Nitrogen Doped Graphene Generated by Microwave Plasma and Reduction Expansion Synthesis

The article of record as published may be found at http://dx.doi.org/10.1166/nnl.2016.2055This work aimed to produce nitrogen doped graphene from Graphite Oxide (GO) by combining the Expansion Reduction Synthesis (RES) approach, which utilizes urea as doping/reducing agent, with the use of an Atmospheric Plasma torch (Plasma), which provides the high temperature reactor environment known to thermally exfoliate it. The use of this combined strategy (Plasma-RES) was tried in an attempt to increase the surface area of the products. The amount of nitrogen doping was controlled by varying the urea/GO mass ratios in the precursor powders. X-ray diffraction analysis, SEM, TEM, BET surface areas and conductivity measurements of the diverse products are presented. Nitrogen inclusion in the graphene samples was corroborated by the mass spectral signal of the evolved gases generated during thermal programmed oxidation experiments of the products and by EDX analysis. We found that the Plasma-RES method can successfully generate doped graphene in situ as the urea and GO precursors simultaneously decompose and reduce in the discharge zone. When using the same amount of urea in the precursor mixture, samples obtained by Plasma-RES have higher surface area than those generated by RES, however, they contain a smaller nitrogen content

Scaling up the Fabrication of Mechanically-Robust Carbon Nanofiber Foams

The article of record as published may be found at http://dx.doi.org/10.3390/fib4010009This work aimed to identify and address the main challenges associated with fabricating large samples of carbon foams composed of interwoven networks of carbon nanofibers. Solutions to two difficulties related with the process of fabricating carbon foams, maximum foam size and catalyst cost, were developed. First, a simple physical method was invented to scale-up the constrained formation of fibrous nanostructures process (CoFFiN) to fabricate relatively large foams. Specifically, a gas deflector system capable of maintaining conditions supportive of carbon nanofiber foam growth throughout a relatively large mold was developed. ANSYS CFX models were used to simulate the gas flow paths with and without deflectors; the data generated proved to be a very useful tool for the deflector design. Second, a simple method for selectively leaching the Pd catalyst material trapped in the foam during growth was successfully tested. Multiple techniques, including scanning electron microscopy, surface area measurements, and mechanical testing, were employed to characterize the foams generated in this study. All results confirmed that the larger foam samples preserve the basic characteristics: their interwoven nanofiber microstructure forms a low-density tridimensional solid with viscoelastic behavior. Fiber growth mechanisms are also discussed. Larger samples of mechanically-robust carbon nanofiber foams will enable the use of these materials as strain sensors, shock absorbers, selective absorbents for environmental remediation and electrodes for energy storage devices, among other applications.Office of Naval Research, Code 30, Force Protection ThrustOffice of Naval Research, Code 30, Force Protection Thrus

Microwave Dielectric Properties and Targeted Heating of Polypropylene Nano-Composites Containing Carbon Nanotubes and Carbon Black

The complex dielectric constants of three polypropylene (PP) composite samples were measured at microwave frequency ranges of X (8.2-12.4 GHz) and Ka band (26.5-40 GHz), and as a function of filler content. Three types of carbon filler materials -- pristine multiwall carbon nanotubes (p-CNTs), functionalized multiwall carbon nanotubes (f-CNTs), and carbon black (p-CB) were investigated. Attenuation constant for each composite was calculated, based on its measured complex dielectric constant, to highlight the importance of studying frequency dependent performance of composite materials for microwave heating. Most of the reported works for polymer composite heating using microwave power, have been conducted using commercial microwave ovens operating at 2.45 GHz. The results of this investigation for the CNT-composite samples indicate the importance of frequency optimization for creating maximum heat generation. The composite samples were also irradiated using low-power microwave energy at 2.6, 10 and 28 GHz and using a thermographic camera their relative capabilities for producing heat was investigated. The heating results corroborated those of the dielectric property measurements

Jornadas Nacionales de Robótica y Bioingeniería 2023: Libro de actas

Las Jornadas de Robótica y Bioingeniería de 2023 tienen lugar en la Escuela Técnica Superior de Ingeniería Industrial de la Universidad Politécnica de IVIadrid, entre los días 14 y 16 de junio de 2023. En este evento propiciado por el Comité Español de Automática (CEA) tiene lugar la celebración conjunta de las XII Jornadas Nacionales de Robótica y el XIV Simposio CEA de Bioingeniería. Las Jornadas Nacionales de Robótica es un evento promovido por el Grupo Temático de Robótica (GTRob) de CEA para dar visibilidad y mostrar las actividades desarrolladas en el ámbito de la investigación y transferencia tecnológica en robótica. Asimismo, el propósito de Simposio de Bioingeniería, que cumple ahora su decimocuarta dicción, es el de proporcionar un espacio de encuentro entre investigadores, desabolladores, personal clínico, alumnos, industriales, profesionales en general e incluso usuarios que realicen su actividad en el ámbito de la bioingeniería. Estos eventos se han celebrado de forma conjunta en la anualidad 2023. Esto ha permitido aunar y congregar un elevado número de participantes tanto de la temática robótica como de bioingeniería (investigadores, profesores, desabolladores y profesionales en general), que ha posibilitado establecer puntos de encuentro, sinergias y colaboraciones entre ambos. El programa de las jornadas aúna comunicaciones científicas de los últimos resultados de investigación obtenidos, por los grupos a nivel español más representativos dentro de la temática de robótica y bioingeniería, así como mesas redondas y conferencias en las que se debatirán los temas de mayor interés en la actualidad. En relación con las comunicaciones científicas presentadas al evento, se ha recibido un total de 46 ponencias, lo que sin duda alguna refleja el alto interés de la comunidad científica en las Jornadas de Robótica y Bioingeniería. Estos trabajos serán expuestos y presentados a lo largo de un total de 10 sesiones, distribuidas durante los diferentes días de las Jornadas. Las temáticas de los trabajos cubren los principales retos científicos relacionados con la robótica y la bioingeniería: robótica aérea, submarina, terrestre, percepción del entorno, manipulación, robótica social, robótica médica, teleoperación, procesamiento de señales biológicos, neurorehabilitación etc. Confiamos, y estamos seguros de ello, que el desarrollo de las jornadas sea completamente productivo no solo para los participantes en las Jornadas que podrán establecer nuevos lazos y relaciones fructíferas entre los diferentes grupos, sino también aquellos investigadores que no hayan podido asistir. Este documento que integra y recoge todas las comunicaciones científicas permitirá un análisis más detallado de cada una de las mismas