Generation of Free Carriers in MoSe2 Monolayers Via Energy Transfer from CsPbBr3 Nanocrystals

Transition metal dichalcogenide (TMDCs) monolayers make an excellent component in optoelectronic devices such as photodetectors and phototransistors. Selenide-based TMDCs, specifically molybdenum diselenide (MoSe2) monolayers with low defect densities, show much faster photoresponses compared to their sulfide counterpart. However, the typically low absorption of the atomically thin MoSe2 monolayer and high exciton binding energy limit the photogeneration of charge carriers. Yet, integration of light-harvesting materials with TMDCs can produce increased photocurrents via energy transfer. In this article, it is demonstrated that the interaction of cesium lead bromide (CsPbBr3) nanocrystals with MoSe2 monolayers results into an energy transfer efficiency of over 86%, as ascertained from the quenching and decay dynamics of the CsPbBr3 nanocrystals emission. Notably, the increase in the MoSe2 monolayer emission in the heterostructure accounts only for 33% of the transferred energy. It is found that part of the excess energy generates directly free carriers in the MoSe2 monolayer, as a result of the transfer of energy into the exciton continuum. The efficiency of the heterostructure via enhanced photocurrents with respect to the single material unit is proven. These results demonstrate a viable route to overcome the high exciton binding energy typical for TMDCs, as such having an impact on optoelectronic processes that rely on efficient exciton dissociation

Examining queue-jumping phenomenon in heterogeneous traffic stream at signalized intersection using UAV-based data

© 2020, Springer-Verlag London Ltd., part of Springer Nature. This research presents an in-depth microscopic analysis of heterogeneous and undisciplined traffic at the signalized intersection. Traffic data extracted from the video recorded using an unmanned aerial vehicle (UAV) at an approach of a signalized intersection is analyzed to study the within green time dynamics of traffic flow. Various parameters of Wiedemann 74, Wiedemann 99, and lateral behavior models used in microscopic traffic simulation package, Vissim, are calibrated for the local heterogeneous traffic. This research is aimed at exploring the queue-jumping phenomenon of motorbikes at signalized intersections and its impact on the saturation flow rate, travel time, and delay. The study of within green time flow dynamics shows that the flow of traffic within green time is not uniform. Surprisingly, the results indicate that the traffic flow for the first few seconds of the green time is significantly higher than the remaining period of green time, which shows a contradiction to the fact that traffic flow for the first few seconds is lower due to accelerating vehicles. Mode-wise traffic counted per second shows that this anomaly is attributed to the presence of motorbikes in front of the queue. Consequently, the outputs of simulation results obtained from calibrated Vissim show that the simulated travel time for motorbikes is significantly lower than the field-observed travel times even though the average simulated traffic flow matches accurately with the field-observed traffic flow. The findings of this research highlight the need to incorporate the queue-jumping behavior of motorbikes in the microsimulation packages to enhance their capability to model heterogeneous and undisciplined traffic

Numerical solution of the blasius equation with Crocco-Wang transformation

This paper presents a direct second-order finite-difference solution of the two-point boundary value problem derived from the classical third-order Blasius problem using the Crocco-Wang transformation. Noting the end-point singularity introduced by the Crocco-Wang transformation due to a zero boundary condition, the method provides special handling of this singularity to ensure second-order accuracy. Additionally, the method uses an extrapolation procedure to obtain results of increased accuracy. We compare our computed solution with an approximate analytical solution and numerical solutions previously reported and find that our results are in excellent agreement

New approximations for block sorting

We develop, present, and analyze a simple, new 2-approximation algorithm for block sorting in which we use a newly introduced combinatorial structure called an ordered pair. Our algorithm achieves the best known approximation ratio of 2, the tightest known upper bound in terms of the number of block moves needed for block sorting

Erratum to: New approximations for block sorting (Netw Model Anal Health Inform Bioinforma, (2016), 5, (6), 10.1007/s13721-016-0113-x)

Figure 1 of the original article should “credit: Anthony Labarre”. The below given Fig. 1 is the “Picture by Anthony Labarre, taken from URL”. (Figure presented.

Effect of curbside bus stops on passenger car units and capacity in disordered traffic using simulation model

Representation of traffic in terms of Passenger Car Unit (PCU) is imperative to estimate capacity in disordered traffic. Many studies have been conducted on investigation of impacts of traffic and geometric conditions on traffic characteristics and PCUs. However, the sensitivity of PCUs due to roadside frictions are not adequately studied. To address this gap, this study aims to estimate PCU values for vehicles under the influence of curbside bus stop, which is the most common roadside friction in developing countries. Lack of space for providing exclusive bus bays and higher demand for public transport buses in urban roads justify the need for this study. Methodology of this study involves development and validation of a microscopic simulation model to quantify the impact of curbside bus stop on PCU as well as capacity. The results indicate the significant differences in PCU values due to the presence of curbside bus stop with varying traffic volume and composition

Investigation of mass transfer intensification under power ultrasound irradiation using 3D computational simulation: A comparative analysis

This paper aims at investigating the influence of acoustic streaming induced by low-frequency (24 kHz) ultrasound irradiation on mass transfer in a two-phase system. The main objective is to discuss the possible mass transfer improvements under ultrasound irradiation. Three analyses were conducted: i) experimental analysis of mass transfer under ultrasound irradiation; ii) comparative analysis between the results of the ultrasound assisted mass transfer with that obtained from mechanically stirring; and iii) computational analysis of the systems using 3D CFD simulation. In the experimental part, the interactive effects of liquid rheological properties, ultrasound power and superficial gas velocity on mass transfer were investigated in two different sonicators. The results were then compared with that of mechanical stirring. In the computational part, the results were illustrated as a function of acoustic streaming behaviour, fluid flow pattern, gas/liquid volume fraction and turbulence in the two-phase system and finally the mass transfer coefficient was specified. It was found that additional turbulence created by ultrasound played the most important role on intensifying the mass transfer phenomena compared to that in stirred vessel. Furthermore, long residence time which depends on geometrical parameters is another key for mass transfer. The results obtained in the present study would help researchers understand the role of ultrasound as an energy source and acoustic streaming as one of the most important of ultrasound waves on intensifying gas-liquid mass transfer in a two-phase system and can be a breakthrough in the design procedure as no similar studies were found in the existing literature