Quantification of Iodine Supply: Representative Data on Intake and Urinary Excretion of Iodine from the German Population in 1996

Background/Methods: In Germany, iodine deficiency is common. In a representative group of 2,500 Germans (age >13 years), using a specially designed food questionnaire, the iodine intake was calculated. In addition, iodine and creatinine concentrations in spot urine samples were determined in three groups with a possibly increased risk of iodine deficiency (769 conscripts, 886 pairs of mothers and newborns) or future hyperthyroidism (574 adults, age range 50-70 years) from 26 representative regions. In four groups of controls (young and older male and female adults; n = 91), 24-hour urine iodine and creatinine were measured in six diurnal fractions to calculate group- and period-specific factors for the estimation of the 24-hour iodine excretion from data of iodine/creatinine ratio and time of micturition in spot urine samples. Results: The mean calculated iodine intake (excretion) was 119 mug/day for the group of Germans above 13 years; it was 119 mug/day (125 mug/day) for adults aged 50-70 years, 137 mug/day (125 mug/day)for conscripts, and 162 mug/day for breast-feeding mothers. The median iodine concentration (iodine/creatinine ratio) was 9.4 mug/dl (83 mug/g) in 566 adults aged 50-70 years, 8.3 mug/dl (57 mug/g) in 772 conscripts. and 5.6 mug/dl (156 mug/g) in 739 breast-fed newborns. Conclusions: Compared to older data, the iodine intake in Germany has increased. In 1996, the meticulously quantified average deficit was about 30% of the recommended iodine intake. Copyright (C) 2002 S. Karger AG, Basel

Comment on "Hole-Burning Experiments within Glassy Models with Infinite Range Interactions"

Comment on: L.F. Cugliandolo and J.L. Iguain; Phys. Rev. Lett. {\bf 85} 3448 (2000)Comment: 1 page, RevTe

Quantification of Iodine Supply: Representative Data on Intake and Urinary Excretion of Iodine from the German Population in 1996

Background/Methods: In Germany, iodine deficiency is common. In a representative group of 2,500 Germans (age >13 years), using a specially designed food questionnaire, the iodine intake was calculated. In addition, iodine and creatinine concentrations in spot urine samples were determined in three groups with a possibly increased risk of iodine deficiency (769 conscripts, 886 pairs of mothers and newborns) or future hyperthyroidism (574 adults, age range 50-70 years) from 26 representative regions. In four groups of controls (young and older male and female adults; n = 91), 24-hour urine iodine and creatinine were measured in six diurnal fractions to calculate group- and period-specific factors for the estimation of the 24-hour iodine excretion from data of iodine/creatinine ratio and time of micturition in spot urine samples. Results: The mean calculated iodine intake (excretion) was 119 mug/day for the group of Germans above 13 years; it was 119 mug/day (125 mug/day) for adults aged 50-70 years, 137 mug/day (125 mug/day)for conscripts, and 162 mug/day for breast-feeding mothers. The median iodine concentration (iodine/creatinine ratio) was 9.4 mug/dl (83 mug/g) in 566 adults aged 50-70 years, 8.3 mug/dl (57 mug/g) in 772 conscripts. and 5.6 mug/dl (156 mug/g) in 739 breast-fed newborns. Conclusions: Compared to older data, the iodine intake in Germany has increased. In 1996, the meticulously quantified average deficit was about 30% of the recommended iodine intake. Copyright (C) 2002 S. Karger AG, Basel

Translational and reorientational dynamics in carboxylic acid-based deep eutectic solvents

The glass formation and the dipolar reorientational motions in deep eutectic solvents (DESs) are frequently overlooked, despite their crucial role in defining the room-temperature physiochemical properties. To understand the effects of these dynamics on the ionic conductivity and their relation to the mechanical properties of the DES, we conducted broadband dielectric and rheological spectroscopy over a wide temperature range on three well-established carboxylic-acid-based natural DESs: These are the eutectic mixtures of choline chloride with oxalic acid (oxaline), malonic acid (maline), and phenylacetic acid (phenylaceline). In all three DESs, we observe signs of a glass transition in the temperature dependence of their dipolar reorientational and structural dynamics, as well as varying degrees of motional decoupling between the different observed dynamics: Maline and oxaline display a breaking of the Walden rule near the glass-transition temperature, while the relation between the dc conductivity and dipolar relaxation time in both maline and phenylaceline is best described by a power law. The glass-forming properties of the investigated systems not only govern the orientational dipolar motions and rheological properties, which are of interest from a fundamental point of view, but they also affect the dc conductivity, even at room temperature, which is of high technical relevance

