Double Carbon−Hydrogen Activation of 2-Vinylpyridine: Synthesis of Tri- and Pentanuclear Clusters Containing the μ-NC\u3csub\u3e5\u3c/sub\u3eH\u3csub\u3e4\u3c/sub\u3eCH═C Ligand

Reactions of 2-vinylpyridine with the triruthenium complexes [Ru3(CO)12] and [Ru3(CO)10(μ-dppm)] leads to a previously unknown double carbon−hydrogen bond activation of the β-carbon of the vinyl group to afford the pentaruthenium and triruthenium complexes [Ru5(CO)14(μ4-C5H4CH═C)(μ-H)2] (1) and [Ru3Cl(CO)5(μ-CO)(μ-dppm)(μ3-NC5H4CH═C)(μ-H)] (2), respectively. Crystal structures reveal two different forms of bridging of the dimetalated 2-vinylpyridyl ligand, capping a square face in 1 and a triangular face in 2

Precursors, black holes, and a locality bound

We revisit the problem of precursors in the AdS/CFT correspondence. Identification of the precursors is expected to improve our understanding of the tension between holography and bulk locality and of the resolution of the black hole information paradox. Previous arguments that the precursors are large, undecorated Wilson loops are found to be flawed. We argue that the role of precursors should become evident when one saturates a certain locality bound. The spacetime uncertainty principle is a direct consequence of this bound.Comment: 26 pages, 8 figs; reference added, minor clarification in sec. 2; incorrect draft mistakenly used in version

Supplementing a-Linolenic acid in the in vitro maturation media improves nuclear maturation rate of oocytes and early embryonic development in the Nili Ravi buffalo

The present study was conducted to investigate the effect of omega-3 poly unsaturated fatty acid (PUFA), α-linolenic acid (ALA; 18:3 n-3) on the in vitro maturation (IVM) of buffalo oocytes and subsequent embryonic development. Buffalo cumulusoocyte complexes (COCs; n = 2282) were in vitro matured in TCM-199 (0.6% fatty acid free bovine serum albumin, 0.02 Units/ml FSH, 1 µg/ml 17-β-estradiol, 10 µg/ml epidermal growth factor, 50 µg/ml gentamicin) supplemented with 0 (control), 25, 50, 100, 150 or 300 µm ALA under an atmosphere of 5% CO2 in air at 38.5ºC for 22-24 h. The matured oocytes were then fertilized in Tyrode’s Albumin Lactate Pyruvate (TALP) medium and cultured in synthetic oviductal fluid (SOF) medium. Concentrations up to 100 μm ALA improves (P ≤ 0.05) the cumulus expansion compared to control. Higher percentage of oocytes reaching MII stage was observed at 50 μm and 100 μm of ALA compared to control (P ≤ 0.05). Concentrations of 150 and 300 µm ALA were detrimental both for cumulus expansion and nuclear maturation rate of buffalo oocytes. Moreover, supplementation with 100 μm ALA improved (P ≤ 0.05) cleavage rate compared to control and treatment with 50 and 100 μm ALA yielded significantly higher morulae compared to control. The results of present study indicate that the supplementation with 100 μm ALA to the IVM medium improves nuclear maturation rate of buffalo oocytes and subsequent early embryonic development

Agito (Agility Non-Thermal Wind Offensive) Sebagai Pendeteksi Cuaca Kota Balikpapan Menggunakan Gnss Wind Turbine

Balikpapan sebagai salah satu kota di Kalimantan Timur, merupakan kota dengan karakteristik wilayah cukup unik, kondisi topografi wilayah terdiri dari daerah pesisir dengan daratan yang berbukit, potensi angin yang dapat dimanfaatkan. Berdasarkan data Bappeda kota Balikpapan menjelaskan bahwa topografi Balikpapan yang hampir seluruhnya berbukit (85%), serta ketinggian wilayah kota Balikpapan dari permukaan air laut berkisar 0–80 meter. Karakteristik wilayah, ketinggian daerah dari permukaan laut merupakan salah satu faktor yang  berpengaruh  pada unsur curah hujan dan suhu yang ada, sehingga mempengaruhi cuaca kota Balikpapan yang tidak menentu. Berdasarkan fenomena cuaca tersebut, menjadi sebuah objek penelitian kami dalam mengetahui cuaca berdasarkan tingkat kecepatan angin dipesisir pantai MONPERA. Penelitian ini menggunakan media alat yang menunjang dalam pengambilan data penelitian yaitu AGITO sehingga akan didapatkan berupa hasil data berupa suhu, kelembaban, dan kecepatan angin daerah tersebut. Data yang ada akan diolah sehingga dapat diketahui bahwa dalam mendeteksi cuaca Kota Balikpapan dapat dikategorikan yaitu cuaca cerah, jika suhu ≥25˚C, kelembaban <88%, dan kecepatan angin cenderung naik, serta cuaca dideteksi hujan jika suhu ≤25 ˚C, kelembaban ≥88%, dan kecepatan angin cenderung turun

