2,666 research outputs found
Phonon-affected steady-state transport through molecular quantum dots
We consider transport through a vibrating molecular quantum dot contacted to
macroscopic leads acting as charge reservoirs. In the equilibrium and
nonequilibrium regime, we study the formation of a polaron-like transient state
at the quantum dot for all ratios of the dot-lead coupling to the energy of the
local phonon mode. We show that the polaronic renormalization of the dot-lead
coupling is a possible mechanism for negative differential conductance.
Moreover, the effective dot level follows one of the lead chemical potentials
to enhance resonant transport, causing novel features in the inelastic
tunneling signal. In the linear response regime, we investigate the impact of
the electron-phonon interaction on the thermoelectrical properties of the
quantum dot device.Comment: 11 pages, 7 figures, FQMT11 Proceeding
Phonon affected transport through molecular quantum dots
To describe the interaction of molecular vibrations with electrons at a
quantum dot contacted to metallic leads, we extend an analytical approach that
we previously developed for the many-polaron problem. Our scheme is based on an
incomplete variational Lang-Firsov transformation, combined with a perturbative
calculation of the electron-phonon self-energy in the framework of generalised
Matsubara functions. This allows us to describe the system at weak to strong
coupling and intermediate to large phonon frequencies. We present results for
the quantum dot spectral function and for the kinetic coefficient that
characterises the electron transport through the dot. With these results we
critically examine the strengths and limitations of our approach, and discuss
the properties of the molecular quantum dot in the context of polaron physics.
We place particular emphasis on the importance of corrections to the concept of
an antiadiabatic dot polaron suggested by the complete Lang-Firsov
transformation.Comment: 30 pages, 15 figures, revised version including new figure
Uniform electron gases
We show that the traditional concept of the uniform electron gas (UEG) --- a
homogeneous system of finite density, consisting of an infinite number of
electrons in an infinite volume --- is inadequate to model the UEGs that arise
in finite systems. We argue that, in general, a UEG is characterized by at
least two parameters, \textit{viz.} the usual one-electron density parameter
and a new two-electron parameter . We outline a systematic
strategy to determine a new density functional across the
spectrum of possible and values.Comment: 8 pages, 2 figures, 5 table
An ultrashort pulse ultra-violet radiation undulator source driven by a laser plasma wakefield accelerator
Narrow band undulator radiation tuneable over the wavelength range of 150–260 nm has been produced by short electron bunches from a 2 mm long laser plasma wakefield accelerator based on a 20 TW femtosecond laser system. The number of photons measured is up to 9 × 106 per shot for a 100 period undulator, with a mean peak brilliance of 1 × 1018 photons/s/mrad2/mm2/0.1% bandwidth. Simulations estimate that the driving electron bunch r.m.s. duration is as short as 3 fs when the electron beam has energy of 120–130 MeV with the radiation pulse duration in the range of 50–100 fs
Investigation of the feasibility to use Zeeman-effect background correction for the graphite furnace determination of phosphorus using high-resolution continuum source atomic absorption spectrometry as a diagnostic tool
The determination of phosphorus by graphite furnace atomic absorption spectrometry at the non-resonance line at 213.6 nm, and the capability of Zeeman-effect background correction (Z-BC) to deal with the fine-structured background absorption due to the PO molecule have been investigated in the presence of selected chemical modifiers. Two line source atomic absorption spectrometers, one with a longitudinally heated and the other with a transversely heated graphite tube atomizer have been used in this study, as well as two prototype high-resolution continuum source atomic absorption spectrometers, one of which had a longitudinally arranged magnet at the furnace. It has been found that Z-BC is capable correcting very well the background caused by the PO molecule, and also that of the NO molecule, which has been encountered when the Pd + Ca mixed modifier was used. Both spectra exhibited some Zeeman splitting, which, however, did not cause any artifacts or correction errors. The practical significance of this study is to confirm that accurate results can be obtained for the determination of phosphorus using Z-BC.
