Damage in porous media due to salt crystallization

We investigate the origins of salt damage in sandstones for the two most common salts: sodium chloride and sulfate. The results show that the observed difference in damage between the two salts is directly related to the kinetics of crystallization and the interfacial properties of the salt solutions and crystals with respect to the stone. We show that, for sodium sulfate, the existence of hydrated and anhydrous crystals and specifically their dissolution and crystallization kinetics are responsible for the damage. Using magnetic resonance imaging and optical microscopy we show that when water imbibes sodium sulfate contaminated sandstones, followed by drying at room temperature, large damage occurs in regions where pores are fully filled with salts. After partial dissolution, anhydrous sodium sulfate salt present in these regions gives rise to a very rapid growth of the hydrated phase of sulfate in the form of clusters that form on or close to the remaining anhydrous microcrystals. The rapid growth of these clusters generates stresses in excess of the tensile strength of the stone leading to the damage. Sodium chloride only forms anhydrous crystals that consequently do not cause damage in the experiments

Uniqueness of solutions of the stochastic Navier-Stokes equation with invariant measure given by the enstrophy

A stochastic Navier-Stokes equation with space-time Gaussian white noise is considered, having as infinitesimal invariant measure a Gaussian measure \mu_{\nu} whose covariance is given in terms of the enstrophy. Pathwise uniqueness for \mu_{\nu}-a.e. initial velocity is proven for solutions having \mu_{\nu} as invariant measure.Comment: Published by the Institute of Mathematical Statistics (http://www.imstat.org) in the Annals of Probability (http://www.imstat.org/aop/) at http://dx.doi.org/10.1214/00911790400000037

On the origin of the extremely different solubilities of polyethers in water

The solubilities of polyethers are surprisingly counter-intuitive. The best-known example is the difference between polyethylene glycol ([–CH2–CH2–O–]n) which is infinitely soluble, and polyoxymethylene ([–CH2–O–]n) which is completely insoluble in water, exactly the opposite of what one expects from the C/O ratios of these molecules. Similar anomalies exist for oligomeric and cyclic polyethers. To solve this apparent mystery, we use femtosecond vibrational and GHz dielectric spectroscopy with complementary ab initio calculations and molecular dynamics simulations. We find that the dynamics of water molecules solvating polyethers is fundamentally different depending on their C/O composition. The ab initio calculations and simulations show that this is not because of steric effects (as is commonly believed), but because the partial charge on the O atoms depends on the number of C atoms by which they are separated. Our results thus show that inductive effects can have a major impact on aqueous solubilities

Detection of Volatile Organic Compounds in Upland peat by Means of Proton-transfer-reaction Mass Spectrometry

This research represents the results of the detection of volatile organic compounds (VOCs) in the sphagnum moss and peat from two upland bogs located in Germany. Proton-transfer-reaction mass spectrometry (PTR-MS), used for the research, is a high-sensitive method, which permit to detect low concentrations of VOCs in ambient air. Along with natural VOCs of peat plants (generally sphagnum moss), the results of the study showed the presence of anthropogenic VOCs emissions like butanol, toluene, and benzene. This fact testifies about the capability of peat moss to accumulate these compounds. Possible sources of these VOCs in the peat samples can be agricultural machines and the traffic of the nearest roads

Aging of rotational diffusion in colloidal gels and glasses

We study the rotational diffusion of aging Laponite suspensions for a wide range of concentrations using depolarized dynamic light scattering. The measured orientational correlation functions undergo an ergodic to non-ergodic transition that is characterized by a concentration-dependent ergodicity-breaking time. We find that the relaxation times associated with rotational degree of freedom as a function of waiting time, when scaled with their ergodicity-breaking time, collapse on two distinct master curves. These master curves are similar to those previously found for the translational dynamics; The two different classes of behavior were attributed to colloidal gels and glasses. Therefore, the aging dynamics of rotational degree of freedom provides another signature of the distinct dynamical behavior of colloidal gels and glasses.Comment: 12 pages, 7 figure