Synthesis and photophysical studies of monocarboxy phthalocyanines containing quaternizable groups

This work reports on the synthesis and photophysical properties of novel unsymmetrically substituted monocarboxy magnesium (MgPc, 3), aluminum (ClAlPc, 4) and unmetallated (H2Pc, 5) phthalocyanines. Magnesium phthalocyanine (3) was converted into water soluble quaternized derivative (QMgPc, 6) by reaction with methyl iodide. The synthesized phthalocyanines were characterized by IR, UV–Vis, NMR, mass spectrometry and elemental analyses. Photophysical and photochemical studies were carried out in order to determine the potential of the complexes as photosensitizers for use in photodynamic therapy. Triplet quantum yields ranged from 0.37 to 0.40 and triplet lifetimes from 110 to 140 μs in DMSO

Synthesis and photophysical properties of peripherally and non-peripherally mercaptopyridine substituted metal free, Mg (II) and Al (III) phthalocyanines

The syntheses and photophysical properties of metallophthalocyanines containing Mg2+ and Al3+ as central metal ions and their unmetallated derivative (complexes 3–8) tetra- substituted at the non-peripheral (α) and peripheral (β) positions with 2-mercaptopyridine are reported. The trends in triplet and fluorescence quantum yields are described for these compounds. The complexes exhibited relatively high triplet quantum yields (ΦT) ranging from 0.33 to 0.54 and fluorescence quantum yields (ΦF) ranging from 0.02 to 0.29. Triplet state lifetimes of the complexes were long ranging from 120 to 460 μs, indicating a potential use of these complexes as photosensitizers

Spectral properties and photophysical behaviour of water soluble cationic Mg (II) and Al (III) phthalocyanines

Peripherally and non-peripherally tetrasubstituted-[(N-methyl-2-pyridylthio)]phthalocyaninato magnesium (II) (5 and 6) and chloro aluminium (III) (7 and 8) tetraiodide have been synthesized and characterized. The photophysical properties of the complexes in dimethyl sulfoxide (DMSO) and aqueous medium in the presence and absence of cremophore EL have been studied. These complexes show high solubility in aqueous medium though they were aggregated. The triplet state quantum yields (FT) and the triplet lifetimes (tT) were found to be higher in DMSO with ΦT ranging from 0.32 to 0.51, while tT ranged from 282 to 622 ms in DMSO, compared to aqueous medium (pH 7.4 buffer) where ΦT ranged from 0.15 to 0.19 and tT from 26 to 35 ms. Addition of cremophore EL in aqueous solution resulted in partial disaggregation and increased photoactivity. The fluorescence lifetimes of the complexes showed strong dependence on their immediate environment. The ionic magnesium(II) and aluminium(III) phthalocyanines strongly bind to bovine serum albumin (BSA)

Thermoelectric Generators as an Alternative Energy Source in Shipboard Microgrids

In recent years, the usage potential of alternative energy sources has been gaining importance to increase the efficiency of ships within the scope of the obligations brought by international maritime regulations. The possibility of using alternative energy sources such as solar energy, wind energy, fuel cells, and waste heat recovery technologies on ships has been evaluated in the literature. Today, ships also have waste heat recovery systems as standard equipment for this purpose, and this method is suitable for thermoelectric generators that generate electricity from temperature differences on shipboards. This article aims to review the thermal technologies for the power generation of shipboards. By conducting a case study, an energy efficiency increase was obtained when functional areas were selected on a practical ship, and the effect of this efficiency increase on emissions was examined. As a result of the research, it was discovered that thermoelectric generators increased onboard energy efficiency and have significant potential for sustainability in the maritime sector

An analysis and comparison of multinational officers of the watch in the global maritime labor market

Officer of the watch (OOW) is an important part of the maritime labor market. For many years, countries have been improving their development of OOWs for the maritime market, in terms of both quantity and quality. As the supply of qualified OOWs for maritime transportation is such an important issue, shipping companies recruit multinational OOWs for both economic and socio-cultural reasons. This study aims to identify the qualifications of an ideal officer that holds office on commercial ships, and to make a comparison among Filipino, Chinese, Indian, Eastern European and Turkish OOWs. The research takes into account expert opinions of a number of shipping companies that employ multinational seafarers. A Fuzzy Analytic Hierarchy Process (FAHP) technique is applied in this study to assist in the comparison of officers. A number of main and sub-criteria are outlined to determine both positive and negative aspects of OOWs from the selected countries for decision making purposes. This study allows maritime countries to evaluate their maritime education and training policies for selection and assessment of OOWs. © 2019, © 2019 Informa UK Limited, trading as Taylor & Francis Group

Synthesis and photophysical studies of monocarboxy phthalocyanines containing quaternizable groups

This work reports on the synthesis and photophysical properties of novel unsymmetrically substituted monocarboxy magnesium (MgPc, 3), aluminum (ClAlPc, 4) and unmetallated (H2Pc, 5) phthalocyanines. Magnesium phthalocyanine (3) was converted into water soluble quaternized derivative (QMgPc, 6) by reaction with methyl iodide. The synthesized phthalocyanines were characterized by IR, UV–Vis, NMR, mass spectrometry and elemental analyses. Photophysical and photochemical studies were carried out in order to determine the potential of the complexes as photosensitizers for use in photodynamic therapy. Triplet quantum yields ranged from 0.37 to 0.40 and triplet lifetimes from 110 to 140 μs in DMSO

Prediction of Ship Main Particulars for Harbor Tugboats Using a Bayesian Network Model and Non-Linear Regression

Determining the key characteristics of a ship during the concept and preliminary design phases is a critical and intricate process. In this study, we propose an alternative to traditional empirical methods by introducing a model to estimate the main particulars of diesel-powered Z-Drive harbor tugboats. This prediction is performed to determine the main particulars of tugboats: length, beam, draft, and power concerning the required service speed and bollard pull values, employing Bayesian network and non-linear regression methods. We utilized a dataset comprising 476 samples from 68 distinct diesel-powered Z-Drive harbor tugboat series to construct this model. The case study results demonstrate that the established model accurately predicts the main parameters of a tugboat with the obtained average of mean absolute percentage error values; 6.574% for the Bayesian network and 5.795%, 9.955% for non-linear regression methods. This model, therefore, proves to be a practical and valuable tool for ship designers in determining the main particulars of ships during the concept design stage by reducing revision return possibilities in further stages of ship design

Characterization of 2,(3)-tetra-(4-oxo-benzamide) phthalocyaninato cobalt (II)—single walled carbon nanotube conjugate platforms and their use in electrocatalysis of amitrole

In this paper we report on the use of carboxylic acid functionalized single walled carbon nanotubes (SWCNT) in the synthesis of 2,(3)-tetra-(4-oxo-benzamide)phthalocyaninato cobalt (II)–single walled carbon nanotube conjugates (CoTOBPc–SWCNT), their characterization and application in the electrocatalytic oxidation of amitrole. Cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy were used for the detection of amitrole on the modified glassy carbon electrode. The catalytic rate constant was 1.6 × 103 M−1 s−1 and the apparent electron rate transfer constant was 1.5 × 10−5 cm s−1. The linear dynamic range was 1.0 × 10−6–3.0 × 10−5 M, with a sensitivity of ∼1.13 A mol−1 L cm−2