Paramètres contrôlant la géométrie des bassins d'avant-chaîne dans les chaînes alpines

Les bassins d'avant-chaîne s'édifient au front des chaînes à la suite d'une flexion de la lithosphère continentale. L'étude comparée de différents bassins permet de mettre en évidence les paramètres qui influent très étroitement sur leur évolution et leur géométri

Paramètres contrôlant la géométrie des bassins d'avant-chaîne dans les chaînes alpines

Les bassins d'avant-chaîne s'édifient au front des chaînes à la suite d'une flexion de la lithosphère continentale. L'étude comparée de différents bassins permet de mettre en évidence les paramètres qui influent très étroitement sur leur évolution et leur géométri

Nickel‐Catalyzed Inter‐ and Intramolecular Aryl Thioether Metathesis by Reversible Arylation

A nickel‐catalyzed aryl thioether metathesis has been developed to access high‐value thioethers. 1,2‐Bis(dicyclohexylphosphino)ethane (dcype) is essential to promote this highly functional‐group‐tolerant reaction. Furthermore, synthetically challenging macrocycles could be obtained in good yield in an unusual example of ring‐closing metathesis that does not involve alkene bonds. In‐depth organometallic studies support a reversible Ni0/NiII pathway to product formation. Overall, this work not only provides a more sustainable alternative to previous catalytic systems based on Pd, but also presents new applications and mechanistic information that are highly relevant to the further development and application of unusual single‐bond metathesis reactions

Efficient access to unprotected primary amines by iron-catalyzed aminochlorination of alkenes

Primary amines are essential constituents of biologically active molecules and versatile intermediates in the synthesis of drugs and agrochemicals. However, their preparation from easily accessible alkenes remains challenging. Here, we report a general strategy to access primary amines from alkenes through an operationally simple iron-catalyzed aminochlorination reaction. A stable hydroxylamine derivative and benign sodium chloride act as the respective nitrogen and chlorine sources. The reaction proceeds at room temperature under air; tolerates a large scope of aliphatic and conjugated alkenes, including densely functionalized substrates; and provides excellent anti-Markovnikov regioselectivity with respect to the amino group. The reactivity of the 2-chloroalkylamine products, an understudied class of amphoteric molecules, enables facile access to linear or branched aliphatic amines, aziridines, aminonitriles, azido amines, and homoallylic amines

"Arc-continent collision" of the Aleutian-Komandorsky arc into Kamchatka: Insight into Quaternary tectonic segmentation through Pleistocene marine terraces and morphometric analysis of fluvial drainage

At the NW corner of the Pacific region, just south of the Kamchatsky Peninsula, the northern tip of the Pacific plate subduction and associated volcanic arc interacts with the western end of the Aleutian-Komandorsky dextral transform plate boundary and associated arc. Study of both Holocene and Pleistocene sequences of uplifted marine terraces and also of fluvial drainage patterns on the Kamchatsky Peninsula allows us to highlight active tectonics produced by complex plate interaction. Our results show that the central eastern coast of the peninsula is currently divided into four different zones consisting in uplifted blocks associated with various uplift rates in front of a fold-and-thrust zone to the west. Our main tectonic benchmark—the altitude of the shoreline correlated to the Last Interglacial Maximum (Marine Isotopic Stage 5e)—yields late Pleistocene uplift rates ranging from 0.2 to 2.74 mm/yr. One of the main active faults bounding the coastal blocks is dextral and is interpreted as a prolongation of an offshore fault of the Aleutian-Komandorsky dextral transform plate boundary. We suggest that structures on the Kamchatsky Peninsula accommodate a part of the transform motion, but that mainly, the arc-continent collision of the Aleutian arc against Kamchatka produces a “bulldozer” effect on the Kamchatsky Peninsula

Neogene-Quaternary slow coastal uplift of Western Europe through the perspective of sequences of strandlines from the Cotentin Peninsula (Normandy, France)

The Cotentin Peninsula (Normandy, France) displays sequences of marine terraces and rasas, the latter being wide Late Cenozoic coastal erosion surfaces, that are typical of Western European coasts in Portugal, Spain, France and southern England. Remote sensing imagery and field mapping enabled reappraisal of the Cotentin coastal sequences. From bottom to top, the N Cotentin sequence includes four previously recognized Pleistocene marine terraces (T1 to T4) at elevations < 40 m as well as four higher and older rasas (R1 to R4) reaching 200 ± 5 m in elevation. Low-standing marine terraces are not observed in the central part of the Peninsula and a limited number of terraces are described to the south. The high-standing rasas are widespread all over the peninsula. Such strandline distributions reveal major changes during the Late Cenozoic. Progressive uplift of an irregular sea-floor led to subaerial exposure of bathymetric highs that were carved into rocky platforms, rasas and marine terraces. Eventually, five main islands coalesced and connected to the mainland to the south to form the Cotentin Peninsula. On the basis of previous dating of the last interglacial maximum terrace (i.e. Marine Isotopic Stage, MIS 5e), sequential morphostratigraphy and modelling, we have reappraised uplift rates and derived: (i) mean Upper Pleistocene (i.e. since MIS 5e ~ 122 +/− 6 ka, i.e. kilo annum) apparent uplift rates of 0.04 ± 0.01 mm/yr, (ii) mean Middle Pleistocene eustasy-corrected uplift rates of 0.09 ± 0.03 mm/yr, and (iii) low mean Pleistocene uplift rates of 0.01 mm/yr. Extrapolations of these slow rates combined with geological evidence implies that the formation of the sequences from the Cotentin Peninsula occurred between 3 Ma (Pliocene) and 15 Ma (Miocene), which cannot be narrowed down further without additional research. Along the coasts of Western Europe, sequences of marine terraces and rasas are widespread (169 preserve the MIS 5e benchmark). In Spain, Portugal, S England and other parts of western France, the sequences morphostratigraphy is very similar to that of Cotentin. The onset of such Western European sequences occurred during the Miocene (e.g. Spain) or Pliocene (e.g. Portugal). We interpret this Neogene-Quaternary coastal uplift as a symptom of the increasing lithospheric compression that accompanies Cenozoic orogenies