Method of heat treating a formed powder product material

Heat treating a product material of prealloyed powders after shaping by superplastic deformation restores the ability of the material to resist deformation at high temperatures. Heat treating is accomplished by heating to a temperature between the solidus and liquidus with the application of isostatic pressure to close any voids. This pressure may be simultaneously applied while the material is at the heat treating temperature. The pressure may also be applied when the material cools to a temperature between that at which it is shaped and the solidus

New cobalt alloys have high-temperature strength and long life in vacuum environments

Cobalt refractory metal alloys combine sheet formability with high temperature strength and low material loss in vacuum

Method of forming articles of manufacture from superalloy powders

A highly alloyed superalloy material is obtained using prealloyed powders. The material is easily shaped at high temperatures when it becomes superplastic because of its particular microstructure

High strength alloy for immediate temperature, 24 24 to 704 C (75 to 1300 F), applications

Application of prealloyed powder technology to the NASA-TRW-VI-A alloy shows the potential of highly alloyed normally cast superalloys for achieving superior properties at intermediate temperatures

Effect of cyclic conditions on the dynamic oxidation of gas turbine superalloys

The effects of operating parameters of a dynamic apparatus used to study oxidation and thermal fatigue of gas turbine materials were studied. IN-100, TD-NiCr, and WI-52 were tested at a maximum temperature of 1,090 deg C. Heating time per cycle was varied from 1/20 hr to 10 hr. Minimum temperatures between heating cycles were room temperature, 430 deg, and 650 deg C. Cooling air velocities were zero, Mach 0.7, and Mach 1. Increasing the number of cycles for a given time at temperature increased weight loss. Thermal fatigue was related to number of cycles more than to time at temperature

High-temperature strength of prealloyed-powder products increased by heat/pressure treatment

Heat treatment process involves heating products to a temperature above the solidus, and subsequently applying pressure at a temperature below the solidus. Technique can be modified to one step process involving simultaneous application if both high pressure and heat. Process is not limited to cobalt-base alloys

High temperature cobalt-base alloy Patent

High temperature cobalt-base alloy resistant to corrosion by liquid metals and to sublimation in vacuum environmen

Application of directional solidification to a NASA nickel-base alloy /TAZ-8B/

Directional solidification of nickel base alloy TAZ-8B to enhance potential for advanced gas turbine engine application

Evaluation of a cobalt-base alloy, HS-31, made by extrusion of prealloyed powders

Evaluation of cobalt base alloy made by extrusion of prealloyed powder

Calculating NMR parameters in aluminophosphates : evaluation of dispersion correction schemes

Periodic density functional theory (DFT) calculations have recently emerged as a popular tool for assigning solid-state nuclear magnetic resonance (NMR) spectra. However, in order for the calculations to yield accurate results, accurate structural models are also required. In many cases the structural model (often derived from crystallographic diffraction) must be optimised (i.e., to an energy minimum) using DFT prior to the calculation of NMR parameters. However, DFT does not reproduce weak long-range "dispersion'' interactions well, and optimisation using some functionals can expand the crystallographic unit cell, particularly when dispersion interactions are important in defining the structure. Recently, dispersion-corrected DFT (DFT-D) has been extended to periodic calculations, to compensate for these missing interactions. Here, we investigate whether dispersion corrections are important for aluminophosphate zeolites (AlPOs) by comparing the structures optimised by DFT and DFT-D (using the PBE functional). For as-made AlPOs (containing cationic structure-directing agents (SDAs) and framework-bound anions) dispersion interactions appear to be important, with significant changes between the DFT and DFT-D unit cells. However, for calcined AlPOs, where the SDA-anion pairs are removed, dispersion interactions appear much less important, and the DFT and DFT-D unit cells are similar. We show that, while the different optimisation strategies yield similar calculated NMR parameters (providing that the atomic positions are optimised), the DFT-D optimisations provide structures in better agreement with the experimental diffraction measurements. Therefore, it appears that DFT-D calculations can, and should, be used for the optimisation of calcined and as-made AlPOs, in order to provide the closest agreement with all experimental measurements.PostprintPeer reviewe