5,396 research outputs found
Vibronic structure of the second triplet state of 1,3,5-hexatriene
Electron impact spectroscopy is used to study the vibronic structive of the second triplet state of 1,3,5-hexatriene
Sputtered silicon nitride coatings for wear protection
Silicon nitride films were deposited by RF sputtering on 304 stainless steel substrates in a planar RF sputtering apparatus. The sputtering was performed from a Si3N4 target in a sputtering atmosphere of argon and nitrogen. The rate of deposition, the composition of the coatings, the surface microhardness and the adhesion of the coatings to the substrates were investigated as a function of the process parameters, such as: substrate target distance, fraction nitrogen in the sputtering atmosphere and sputtering pressure. Silicon rich coating was obtained for fraction nitrogen below 0.2. The rate of deposition decreases continuously with increasing fraction nitrogen and decreasing sputtering pressure. It was found that the adherence of the coatings improves with decreasing sputtering pressure, almost independently of their composition
Some properties of RF sputtered hafnium nitride coatings
Hafnium nitride coatings were deposited by reactive RF sputtering from a hafnium target in nitrogen and argon gas mixtures. The rate of deposition, composition, electrical resistivity and complex index of refraction were investigated as a function of target substrate distance and the fraction nitrogen, (fN2) in the sputtering atmosphere. The relative composition of the coatings is independent on fN2 for values above 0.1. The electric resistivity of the hafnium nitride films changes over 8 orders of magnitude when fN2 changes from 0.10 to 0.85. The index of refraction is almost constant at 2.8(1-0.3i) up to fN2 = 0.40 then decreases to 2.1(1 - 0.01i) for higher values of fN2
Doublet-->quartet transitions in nitric oxide as detected by electron-impact spectroscopy
Vibronic bands in NO are investigated using electron beam excitation. The beams had energies of 25, 35, and 50 eV
Characterization and measurement of polymer wear
Analytical tools which characterize the polymer wear process are discussed. The devices discussed include: visual observation of polymer wear with SEM, the quantification with surface profilometry and ellipsometry, to study the chemistry with AES, XPS and SIMS, to establish interfacial polymer orientation and accordingly bonding with QUARTIR, polymer state with Raman spectroscopy and stresses that develop in polymer films using a X-ray double crystal camera technique
Effect of lubricant extreme-pressure additives on surface fatigue life of AISI 9310 spur gears
Surface fatigue tests were conducted with AISI 9310 spur gears using a formulated synthetic tetraester oil (conforming to MIL-L-23699 specifications) as the lubricant containing either sulfur or phosphorus as the EP additive. Four groups of gears were tested. One group of gears tested without an additive in the lubricant acted as the reference oil. In the other three groups either a 0.1 wt % sulfur or phosphorus additive was added to the tetraester oil to enhance gear surface fatigue life. Test conditions included a gear temperature of 334 K (160 F), a maximum Hertz stress of 1.71 GPa (248 000 psi), and a speed of 10,000 rpm. The gears tested with a 0.1 wt % phosphorus additive showed pitting fatigue life 2.6 times the life of gears tested with the reference tetraester based oil. Although fatigue lives of two groups of gears tested with the sulfur additive in the oil showed improvement over the control group gear life, the results, unlike those obtained with the phosphorus oil, were not considered to be statistically significant
The discontinuous nature of the exchange-correlation functional -- critical for strongly correlated systems
Standard approximations for the exchange-correlation functional have been
found to give big errors for the linearity condition of fractional charges,
leading to delocalization error, and the constancy condition of fractional
spins, leading to static correlation error. These two conditions are now
unified for states with both fractional charge and fractional spin: the exact
energy functional is a plane, linear along the fractional charge coordinate and
constant along the fractional spin coordinate with a line of discontinuity at
the integer. This sheds light on the nature of the derivative discontinuity and
calls for explicitly discontinuous functionals of the density or orbitals that
go beyond currently used smooth approximations. This is key for the application
of DFT to strongly correlated systems.Comment: 5 pages 2 figure
The dual sunday school program, its philosophy and practice at First Wesleyan Church, High Point, NC
https://place.asburyseminary.edu/ecommonsatsdissertations/1062/thumbnail.jp
Localization and delocalization errors in density functional theory and implications for band-gap prediction
The band-gap problem and other systematic failures of approximate functionals
are explained from an analysis of total energy for fractional charges. The
deviation from the correct intrinsic linear behavior in finite systems leads to
delocalization and localization errors in large or bulk systems. Functionals
whose energy is convex for fractional charges such as LDA display an incorrect
apparent linearity in the bulk limit, due to the delocalization error. Concave
functionals also have an incorrect apparent linearity in the bulk calculation,
due to the localization error and imposed symmetry. This resolves an important
paradox and opens the possibility to obtain accurate band-gaps from DFT.Comment: 4 pages 4 figure
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