IRAC Excess in Distant Star-Forming Galaxies: Tentative Evidence for the 3.3μ\mum Polycyclic Aromatic Hydrocarbon Feature ?

We present evidence for the existence of an IRAC excess in the spectral energy distribution (SED) of 5 galaxies at 0.6<z<0.9 and 1 galaxy at z=1.7. These 6 galaxies, located in the Great Observatories Origins Deep Survey field (GOODS-N), are star forming since they present strong 6.2, 7.7, and 11.3 um polycyclic aromatic hydrocarbon (PAH) lines in their Spitzer IRS mid-infrared spectra. We use a library of templates computed with PEGASE.2 to fit their multiwavelength photometry and derive their stellar continuum. Subtraction of the stellar continuum enables us to detect in 5 galaxies a significant excess in the IRAC band pass where the 3.3 um PAH is expected. We then assess if the physical origin of the IRAC excess is due to an obscured active galactic nucleus (AGN) or warm dust emission. For one galaxy evidence of an obscured AGN is found, while the remaining four do not exhibit any significant AGN activity. Possible contamination by warm dust continuum of unknown origin as found in the Galactic diffuse emission is discussed. The properties of such a continuum would have to be different from the local Universe to explain the measured IRAC excess, but we cannot definitively rule out this possibility until its origin is understood. Assuming that the IRAC excess is dominated by the 3.3 um PAH feature, we find good agreement with the observed 11.3 um PAH line flux arising from the same C-H bending and stretching modes, consistent with model expectations. Finally, the IRAC excess appears to be correlated with the star-formation rate in the galaxies. Hence it could provide a powerful diagnostic for measuring dusty star formation in z>3 galaxies once the mid-infrared spectroscopic capabilities of the James Webb Space Telescope become available.Comment: 25 pages, 4 figures, accepted by Ap

Spatial Separation of the 3.29 micron Emission Feature and Associated 2 micron Continuum in NGC 7023

We present a new 0.9" resolution 3.29 micron narrowband image of the reflection nebula NGC 7023. We find that the 3.29 micron IEF in NGC 7023 is brightest in narrow filaments NW of the illuminating star. These filaments have been seen in images of K', molecular hydrogen emission lines, the 6.2 and 11.3 micron IEFs, and HCO+. We also detect 3.29 micron emission faintly but distinctly between the filaments and the star. The 3.29 micron image is in contrast to narrowband images at 2.09, 2.14, and 2.18 micron, which show an extended emission peak midway between the filaments and the star, and much fainter emission near the filaments. The [2.18]-[3.29] color shows a wide variation, ranging from 3.4-3.6 mag at the 2 micron continuum peak to 5.5 mag in the filaments. We observe [2.18]-[3.29] to increase smoothly with increasing distance from the star, up until the filament, suggesting that the main difference between the spatial distributions of the 2 micron continuum and the the 3.29 micron emission is related to the incident stellar flux. Our result suggests that the 3.29 micron IEF carriers are likely to be distinct from, but related to, the 2 micron continuum emitters. Our finding also imply that, in NGC 7023, the 2 micron continuum emitters are mainly associated with HI, while the 3.29 micron IEF carriers are primarily found in warm molecular hydrogen, but that both can survive in HI or molecular hydrogen. (abridged)Comment: to appear in ApJ, including 1 table and 8 figures, high resolution figures available at http://www.ast.cam.ac.uk/~jin/n7023

Molecular Hydrogen Formation on Ice Under Interstellar Conditions

The results of experiments on the formation of molecular hydrogen on low density and high density amorphous ice surfaces are analyzed using a rate equation model. The activation energy barriers for the relevant diffusion and desorption processes are obtained. The more porous morphology of the low density ice gives rise to a broader spectrum of energy barriers compared to the high density ice. Inserting these parameters into the rate equation model under steady state conditions we evaluate the production rate of molecular hydrogen on ice-coated interstellar dust grains.Comment: 20 pages, 3 tables and 10 figures. Accepted to ApJ. Minor changes made and adittional references adde