Ionic conductivity in Li2O-Al2O3-SiO2 based glasses and glass ceramics

The complex conductivity of lithium aluminosilicate based glasses and glass-ceramics (Zerodur from Schott) has been investigated in a broad range of temperatures (200 K &lt; T &lt; 700 K) and frequencies (10 mHz&lt;v&lt;2.5 THz). The data are presented in terms of the conductivity and the electrical modulus formalisms. The width of the modulus loss peak as measured for the ceramic sample is broader than that determined for its precursor glass. This result is shown to be associated with the considerably smaller dc conductivity of this material.</jats:p

Shear and dielectric responses of propylene carbonate, tripropylene glycol, and a mixture of two secondary amides

Propylene carbonate and a mixture of two secondary amides, N-methylformamide and Nethylacetamide, are investigated by means of broadband dielectric and mechanical shear spectroscopy. The similarities between the rheological and the dielectric responses of these liquids and of the previously investigated tripropylene glycol are discussed within a simple approach that employs an electrical circuit for describing the frequency-dependent behavior of viscous materials. The circuit is equivalent to the Gemant-DiMarzio-Bishop model, but allows for a negative capacitive element. The circuit can be used to calculate the dielectric from the mechanical response and vice versa. Using a single parameter for a given system, good agreement between model calculations and experimental data is achieved for the entire relaxation spectra, including secondary relaxations and the Debye-like dielectric peak in the secondary amides. In addition, the predictions of the shoving model are confirmed for the investigated liquids

Invariance of the Local Segmental Relaxation Dispersion in Polycyclohexylmethacrylate / Poly-alpha-Methylstyrene Blends

Dielectric spectroscopy was carried out on polycyclohexylmethacrylate (PCHMA) and its blend with poly-alpha-methylstyrene (PaMS) as a function of temperature and pressure. When measured at conditions whereby the local segmental relaxation time for the PCHMA was constant, the dispersion in the loss spectra had a fixed shape; that is, the relaxation time determines the breadth of the relaxation time distribution, independently of T and P. This result is known for neat materials and could be observed for the blend herein due to the nonpolar character of the PaMS and the degree of thermodynamic miscibility of the blend.Comment: 13 pages 5 figure

NMR and conductivity studies of the mixed glass former effect in lithium borophosphate glasses

Alkali ion charge transport has been studied in a series of mixed glass former lithium borophosphate glasses of composition 0.33Li2O + 0.67[xB2O3 + (1 – x)P2O5]. The entire concentration range, 0.0 ≤ x ≤ 1.0, from pure glassy Li2P4O11 to pure glassy Li2B4O7 has been examined while keeping the molar fraction of Li2O constant. Electrical conductivity measurements and nuclear magnetic resonance techniques such as spin relaxometry, line shape analysis, and stimulated-echo spectroscopy were used to examine the temperature and frequency dependence of the Li+ ion motion over wide ranges of time scale and temperature. By accurately determining motional time scales and activation energies over the entire composition range the ion dynamics and the charge transport are found to be fastest if the borate and the phosphate fractions are similar. The nonlinear variation of the charge conduction, the most notable feature of the mixed glass former effect, is discussed in terms of the composition dependence of network former units which determine the local glass structure

Landscape equivalent of the shoving model

It is shown that the shoving model expression for the average relaxation time of viscous liquids follows largely from a classical "landscape" estimation of barrier heights from curvature at energy minima. The activation energy involves both instantaneous bulk and shear moduli, but the bulk modulus contributes less than 8% to the temperature dependence of the activation energy. This reflects the fact that the physics of the two models are closely related.Comment: 4 page