Elaboration and characterization of Fe1–xO thin films sputter deposited from magnetite target

Majority of the authors report elaboration of iron oxide thin films by reactive magnetron sputtering from an iron target with Ar–O2 gas mixture. Instead of using the reactive sputtering of a metallic target we report here the preparation of Fe1–xOthin films, directly sputtered froma magnetite target in a pure argon gas flow with a bias power applied. This oxide is generally obtained at very low partial oxygen pressure and high temperature.We showed that bias sputtering which can be controlled very easily can lead to reducing conditions during deposition of oxide thin film on simple glass substrates. The proportion of wustite was directly adjusted bymodifying the power of the substrate polarization. Atomic force microscopy was used to observe these nanostructured layers. Mössbauer measurements and electrical properties versus bias polarization and annealing temperature are also reported

Barrier effect to charge injection in polyethylene by silver nanoparticles containing plasma polymer composites investigated by conductivity measurements

International audienceMain challenge in the development of HVDC polymeric insulation is to avoid the accumulation of space charge under electrical and/or thermal stresses which can significantly reduce the component reliability. Injection mitigation in low density polyethylene (LDPE) films by plasma processed silver nanoparticles (AgNPs) containing plasma polymer composites was recently reported through space charge measurements. The barrier effect has been assigned to the creation of permanent deep traps by introducing silver nanoparticles near the polyethylene surface. To substantiate the above findings, current measurements realized on composite layers and on polyethylene films with and without silver nanoparticles have been carried out. It is shown that in the presence of AgNPs in organosilicon layer, polarization/depolarization currents are one order of magnitude lower, transient currents decay faster and are not sensitive to multiple polarization. This can be understood if the AgNPs in the layer are acting as deep traps mitigating further injection with the result to decrease the apparent conductivity of the layer and to increase its breakdown strength. Similar trend is observed in polyethylene tailored by composite layer. These results strengthen the interpretation of the barrier effect based on space charge stabilized by deep traps formed by the AgNPs

Quantifier l'effet de choix du site dans l'incertitude des jaugeages ADCP par transects

HMEM, Durham, New Hampshire, USA, 09-/07/2017 - 12/07/2017International audienceStage-discharge rating curves are used to relate streamflow discharge to continuously measured river stage readings to create a continuous record of streamflow discharge. The stage-discharge relationship is estimated and refined using discrete streamflow measurements over time, during which both the discharge and stage are measured. There is uncertainty in the resulting rating curve due to multiple factors including the curve-fitting process, assumptions on the form of the model used, fluvial geomorphology of natural channels, and the approaches used to extrapolate the rating equation beyond available observations. This rating curve uncertainty leads to uncertainty in the streamflow timeseries, and therefore to uncertainty in predictive models that use the streamflow data. Many different methods have been proposed in the literature for estimating rating curve uncertainty, differing in mathematical rigor, in the assumptions made about the component errors, and in the information required to implement the method at any given site. This study describes the results of an international experiment to test and compare streamflow uncertainty estimation methods from 7 research groups across 9 institutions. The methods range from simple LOWESS fits to more complicated Bayesian methods that consider hydraulic principles directly. We evaluate these different methods when applied to three diverse gauging stations using standardized information (channel characteristics, hydrographs, and streamflow measurements). Our results quantify the resultant spread of the stage-discharge Quantifying the uncertainty of discharge measurements (or "gaugings") is a challenge in the hydrometric community. A useful tool to empirically estimate the uncertainty of a gauging method is the field inter-laboratory experiment (Le Coz et al., 2016). Previous inter-laboratory experiments conducted in France (in 2009, 2010, 2011 and 2012) showed that the expanded uncertainty (with a probability level of 95%) of an ADCP gauging made of six successive transects is typically around 5% under optimum site conditions (straight reach, uniform and smooth streambed cross-section, homogeneous flow, etc.) and may be twice higher under poorer site conditions. In practice, the selected cross-section does not always match all quality requirements which may result in larger uncertainty. However, the uncertainty due to site selection is very difficult to estimate with predictive equations. From 9 to 10 November 2016, 50 teams from 8 different countries, using 50 ADCPs simultaneously, conducted more than 600 discharge measurements in steady flow conditions (~14 m3/s released by a dam). 26 cross-sections with various shapes and flow conditions were distributed over 500 meters along the Taurion River at Saint-Priest-de-Taurion, France. A specific experiment protocol, which consisted of circulating every team over half of the cross-sections, was implemented in order to quantify the impact of site selection on the discharge measurement uncertainty. Beyond the description of the experiments, uncertainty estimates are presented. The overall expanded uncertainty of a 6-transect ADCP gaugings (duration around 720 seconds) is estimated to be around 6%.The uncertainty of the discharge measurements varies among the cross-sections. These variations are well correlated to the expert judgment on the cross-section quality made by each team. First results seem to highlight a relation between uncertainty computed for each cross-section and criteria such as flow shallowness and measured discharge ratio. Further investigations are necessary to identify the criteria related to error sources that are possibly meaningful for categorizing measurement conditions and site selection. Moreover, experimental uncertainty and the uncertainty predicted by analytical methods such as QRev, QUant, OURSIN, RiverFlowUA or QMSys software will be compared

