Elemental Contamination in Indoor Floor Dust and Its Correlation with PAHs, Fungi, and Gram plus /-Bacteria

In this study, we performed elemental analysis for floor dust samples collected in Jordanian microenvironments (dwellings and educational building). We performed intercorrelation and cluster analysis between the elemental, polyaromatic hydrocarbon (PAH), and microorganism concentrations. In general, the educational building workshops had the highest elemental contamination. The age of the dwelling and its occupancy played a role on the elemental contamination level: older and more occupied dwellings had greater contamination. The elemental contamination at a dwelling entrance was observed to be higher than in the living room. We found exceptionally high concentrations for Fe and Mn in the educational workshop and additionally, Hg, Cr, and Pb concentrations exceeded the limits set by the Canadian Council of Ministers of the Environment. According to the cluster analysis, we found three major groups based on location and contamination. According to the enrichment factor (EF) assessment, Al, Co, Mn, Ti, and Ba had EF 40 (i.e., extremely enriched). In contrast, Ca and P were geogenically enriched. Furthermore, significant Spearman correlations indicated nine subgroups of elemental contamination combined with PAHs and microbes.Peer reviewe

Elemental Contamination in Indoor Floor Dust and Its Correlation with PAHs, Fungi, and Gram+/− Bacteria

In this study, we performed elemental analysis for floor dust samples collected in Jordanian microenvironments (dwellings and educational building). We performed intercorrelation and cluster analysis between the elemental, polyaromatic hydrocarbon (PAH), and microorganism concentrations. In general, the educational building workshops had the highest elemental contamination. The age of the dwelling and its occupancy played a role on the elemental contamination level: older and more occupied dwellingshad greater contamination. The elemental contamination at a dwelling entrance was observed to be higher than in the living room. We found exceptionally high concentrations for Fe and Mn in the educational workshop and additionally, Hg, Cr, and Pb concentrations exceeded the limits set by the Canadian Council of Ministers of the Environment. According to the cluster analysis, we found three major groups based on location and contamination. According to the enrichment factor (EF) assessment, Al, Co, Mn, Ti, and Ba had EF 40 (i.e., extremely enriched). In contrast, Ca and P were geogenically enriched. Furthermore, significant Spearman correlations indicated nine subgroups of elemental contamination combined with PAHs and microbes

Elemental Contamination in Indoor Floor Dust and Its Correlation with PAHs, Fungi, and Gram+/− Bacteria

In this study, we performed elemental analysis for floor dust samples collected in Jordanian microenvironments (dwellings and educational building). We performed intercorrelation and cluster analysis between the elemental, polyaromatic hydrocarbon (PAH), and microorganism concentrations. In general, the educational building workshops had the highest elemental contamination. The age of the dwelling and its occupancy played a role on the elemental contamination level: older and more occupied dwellingshad greater contamination. The elemental contamination at a dwelling entrance was observed to be higher than in the living room. We found exceptionally high concentrations for Fe and Mn in the educational workshop and additionally, Hg, Cr, and Pb concentrations exceeded the limits set by the Canadian Council of Ministers of the Environment. According to the cluster analysis, we found three major groups based on location and contamination. According to the enrichment factor (EF) assessment, Al, Co, Mn, Ti, and Ba had EF 40 (i.e., extremely enriched). In contrast, Ca and P were geogenically enriched. Furthermore, significant Spearman correlations indicated nine subgroups of elemental contamination combined with PAHs and microbes

Organic and Elemental Carbon in the Urban Background in an Eastern Mediterranean City

The Mediterranean region is an important area for air pollution as it is the crossroads between three continents; therefore, the concentrations of atmospheric aerosol particles are influenced by emissions from Africa, Asia, and Europe. Here we concentrate on an eleven-month time series of the ambient concentration of organic carbon (OC) and elemental carbon (EC) between May 2018– March 2019 in Amman, Jordan. Such a dataset is unique in Jordan. The results show that the OC and EC annual mean concentrations in PM2.5 samples were 5.9 ± 2.8 µg m–3 and 1.7 ± 1.1 µg m–3, respectively. It was found that the majority of OC and EC concentrations were within the fine particle fraction (PM2.5). During sand and dust storm (SDS) episodes OC and EC concentrations were higher than the annual means; the mean values during these periods were about 9.6 ± 3.5 µg m–3 and 2.5 ± 1.2 µg m–3 in the PM2.5 samples. Based on this, the SDS episodes were identified to be responsible for an increased carbonaceous aerosol content as well as PM2.5 and PM10 content, which may have direct implications on human health. This study encourages us to perform more extensive measurements during a longer time period and to include an advanced chemical and physical characterization for urban aerosols in the urban atmosphere of Amman, which can be representative of other urban areas in the region

Organic and Elemental Carbon in the Urban Background in an Eastern Mediterranean City

The Mediterranean region is an important area for air pollution as it is the crossroads between three continents; therefore, the concentrations of atmospheric aerosol particles are influenced by emissions from Africa, Asia, and Europe. Here we concentrate on an eleven-month time series of the ambient concentration of organic carbon (OC) and elemental carbon (EC) between May 2018–March 2019 in Amman, Jordan. Such a dataset is unique in Jordan. The results show that the OC and EC annual mean concentrations in PM2.5 samples were 5.9 ± 2.8 µg m–3 and 1.7 ± 1.1 µg m–3, respectively. It was found that the majority of OC and EC concentrations were within the fine particle fraction (PM2.5). During sand and dust storm (SDS) episodes OC and EC concentrations were higher than the annual means; the mean values during these periods were about 9.6 ± 3.5 µg m–3 and 2.5 ± 1.2 µg m–3 in the PM2.5 samples. Based on this, the SDS episodes were identified to be responsible for an increased carbonaceous aerosol content as well as PM2.5 and PM10 content, which may have direct implications on human health. This study encourages us to perform more extensive measurements during a longer time period and to include an advanced chemical and physical characterization for urban aerosols in the urban atmosphere of Amman, which can be representative of other urban areas in the region