Modeling signal-to-noise ratio of otoacoustic emissions in workers exposed to different industrial noise levels

Introduction: Noise is considered as the most common cause of harmful physical effects in the workplace. A sound that is generated from within the inner ear is known as an otoacoustic emission (OAE). Distortion-product otoacoustic emissions (DPOAEs) assess evoked emission and hearing capacity. The aim of this study was to assess the signal-to-noise ratio in different frequencies and at different times of the shift work in workers exposed to various levels of noise. It was also aimed to provide a statistical model for signal-to-noise ratio (SNR) of OAEs in different frequencies based on the two variables of sound pressure level (SPL) and exposure time. Materials and Methods: This case-control study was conducted on 45 workers during autumn 2014. The workers were divided into three groups based on the level of noise exposure. The SNR was measured in frequencies of 1000, 2000, 3000, 4000, and 6000 Hz in both ears, and in three different time intervals during the shift work. According to the inclusion criterion, SNR of 6 dB or greater was included in the study. The analysis was performed using repeated measurements of analysis of variance, spearman correlation coefficient, and paired samples t-test. Results: The results showed that there was no statistically significant difference between the three exposed groups in terms of the mean values of SNR (P > 0.05). Only in signal pressure levels of 88 dBA with an interval time of 10:30-11:00 AM, there was a statistically significant difference between the right and left ears with the mean SNR values of 3000 frequency (P = 0.038). The SPL had a significant effect on the SNR in both the right and left ears (P = 0.023, P = 0.041). The effect of the duration of measurement on the SNR was statistically significant in both the right and left ears (P = 0.027, P < 0.001). Conclusion: The findings of this study demonstrated that after noise exposure during the shift, SNR of OAEs reduced from the beginning to the end of the shift

Understanding the effect of water on the transient decomposition of zinc dialkyldithiophosphate (ZDDP)

The effect of water on the transient kinetics of the decomposition reaction of zinc dialkyldithiophosphate (ZDDP) additive has been investigated using X-ray photoelectron spectroscopy (XPS). Water was found to have a long-lasting detrimental effect on ZDDP triboreactive film layers by changing their composition depending on their proximity to the metal surface. Particularly, water impeded the polymerisation reaction in the top layers, which results in the formation of short zinc (thio)phosphate chains. The most probable explanation for this was related to the formation of a single or multiple bridges between water molecules and PO2 groups of the decomposed ZDDP. This caging effect, which does not fade away as water evaporates, can suppress the chemical reactivity of these groups to a great extent, which in turn can hinder their polymerisation into long phosphate chains

Kurt Symanzik - a stable fixed point beyond triviality

In 1970 Kurt Symanzik proposed a "precarious" phi**4-theory with a negative quartic coupling constant as a valid candidate for an asymptotically free theory of strong interactions. Symanzik's deep insight in the non-trivial properties of this theory has been overruled since then by the Hermitian intuition of generations of scientists, who considered or consider this actually non-Hermitian highly important theory to be unstable. This short - certainly controversial - communication tries to shed some light on the historical and formalistic context of Symanzik's theory in order to sharpen our (quantum) intuition about non-perturbative theoretical physics between (non)triviality and asymptotic freedom.Comment: 6 pages, no figures, new style files, revised for typos, improved discussion, new references adde

Crops For the Future (CFF): an overview of research efforts in the adoption of underutilised species

Main conclusion Crops For the Future (CFF), as an entity, has established a broad range of research activities to promote the improvement and adoption of currently underutilised crops. Abstract This paper summarises selected research activities at Crops For the Future (CFF) in pursuit of its mission 'to develop solutions for diversifying future agriculture using underutilised crops'. CFF is a research company focussed on the improvement of underutilised crops, so that they might be grown and consumed more widely with benefits to human food and nutritional security; its founding guarantors were the Government of Malaysia and the University of Nottingham. From its base in Malaysia, it engages in research around the world with a focus on species and system diversification. CFF has adopted a food system approach that adds value by delivering prototype food, feed and knowledge products. Bambara groundnut (Vigna subterranea) was adopted as an exemplar crop around which to develop CFF's food system approach with emphasis on the short-day photoperiod requirement for pod-filling and the hard-to-cook trait. Selective breeding has allowed the development of lines that are less susceptible to photoperiod but also provided a range of tools and approaches that are now being exploited in other crops such as winged bean (Psophocarpus tetragonolobus), amaranth (Amaranthus spp.), mor-inga (Moringa oleifera) and proso (Panicum miliaceum) and foxtail (Setaria italica) millets. CFF has developed and tested new food products and demonstrated that several crops can be used as feed for black soldier fly which can, in turn, be used to feed fish thereby reducing the need for fishmeal. Information about underutilised crops is widely dispersed; so, a major effort has been made to develop a knowledge base that can be interrogated and used to answer practical questions about potential exploitation of plant and nutritional characteristics. Future research will build on the success with Bambara groundnut and include topics such as urban agriculture, rural development and diversification, and the development of novel foods. CFF's remit and research objective