. Participants identified the distinctly marked checkered garter snake (Thamnophis marcianus) more readily (87% of participants) than the gopher snake (Pituophis catenifer) and Trans-Pecos rat snake (Bogertophis subocularis; 55% and 46% of participants, respectively). The probability of participants correctly identifying a snake using the online SISE increased substantially if ≥4 of the 7 descriptive questions were answered correctly. The age of participants and affinity toward snakes affected participant ability to correctly answer questions about snake morphology and identify snakes. In general, participants who displayed fear of snakes were less likely to correctly identify snake species than those who expressed a snake-neutral or enthusiast attitude. Additionally, younger participants performed better, on average, than older participants. Most participants (97%) claimed they would be able to use the online SISE to correctly identify other snakes in the future. We believe the public can use the online SISE to identify snakes, and hence, it can be an educational tool for the public to learn about an often neglected wildlife suborder

    Why do ultrasoft repulsive particles cluster and crystallize? Analytical results from density functional theory

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    We demonstrate the accuracy of the hypernetted chain closure and of the mean-field approximation for the calculation of the fluid-state properties of systems interacting by means of bounded and positive-definite pair potentials with oscillating Fourier transforms. Subsequently, we prove the validity of a bilinear, random-phase density functional for arbitrary inhomogeneous phases of the same systems. On the basis of this functional, we calculate analytically the freezing parameters of the latter. We demonstrate explicitly that the stable crystals feature a lattice constant that is independent of density and whose value is dictated by the position of the negative minimum of the Fourier transform of the pair potential. This property is equivalent with the existence of clusters, whose population scales proportionally to the density. We establish that regardless of the form of the interaction potential and of the location on the freezing line, all cluster crystals have a universal Lindemann ratio L = 0.189 at freezing. We further make an explicit link between the aforementioned density functional and the harmonic theory of crystals. This allows us to establish an equivalence between the emergence of clusters and the existence of negative Fourier components of the interaction potential. Finally, we make a connection between the class of models at hand and the system of infinite-dimensional hard spheres, when the limits of interaction steepness and space dimension are both taken to infinity in a particularly described fashion.Comment: 19 pages, 5 figures, submitted to J. Chem. Phys; new version: minor changes in structure of pape
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