Metal Enrichment of the Intergalactic Medium in Cosmological Simulations

Observations have established that the diffuse intergalactic medium (IGM) at z ~ 3 is enriched to ~0.1-1% solar metallicity and that the hot gas in large clusters of galaxies (ICM) is enriched to 1/3-1/2 solar metallicity at z=0. Metals in the IGM may have been removed from galaxies (in which they presumably form) during dynamical encounters between galaxies, by ram-pressure stripping, by supernova-driven winds, or as radiation-pressure driven dust efflux. This study develops a method of investigating the chemical enrichment of the IGM and of galaxies, using already completed cosmological simulations. To these simulations, we add dust and (gaseous) metals, distributing the dust and metals in the gas according to three simple parameterized prescriptions, one for each enrichment mechanism. These prescriptions are formulated to capture the basic ejection physics, and calibrated when possible with empirical data. Our results indicate that dynamical removal of metals from >~ 3*10^8 solar mass galaxies cannot account for the observed metallicity of low-column density Ly-alpha absorbers, and that dynamical removal from >~ 3*10^10 solar mass galaxies cannot account for the ICM metallicities. Dynamical removal also fails to produce a strong enough mass-metallicity relation in galaxies. In contrast, either wind or radiation-pressure ejection of metals from relatively large galaxies can plausibly account for all three sets of observations (though it is unclear whether metals can be distributed uniformly enough in the low-density regions without overly disturbing the IGM, and whether clusters can be enriched quite as much as observed). We investigate in detail how our results change with variations in our assumed parameters, and how results for the different ejection processes compare. (Abridged)Comment: Minor revision, 1 figure added addressing diffusion of metals after their ejection. Accepted by ApJ. 31 EmulateApj Pages with 13 embedded postscript figure

Interstellar Carbon in Translucent Sightlines

We report interstellar C II column densities or upper limits determined from weak absorption of the 2325.4029 A intersystem transition observed in six translucent sightlines with STIS. The sightlines sample a wide range of interstellar characteristics including total-to-selective extinction, R_{V} = 2.6 - 5.1; average hydrogen density along the sightline, = 3 - 14 cm^{-3}; and fraction of H in molecular form, 0 - 40%. Four of the sightlines, those toward HD 37021, HD 37061, HD 147888 and HD 207198, have interstellar gas-phase abundances that are consistent with the diffuse sightline ratio of 161 +/- 17 carbon atoms in the gas per million hydrogen nuclei. We note that while it has a gas-phase carbon abundance that is consistent with the other sightlines, a large fraction of the C II toward HD 37061 is in an excited state. The sightline toward HD 152590 has a measured interstellar gas-phase carbon abundance that is well above the diffuse sightline average; the column density of C in this sightline may be overestimated due to noise structure in the data. Toward HD 27778 we find a 3 sigma abundance upper limit of <108 C atoms in the gas per million H, a substantially enhanced depletion of C as compared to the diffuse sightline value. The interstellar characteristics toward HD 27778 are otherwise not extreme among the sample except for an unusually large abundance of CO molecules in the gas.Comment: Accepted for publication in the Astrophysical Journa

Identification of SH Δv=1\Delta v=1 ro-vibrational lines in R And

We report the identification of SH $\Delta v=1$ ro-vibrational lines in the published high-resolution infrared spectrum of the S-type star, R And. This is the first astronomical detection of this molecule. The lines show inverse P-Cygni profiles, indicating infall motion of the molecular layer due to stellar pulsation. A simple spherical shell model with a constant infall velocity is adopted to determine the condition of the layer. It is found that a single excitation temperature of 2200 K reproduces the observed line intensities satisfactory. SH is located in a layer from 1.0 to ~1.1 stellar radii, which is moving inward with a velocity of 9 km s-1. These results are consistent with the previous measurements of CO $\Delta v=3$ transitions. The estimated molecular abundance SH/H is 1x10^-7, consistent with a thermal equilibrium calculation.Comment: 10 pages, 2 figures. Accepted for publication in ApJ Letter