Valorisation of Biowastes for the Production of Green Materials Using Chemical Methods

With crude oil reserves dwindling, the hunt for a sustainable alternative feedstock for fuels and materials for our society continues to expand. The biorefinery concept has enjoyed both a surge in popularity and also vocal opposition to the idea of diverting food-grade land and crops for this purpose. The idea of using the inevitable wastes arising from biomass processing, particularly farming and food production, is, therefore, gaining more attention as the feedstock for the biorefinery. For the three main components of biomass—carbohydrates, lipids, and proteins—there are long-established processes for using some of these by-products. However, the recent advances in chemical technologies are expanding both the feedstocks available for processing and the products that be obtained. Herein, this review presents some of the more recent developments in processing these molecules for green materials, as well as case studies that bring these technologies and materials together into final products for applied usage

Physico-chemical, structural and physical properties of hydrogenated silicon oxinitride films elaborated by pulsed radiofrequency discharge

International audienceFilms prepared by radiofrequency pulsed plasma enhanced chemical vapor deposition from a mixture of silane (SiH4) and nitrous oxide (N2O) were studied. Variation of operating conditions (flow rate, deposition temperature ...) resulted in films with chemical compositions changing from hydrogenated silicon oxynitride (SiOxNy:H) to silicon oxide (SiOx:H). Infrared and Rutherford backscattering spectroscopy studies of the as-deposited films revealed different SiOx arrangements disturbed by Si–N bonds and H–Si ≡ Si(3 − x)Ox clusters depending on the substrate temperature and the N2O/SiH4 ratio. For films obtained using low N2O/SiH4 rations and annealed at temperature higher than 1273 K, Raman spectroscopy and microscopy analyses revealed the presence of silicon nanocrystals embedded in a matrix containing Si, O, and N. Spectroscopic ellipsometry revealed the presence of silicon nanocrystals along with two other amorphous phases (SiOxNy and SiO2) in annealed samples. The electrical characteristics of annealed films obtained from capacitance–voltage measurements indicated a stable charge trapping in ultra-thin SiOxNy layers. These preliminary results suggest that Si-nc containing silicon oxynitride layers can be potential candidates to be used in the floating gate fabrication of memory devices

Physicochemical and structural properties of ultra thin films with embedded silicon particles

International audienceThis work is devoted to the study of nanostructured silicon thin films which were deposited by a pulsed plasma enhanced chemical vapour deposition process using SiH4/N2O/He mixture. According to the elemental XPS analysis and IR spectroscopy, the as-deposited films were contained silicon, oxygen, nitrogen and bonded hydrogen. The film composition was been controlled by varying the substrate temperature and the plasma pulsation. As a consequence, the increase in the substrate temperature showed evident separation of the two phases: hydrogenated amorphous silicon and silicon oxide with nitrogen impurities. The employment of the square-wave modulated discharges leads to a spectacular improvement of the Si particle size decrease