The best sensitivity with a characteristic mass of m(0) = 11 ng P has been obtained with the pure Pd modifier, which also caused the lowest background level. The characteristic mass obtained with the mixed Pd + Ca modifier depended on the equipment used and was between m(0) = 9 ng P and m(0) = 15 ng P, and the background signal was higher. The major problem of Z-BC remains the relatively restricted linear working range
The Generalised Zakharov-Shabat System and the Gauge Group Action
The generalized Zakharov-Shabat systems with complex-valued non-regular
Cartan elements and the systems studied by Caudrey, Beals and Coifman (CBC
systems) and their gauge equivalent are studied. This study includes: the
properties of fundamental analytical solutions (FAS) for the gauge-equivalent
to CBC systems and the minimal set of scattering data; the description of the
class of nonlinear evolutionary equations, solvable by the inverse scattering
method, and the recursion operator, related to such systems; the hierarchies of
Hamiltonian structures. The results are illustrated on the example of the
multi-component nonlinear Schrodinger (MNLS) equations and the corresponding
gauge-equivalent multi-component Heisenberg ferromagnetic (MHF) type models,
related to so(5;C) algebra.Comment: 17 pages, 1 figure, LaTeX. arXiv admin note: substantial text overlap
with arXiv:0710.330
Unconstrained SU(2) Yang-Mills Quantum Mechanics with Theta Angle
The unconstrained classical system equivalent to spatially homogeneous SU(2)
Yang-Mills theory with theta angle is obtained and canonically quantized. The
Schr\"odinger eigenvalue problem is solved approximately for the low lying
states using variational calculation. The properties of the groundstate are
discussed, in particular its electric and magnetic properties, and the value of
the "gluon condensate" is calculated. Furthermore it is shown that the energy
spectrum of SU(2) Yang-Mills quantum mechanics is independent of the theta
angle. Explicit evaluation of the Witten formula for the topological
susceptibility gives strong support for the consistency of the variational
results obtained.Comment: 20 pages REVTEX, no figures, one reference added, final version to
appear in Phys. Rev.
Triplet Exciton Generation in Bulk-Heterojunction Solar Cells based on Endohedral Fullerenes
Organic bulk-heterojunctions (BHJ) and solar cells containing the trimetallic
nitride endohedral fullerene 1-[3-(2-ethyl)hexoxy
carbonyl]propyl-1-phenyl-Lu3N@C80 (Lu3N@C80-PCBEH) show an open circuit voltage
(VOC) 0.3 V higher than similar devices with [6,6]-phenyl-C[61]-butyric acid
methyl ester (PC61BM). To fully exploit the potential of this acceptor molecule
with respect to the power conversion efficiency (PCE) of solar cells, the short
circuit current (JSC) should be improved to become competitive with the state
of the art solar cells. Here, we address factors influencing the JSC in blends
containing the high voltage absorber Lu3N@C80-PCBEH in view of both
photogeneration but also transport and extraction of charge carriers. We apply
optical, charge carrier extraction, morphology, and spin-sensitive techniques.
In blends containing Lu3N@C80-PCBEH, we found 2 times weaker photoluminescence
quenching, remainders of interchain excitons, and, most remarkably, triplet
excitons formed on the polymer chain, which were absent in the reference
P3HT:PC61BM blends. We show that electron back transfer to the triplet state
along with the lower exciton dissociation yield due to intramolecular charge
transfer in Lu3N@C80-PCBEH are responsible for the reduced photocurrent
Dynamical Properties of small Polarons
On the basis of the two-site polaron problem, which we solve by exact
diagonalization, we analyse the spectral properties of polaronic systems in
view of discerning localized from itinerant polarons and bound polaron pairs
from an ensemble of single polarons. The corresponding experimental techniques
for that concern photoemission and inverse photoemission spectroscopy. The
evolution of the density of states as a function of concentration of charge
carriers and strength of the electron-phonon interaction clearly shows the
opening up of a gap between single polaronic and bi-polaronic states, in
analogy to the Hubbard problem for strongly correlated electron systems. The
crossover regime between adiabatic and anti-adiabatic small polarons is
triggered by two characteristic time scales: the renormalized electron hopping
rate and the renormalized vibrational frequency becoming equal. This crossover
regime is then characterized by temporarily alternating self- localization and
delocalization of the charge carriers which is accompanied by phase slips in
the charge and molecular deformation oscillations and ultimately leads to a
dephasing between these two dynamical components of the polaron problem. We
visualize these features by a study of the temporal evolution of the charge
redistribution and the change in molecular deformations. The spectral and
dynamical properties of polarons discussed here are beyond the applicability of
the standard Lang Firsov approach to the polaron problem.Comment: 31 pages and 23 figs.(eps), accepted in the Phys. Rev.
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