Organic and Elemental Carbon in the Urban Background in an Eastern Mediterranean City

The Mediterranean region is an important area for air pollution as it is the crossroads between three continents; therefore, the concentrations of atmospheric aerosol particles are influenced by emissions from Africa, Asia, and Europe. Here we concentrate on an eleven-month time series of the ambient concentration of organic carbon (OC) and elemental carbon (EC) between May 2018–March 2019 in Amman, Jordan. Such a dataset is unique in Jordan. The results show that the OC and EC annual mean concentrations in PM2.5 samples were 5.9 ± 2.8 µg m–3 and 1.7 ± 1.1 µg m–3, respectively. It was found that the majority of OC and EC concentrations were within the fine particle fraction (PM2.5). During sand and dust storm (SDS) episodes OC and EC concentrations were higher than the annual means; the mean values during these periods were about 9.6 ± 3.5 µg m–3 and 2.5 ± 1.2 µg m–3 in the PM2.5 samples. Based on this, the SDS episodes were identified to be responsible for an increased carbonaceous aerosol content as well as PM2.5 and PM10 content, which may have direct implications on human health. This study encourages us to perform more extensive measurements during a longer time period and to include an advanced chemical and physical characterization for urban aerosols in the urban atmosphere of Amman, which can be representative of other urban areas in the region

Floor dust bacteria and fungi and their coexistence with PAHs in Jordanian indoor environments

Floor dust samples were collected from Jordanian indoor environments (eight dwellings and an educational building) in Amman. Quantitative PCR (qPCR) analyses of selected fungal and bacterial groups were performed. The bacterial and fungal concentrations were also correlated with PAHs concentrations, which were previously measured in the same samples by using GC-MS. The bacterial and fungal concentrations varied significantly among and within the tested indoor environments. Based on the collected samples in the entrance area of the dwellings, the largest variation was found in Gram-negative bacteria and total fungi concentration. The lowest bacterial and fungal concentrations were found in the dwelling that was least occupied and the most recently built. At the educational building, the Gram-positive bacteria concentrations were lower than those observed in the dwellings. Unlike for bacteria, we observed significant negative correlation with some polycyclic aromatic hydrocarbons (PAHs). This calls for further studies investigating biodegradation of PAHs in house dust and presence of potentially health hazardous PAH metabolites. Since biocontamination in floor dust has been given relatively little to no attention in the MENA region we recommend that more extensive measurements be conducted in the future with chemical and biological analysis of floor dust contaminants and their exposure indoors. (C) 2017 Elsevier B.V. All rights reserved.Peer reviewe

Particulate Matter Concentrations in a Middle Eastern City – An Insight to Sand and Dust Storm Episodes

In this study, the particulate matter mass (PM10 and PM2.5) concentrations we measured during May 2018–March 2019 in an urban atmosphere of Amman, Jordan. The results showed that the annual mean PM10 concentration was 64 ± 39 µg m–3 and the PM2.5/PM10 ratio was 0.8 ± 0.2. According to the Jordanian Air Quality standards (JS-1140/2006), the observed PM10 annual mean value was below the limit value but that of the PM2.5 was three times higher than the corresponding limit value. However, both exceeded the World Health Organization (WHO) air quality guideline values. In a larger perspective, the annual mean PM10 concentrations in Jordan were lower than what was reported in other cities in the Middle East but were higher when compared to other Mediterranean cities. During the measurement period, Jordan was affected by Sand and Dust Storm (SDS) episodes on 14 days. The source origins of these dust outbreaks were traced back to North Africa, the Arabian Peninsula, and the Levant. The 24-hour PM10 concentrations during these SDS episodes ranged between 108 and 188 µg m–3, which was about 3–6 times higher than the mean values during clean conditions (~33 µg m–3).Peer reviewe

PAHs in Household Floor Dust Collected in Amman, Jordan

Peer reviewe

A Predictive Model for Steady State Ozone Concentration at an Urban-Coastal Site

Ground level ozone (O3) plays an important role in controlling the oxidation budget in the boundary layer and thus affects the environment and causes severe health disorders. Ozone gas, being one of the well-known greenhouse gases, although present in small quantities, contributes to global warming. In this study, we present a predictive model for the steady-state ozone concentrations during daytime (13:00–17:00) and nighttime (01:00–05:00) at an urban coastal site. The model is based on a modified approach of the null cycle of O3 and NOx and was evaluated against a one-year data-base of O3 and nitrogen oxides (NO and NO2) measured at an urban coastal site in Jeddah, on the west coast of Saudi Arabia. The model for daytime concentrations was found to be linearly dependent on the concentration ratio of NO2 to NO whereas that for the nighttime period was suggested to be inversely proportional to NO2 concentrations. Knowing that reactions involved in tropospheric O3 formation are very complex, this proposed model provides reasonable predictions for the daytime and nighttime concentrations. Since the current description of the model is solely based on the null cycle of O3 and NOx, other precursors could be considered in future development of this model. This study will serve as basis for future studies that might introduce informing strategies to control ground level O3 concentrations, as well as its precursors’ emissions