The Photophysics of the Carrier of Extended Red Emission

Interstellar dust contains a component which reveals its presence by emitting a broad, unstructured band of light in the 540 to 950 nm wavelength range, referred to as Extended Red Emission (ERE). The presence of interstellar dust and ultraviolet photons are two necessary conditions for ERE to occur. This is the basis for suggestions which attribute ERE to an interstellar dust component capable of photoluminescence. In this study, we have collected all published ERE observations with absolute-calibrated spectra for interstellar environments, where the density of ultraviolet photons can be estimated reliably. In each case, we determined the band-integrated ERE intensity, the wavelength of peak emission in the ERE band, and the efficiency with which absorbed ultraviolet photons are contributing to the ERE. The data show that radiation is not only driving the ERE, as expected for a photoluminescence process, but is modifying the ERE carrier as manifested by a systematic increase in the ERE band's peak wavelength and a general decrease in the photon conversion efficiency with increasing densities of the prevailing exciting radiation. The overall spectral characteristics of the ERE and the observed high quantum efficiency of the ERE process are currently best matched by the recently proposed silicon nanoparticle (SNP) model. Using the experimentally established fact that ionization of semiconductor nanoparticles quenches their photoluminescence, we proceeded to test the SNP model by developing a quantitative model for the excitation and ionization equilibrium of SNPs under interstellar conditions for a wide range of radiation field densities.Comment: 42 p., incl. 8 fig. Accepted for publication by Ap

The unusual hydrocarbon emission from the early carbon star HD 100764: The connection between aromatics and aliphatics

We have used the Infrared Spectrograph (IRS) on the Spitzer Space Telescope to obtain spectra of HD 100764, an apparently single carbon star with a circumstellar disk. The spectrum shows emission features from polycyclic aromatic hydrocarbons (PAHs) that are shifted to longer wavelengths than normally seen, as characteristic of ``class C'' systems in the classification scheme of Peeters et al. All seven of the known class C PAH sources are illuminated by radiation fields that are cooler than those which typically excite PAH emission features. The observed wavelength shifts are consistent with hydrocarbon mixtures containing both aromatic and aliphatic bonds. We propose that the class C PAH spectra are distinctive because the carbonaceous material has not been subjected to a strong ultraviolet radiation field, allowing relatively fragile aliphatic materials to survive.Comment: 11 pages (in emulateapj), 5 tables, 7 figures. Accepted for publication in Ap

Formation of molecular hydrogen on analogues of interstellar dust grains: experiments and modelling

Molecular hydrogen has an important role in the early stages of star formation as well as in the production of many other molecules that have been detected in the interstellar medium. In this review we show that it is now possible to study the formation of molecular hydrogen in simulated astrophysical environments. Since the formation of molecular hydrogen is believed to take place on dust grains, we show that surface science techniques such as thermal desorption and time-of-flight can be used to measure the recombination efficiency, the kinetics of reaction and the dynamics of desorption. The analysis of the experimental results using rate equations gives useful insight on the mechanisms of reaction and yields values of parameters that are used in theoretical models of interstellar cloud chemistry.Comment: 23 pages, 7 figs. Published in the J. Phys.: Conf. Se

Spitzer Mapping of PAHs and H2 in Photodissociation Regions

The mid-infrared (MIR) spectra of dense photodissociation regions (PDRs) are typically dominated by emission from polycyclic aromatic hydrocarbons (PAHs) and the lowest pure rotational states of molecular hydrogen (H2); two species which are probes of the physical properties of gas and dust in intense UV radiation fields. We utilize the high angular resolution of the Infrared Spectrograph on the Spitzer Space Telescope to construct spectral maps of the PAH and H2 features for three of the best studied PDRs in the galaxy, NGC 7023, NGC 2023 and IC 63. We present spatially resolved maps of the physical properties, including the H2 ortho-to-para ratio, temperature, and G_o/n_H. We also present evidence for PAH dehydrogenation, which may support theories of H2 formation on PAH surfaces, and a detection of preferential self-shielding of ortho-H2. All PDRs studied exhibit average temperatures of ~500 - 800K, warm H2 column densities of ~10^20 cm^-2, G_o/n_H ~ 0.1 - 0.8, and ortho-to-para ratios of ~ 1.8. We find that while the average of each of these properties is consistent with previous single value measurements of these PDRs, when available, the addition of spatial resolution yields a diversity of values with gas temperatures as high as 1500 K, column densities spanning ~ 2 orders of magnitude, and extreme ortho-to-para ratios of 3.Comment: 14 figure