Scientific applications and advantages of a low-energy synchrotron radiation source

Abstract. Recent improvements to the synchrotron ultraviolet radiation facility led to unprecedented performance. High injection currents and beam stability, as well as tunable electron energies over a wide range make this storage ring a prime source for synchrotron radiation from the extreme-ultraviolet to far-infrared spectral regions. We will discuss plans to capitalize on this unprecedented performance through implementation of new experimental stations and extension of existing ones. It also will be shown that for applications using extremeultraviolet to infrared synchrotron radiation a low electron energy storage ring has distinct advantages

Mind the Gap: Persistent and Mobile Organic Compounds—Water Contaminants That Slip Through

The discharge of persistent and mobile organic chemicals (PMOCs) into the aquatic environment is a threat to the quality of our water resources. PMOCs are highly polar (mobile in water) and can pass through wastewater treatment plants, subsurface environments and potentially also drinking water treatment processes. While a few such compounds are known, we infer that their number is actually much larger. This Feature highlights the issue of PMOCs from an environmental perspective and assesses the gaps that appear to exist in terms of analysis, monitoring, water treatment and regulation. On this basis we elaborate strategies on how to narrow these gaps with the intention to better protect our water resources

Resonant inelastic x-ray scattering from molecules and atoms

X-ray fluorescence spectroscopy is one of the most powerful methods for the understanding of the electronic structure of matter. We report here on fluorescence experiments in the 2 to 6 keV photon energy range using tunable synchrotron radiation and the resulting experimental programs on resonant inelastic scattering in atoms and on polarization measurements in resonant molecular excitations

Abundances in bulge stars from high-resolution, near-IR spectra I. The CNO elements observed during the science verification of CRIRES at VLT

The formation and evolution of the Milky Way bulge is not yet well understood and its classification is ambiguous. Constraints can, however, be obtained by studying the abundances of key elements in bulge stars. The aim of this study is to determine the chemical evolution of CNO, and a few other elements in stars in the Galactic bulge, and to discuss the sensitivities of the derived abundances from molecular lines. High-resolution, near-IR spectra in the H band were recorded using VLT/CRIRES. Due to the high and variable visual extinction in the line-of-sight towards the bulge, an analysis in the near-IR is preferred. The CNO abundances can all be determined simultaneously from the numerous molecular lines in the wavelength range observed. The three giant stars in Baade's window presented here are the first bulge stars observed with CRIRES. We have especially determined the CNO abundances, with uncertainties of less than 0.20 dex, from CO, CN, and OH lines. Since the systematic uncertainties in the derived CNO abundances due to uncertainties in the stellar fundamental parameters, notably Teff, are significant, a detailed discussion of the sensitivities of the derived abundances is included. We find good agreement between near-IR and optically determined O, Ti, Fe, and Si abundances. Two of our stars show a solar [C+N/Fe], suggesting that these giants have experienced the first dredge-up and that the oxygen abundance should reflect the original abundance of the giants. The two giants fit into the picture, in which there is no significant difference between the O abundance in bulge and thick-disk stars. Our determination of the S abundances is the first for bulge stars. The high [S/Fe] values for all the stars indicate a high star-formation rate in an early phase of the bulge evolution.Comment: Accepted by A&

Gravitational Waveguides in Cosmology

We discuss the possibility that, besides the usual gravitational lensing, there may exist a sort of gravitational waveguiding in cosmology which could explain some anomalous phenomena which cannot be understood by the current gravitational lensing models as the existence of "brothers" objects having different brilliancy but similar spectra and redshifts posed on the sky with large angular distance. Furthermore, such a phenomena could explain the huge luminosities coming from quasars using the cosmological structures as selfoc-type or planar waveguide. We describe the gravitational waveguide theory and then we discuss possible realizations in cosmology.Comment: 14 pages, latex, submitted to Int. Jou. Mod. Phys.

Cosmological waveguides for gravitational waves

We study the linearized equations describing the propagation of gravitational waves through dust. In the leading order of the WKB approximation, dust behaves as a non-dispersive, non-dissipative medium. Taking advantage of these features, we explore the possibility that a gravitational wave from a distant source gets trapped by the gravitational field of a long filament of galaxies of the kind seen in the large scale structure of the Universe. Such a waveguiding effect may lead to a huge magnification of the radiation from distant sources, thus lowering the sensitivity required for a successful detection of gravitational waves by detectors like VIRGO, LIGO and LISA.Comment: 19 pages, compressed Latex fil

Effect of Parameters on Oxychlorination of Tert-Butyl Ethers

The effect of concentration, molar ratios of reagents, pH, and temperature on formation of chloro-organic products in reaction of tert-butyl ethers with chloride ions and hydrogen peroxide has been determined. A significant effect of Cl− ions and H2O2 molar ratios on the rate of chloro-organic product formation has been observed. Studies on oxychlorination of tert-butylethyl ether (ETBE) at pH 7, 3.5, and 2.5 have been carried out. It was found that introduction of hydronium ions into the reaction system considerably hastened the process of chloro-organic product formation. Hydronium ions contribute to the formation of the reactive tert-butyl carbocation, which undergoes secondary reactions in the presence of reactive forms of chlorine and oxygen. Moreover, the effect of temperature on ETBE (tert-butylethyl ether) and MTBE (tert-butylmethyl ether) conversions was verified. The reactions of MTBE and ETBE oxychlorination were carried out at temperatures of 5°C, 20°C, and 35°C