A NOVEL SYNTHETIC PROTOCOL FOR THE BIS-TRIAZOLONES DERIVATIVES THROUGH CORRESPONDING N1-ETHOXYCARBONYL-N1-TOSYLHYDRAZONATES

A simple method has been developed for the synthesis of bis-triazolones 2a-n starting from N1-ethoxycarbonyl-N1-tosylhydrazonates 1 and aliphatic diamine. It affords a number of bis-triazolones 2a-n  in reasonable yields. The structures of all new compounds were elucidated using infrared, 1H and 13C NMR studies as well as elemental analysis. Some of these reactions provide successful means to produce biologically important structures

Synthesis and crystal structure of N1-tosylacetylamidrazone

The condensation of two molar equivalents of N1-tosylhydrazonate 1 with one molar equivalent of 1,2-diaminoethane give birth to amidrazone in good yields. The structure of the synthesized compound was identified by X-ray diffraction, IR spectroscopy and nuclear magnetic resonance.Â