272 research outputs found
Molecular Flexibility and Bend in SemiâRigid Liquid Crystals: Implications for the Heliconical Nematic Ground State
The NTB phase phases possess a local helical structure with a pitch length of a few nanometers and is typically exhibited by materials consisting of two rigid mesogenic units linked by a flexibile oligomethylene spacer of odd parity, giving a bent shape. We report the synthesis and characterisation of two novel dimeric liquid crystals, and perform a computational study on ten cyanobiphenyl dimers with varying linking groups, generating a large library of conformers for each compound; this allows us to present molecular bend angles as probability weighted averages of many conformers, rather than use a single conformer. We validate conformer libraries by comparison of interproton distances with those obtained from solution based 1D 1H NOESY NMR, finding good agreement between experiment and computational work. Conversely, we find that using any single conformer fails to reproduce experimental interproton distances. We find the use of a single conformer significantly overestimates the molecular bend angle while also ignoring flexibility; we show that the average bend angle and flexibility are both linked to the relative stability of the NTB phase
Techniques for measuring atmospheric aerosols at the High Resolution Fly's Eye experiment
We describe several techniques developed by the High Resolution Fly's Eye
experiment for measuring aerosol vertical optical depth, aerosol horizontal
attenuation length, and aerosol phase function. The techniques are based on
measurements of side-scattered light generated by a steerable ultraviolet laser
and collected by an optical detector designed to measure fluorescence light
from cosmic-ray air showers. We also present a technique to cross-check the
aerosol optical depth measurement using air showers observed in stereo. These
methods can be used by future air fluorescence experiments.Comment: Accepted for publication in Astroparticle Physics Journal 16 pages, 9
figure
Rapid In Vitro Multiplication of Non-Runnering \u3cem\u3eFragaria vesca\u3c/em\u3e Genotypes from Seedling Shoot Axillary Bud Explants
Fragaria vesca L. has become a model species for genomic studies relevant to important crop plant species in the Rosaceae family, but generating large numbers of plants from non-runner-producing genotypes is slow. To develop a protocol for the rapid generation of plants, leaf explants were compared to single axillary bud shoot explants, both from in vitro-grown Fragaria vesca seedlings, as sources of shoots for new plant production in response to benzyladenine (BA) or thidiazuron (TDZ) combined with indolebutyric acid (IBA) on Murashige and Skoogâs Basal Salt (MS) medium. BA at 2.0 and 4.0 mg Lâ1 and TDZ at 1.5 mg Lâ1 promoted the greatest number of shoots produced per shoot explant. There were no IBA effects or IBA interactions with BA or TDZ. Significant interactions between BA and IBA, but not TDZ and IBA, occurred in leaf explant callus formation and % explants with callus at 6 and 9 weeks of culture and on shoots per leaf explant at 9 weeks. TDZ treatments produced uniformly high levels of callus but low numbers of shoots. The treatment generating the most shoot production was BA at 4.0 mg Lâ1 plus IBA at 0.50 mg Lâ1. After 9 weeks of culture, leaf explants of the non-runner-producing genotype Baron Solemacher had generated 4.6 shoots per explant with the best treatment, while axillary bud explants had generated 30.8 shoots with the best treatment. Thus, in vitro culture of shoot axillary bud explants can generate high numbers of clonal shoots from a single seedling plant in vitro
Study of Small-Scale Anisotropy of Ultrahigh Energy Cosmic Rays Observed in Stereo by HiRes
The High Resolution Fly's Eye (HiRes) experiment is an air fluorescence
detector which, operating in stereo mode, has a typical angular resolution of
0.6 degrees and is sensitive to cosmic rays with energies above 10^18 eV. HiRes
is thus an excellent instrument for the study of the arrival directions of
ultrahigh energy cosmic rays. We present the results of a search for
anisotropies in the distribution of arrival directions on small scales (<5
degrees) and at the highest energies (>10^19 eV). The search is based on data
recorded between 1999 December and 2004 January, with a total of 271 events
above 10^19 eV. No small-scale anisotropy is found, and the strongest
clustering found in the HiRes stereo data is consistent at the 52% level with
the null hypothesis of isotropically distributed arrival directions.Comment: 4 pages, 3 figures. Matches accepted ApJL versio
Measurement of the Flux of Ultrahigh Energy Cosmic Rays from Monocular Observations by the High Resolution Fly's Eye Experiment
We have measured the cosmic ray spectrum above 10^17.2 eV using the two air
fluorescence detectors of the High Resolution Fly's Eye observatory operating
in monocular mode. We describe the detector, photo-tube and atmospheric
calibrations, as well as the analysis techniques for the two detectors. We fit
the spectrum to a model consisting of galactic and extra-galactic sources.Comment: 4 pages, 4 figures. Uses 10pt.rtx, amsmath.sty, aps.rtx, revsymb.sty,
revtex4.cl
New early Triassic Lingulidae (Brachiopoda) genera and species from South China
Two new genera, Sinolingularia gen. nov. and Sinoglottidia gen. nov., together with three new species, Sinolingularia huananensis gen. et sp. nov., Sinolingularia yini gen. et sp. nov. and Sinoglottidia archboldi gen. et sp. nov., are described on the basis of a large collection of well-preserved specimens from several sections straddling the Permian - Triassic boundary in South China. <br /
Search for Point Sources of Ultra-High Energy Cosmic Rays Above 40 EeV Using a Maximum Likelihood Ratio Test
We present the results of a search for cosmic ray point sources at energies
above 40 EeV in the combined data sets recorded by the AGASA and HiRes stereo
experiments. The analysis is based on a maximum likelihood ratio test using the
probability density function for each event rather than requiring an a priori
choice of a fixed angular bin size. No statistically significant clustering of
events consistent with a point source is found.Comment: 7 pages, 7 figures. Accepted for publication in The Astrophysical
Journa
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