Calorimetric and acoustic study of binary mixtures containing an isomeric chlorobutane and butyl ethyl ether or methyl tert-butyl ether

Densities and speeds of sound in the temperature range 283.15-313.15 K have been measured for the binary mixtures formed by an isomeric chlorobutane (1-chlorobutane, 2-chlorobutane, 1-chloro-2-methylpropane, or 2-chloro-2-methylpropane) and butyl ethyl ether or methyl tert-butyl ether. Excess isentropic compressibilities were calculated from the experimental data. Excess enthalpies at T = 298.15 K are also included for the same binary mixtures. All these properties provide an insight into the nature of interactions operating on the present systems. Finally, the Prigogine-Flory-Patterson theory has been used to analyze the H E results and to estimate the isentropic compressibility values of the mixtures at T = 298.15 K

Thermophysical study of 2-acetylthiophene: experimental and modelled results

Several thermophysical properties have been studied for 2-acetylthiophene: (i) vapour pressure was determined at temperatures within 336.16–445.02 K; (ii) density, speed of sound, static permittivity, refractive index, surface tension, and kinematic viscosity were measured at p = 0.1 MPa and at temperatures from 278.15 K (or 283.15 K for the refractive index) to 338.15 K; (iii) volumetric properties were also determined at temperatures in the (283.15–338.15) K range and at pressures up to 65.0 MPa. From these experimental values, different derivative properties have been calculated such as enthalpy of vaporization, isobaric expansibility, isothermal and isentropic compressibility, dipole moment, entropy and enthalpy of surface formation, and dynamic viscosity. All experimental properties were correlated and the results were explained through the intermolecular interactions. Moreover PC-SAFT EoS was used to model the thermodynamic behaviour of the compound. Finally, this EoS combined with the Density Gradient Theory allowed obtaining the influence parameter for the surface tension of 2-acetylthiophene

Optical Bistability in Nonlinear Optical Coupler with Negative Index Channel

We discuss a novel kind of nonlinear coupler with one channel filled with a negative index material (NIM). The opposite directionality of the phase velocity and the energy flow in the NIM channel facilitates an effective feedback mechanism that leads to optical bistability and gap soliton formation

Secuenciación del ITS-1 del ADN ribosomal de Galba truncatula (Gastropoda, Lymnaeidae) y su impacto potencial en la transmisión de la fascioliasis en Mendoza, Argentina

Sequencing of the rDNA ITS–1 proved that the lymnaeid snail species Galba truncatula is present in Argentina and that it belongs to the haplotype HC, the same as that responsible for the fascioliasis transmission in the human hyperendemic area with the highest human prevalences and intensities known, the Northern Bolivian Altiplano.La secuenciación del ITS–1 del ADNr demostró que la especie de gasterópodo lymnaeido Galba truncatula se encuentra en Argentina y que pertenece al haplotipo HC, el mismo responsable de la transmisión de la fascioliasis en el área de hiperendemia humana con las mayores prevalencias e intensidades de fascioliasis conocidas, el Altiplano Norte Boliviano

On the termination of deep-sea fan channels: Examples from the Rhone Fan (Gulf of Lion, Western Mediterranean Sea)

The termination of a deep-sea turbiditic channel represents the ultimate sink of terrigenous sediment in the oceans or lakes. Such environment is characterized by rapid slope decrease and by loss of confinement of turbidity currents. It results in the deposition of Channel-Mouth-Lobes that can be separated from the channel mouth by an erosional (scoured) or by-pass dominated Channel-Lobe Transition Zone. Several factors can control the occurrence, extent and morphologic expression of the area such as the slope break angle, the upslope and downslope angle and the mud/sand ratio in flows. Disentangling these factors remains challenging due to the scarcity of outcrops and to the usual faint morphologies and low thickness of deposits. With bathymetric and seismic data we calculated the morphometric parameters of 8 channel-levees and their Channel-Mouth Lobes from the deepest area of the Rhone fan, a mud-sand rich system, and among which the youngest one (called neofan) was deposited at the end of the Last Glacial Maximum between 21.5 and 18.3 ka cal. BP. Emplacement and shape (finger-shaped or pear-shaped bulges) of Channel-Mouth Lobes is controlled by the seabed morphology (adjacent channel-levees and salt diapirs). A less prominent morphology of the neofan is attributed to premature quiescence related to the post sea-level rise sediment starvation. We show that the occurrence and expression of a Channel-Lobe Transition Zone is controlled by the gradient upstream of the channel mouth slope break. The extended Channel-Lobe Transition Zone and detached lobe of the neofan are attributed to the high upslope gradient (0.26°) while the less detached or attached lobes of other channel-levees is attributed to lower upslope gradient (0.13°). We show that scouring and scours concatenation into flutes at the Channel-Lobe Transition Zone is a major driver for the inception of channels and further confinement of turbidity current. For the first time we show that concatenation of scours in shingled disposition developed an incipient channel sinuosity at this very early stage of channel development. The channel-levee can extend downslope nearly instantaneously by tens of kilometers when isolated nascent channels connect to the channel mouth

Role of quantum coherence in chromophoric energy transport

The role of quantum coherence and the environment in the dynamics of excitation energy transfer is not fully understood. In this work, we introduce the concept of dynamical contributions of various physical processes to the energy transfer efficiency. We develop two complementary approaches, based on a Green's function method and energy transfer susceptibilities, and quantify the importance of the Hamiltonian evolution, phonon-induced decoherence, and spatial relaxation pathways. We investigate the Fenna-Matthews-Olson protein complex, where we find a contribution of coherent dynamics of about 10% and of relaxation of 80%.Comment: 5 pages, 3 figures, included static disorder, correlated environmen

Biophysics - Quantum path to photosynthesis

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/62904/1/446740a.pd

Quantum entanglement in photosynthetic light harvesting complexes

Light harvesting components of photosynthetic organisms are complex, coupled, many-body quantum systems, in which electronic coherence has recently been shown to survive for relatively long time scales despite the decohering effects of their environments. Within this context, we analyze entanglement in multi-chromophoric light harvesting complexes, and establish methods for quantification of entanglement by presenting necessary and sufficient conditions for entanglement and by deriving a measure of global entanglement. These methods are then applied to the Fenna-Matthews-Olson (FMO) protein to extract the initial state and temperature dependencies of entanglement. We show that while FMO in natural conditions largely contains bipartite entanglement between dimerized chromophores, a small amount of long-range and multipartite entanglement exists even at physiological temperatures. This constitutes the first rigorous quantification of entanglement in a biological system. Finally, we discuss the practical utilization of entanglement in densely packed molecular aggregates such as light harvesting complexes.Comment: 14 pages, 7 figures. Improved presentation, published versio