Liquid-liquid transition in supercooled silicon determined by first-principles simulation

First principles molecular dynamics simulations reveal a liquid-liquid phase transition in supercooled elemental silicon. Two phases coexist below $T_c\approx 1232K$. The low density phase is nearly tetra-coordinated, with a pseudogap at the Fermi surface, while the high density phase is more highly coordinated and metallic in nature. The transition is observed through the formation of van der Waals loops in pressure-volume isotherms below $T_c$.Comment: 9 pages 4 figure

Tricritical Phenomena at the Cerium γ→α\gamma \to \alpha Transition

The $\gamma \to \alpha$ isostructural transition in the Ce$_{0.9-x}$La$_x$Th$_{0.1}$ system is measured as a function of La alloying using specific heat, magnetic susceptibility, resistivity, thermal expansivity/striction measurements. A line of discontinuous transitions, as indicated by the change in volume, decreases exponentially from 118 K to close to zero with increasing La doping and the transition changes from being first-order to continuous at a critical concentration $0.10 \leq x_c \leq 0.14$. At the tricritical point, the coefficient of the linear $T$ term in the specific heat $\gamma$ and the magnetic susceptibility start to increase rapidly near $x$ = 0.14 and gradually approaches large values at $x$=0.35 signifying that a heavy Fermi-liquid state evolves at large doping. Near $x_c$, the Wilson ratio, $R_W$, has a value of 3.0, signifying the presence of magnetic fluctuations. Also, the low-temperature resistivity shows that the character of the low-temperature Fermi-liquid is changing

Gaussian excitations model for glass-former dynamics and thermodynamics

We describe a model for the thermodynamics and dynamics of glass-forming liquids in terms of excitations from an ideal glass state to a Gaussian manifold of configurationally excited states. The quantitative fit of this three parameter model to the experimental data on excess entropy and heat capacity shows that ``fragile'' behavior, indicated by a sharply rising excess heat capacity as the glass transition is approached from above, occurs in anticipation of a first-order transition -- usually hidden below the glass transition -- to a ``strong'' liquid state of low excess entropy. The dynamic model relates relaxation to a hierarchical sequence of excitation events each involving the probability of accumulating sufficient kinetic energy on a separate excitable unit. Super-Arrhenius behavior of the relaxation rates, and the known correlation of kinetic with thermodynamic fragility, both follow from the way the rugged landscape induces fluctuations in the partitioning of energy between vibrational and configurational manifolds. A relation is derived in which the configurational heat capacity, rather than the configurational entropy of the Adam Gibbs equation, controls the temperature dependence of the relaxation times, and this gives a comparable account of the experimental observations.Comment: 21 pp., 17 fig

X-Ray Light Curves of Gamma-ray Bursts Detected with the All-Sky Monitor on RXTE

We present X-ray light curves (1.5-12 keV) for fifteen gamma-ray bursts (GRBs) detected by the All-Sky Monitor on the Rossi X-ray Timing Explorer. We compare these soft X-ray light curves with count rate histories obtained by the high-energy (>12 keV) experiments BATSE, Konus-Wind, the BeppoSAX Gamma-Ray Burst Monitor, and the burst monitor on Ulysses. We discuss these light curves within the context of a simple relativistic fireball and synchrotron shock paradigm, and we address the possibility of having observed the transition between a GRB and its afterglow. The light curves show diverse morphologies, with striking differences between energy bands. In several bursts, intervals of significant emission are evident in the ASM energy range with little or no corresponding emission apparent in the high-energy light curves. For example, the final peak of GRB 970815 as recorded by the ASM is only detected in the softest BATSE energy bands. We also study the duration of bursts as a function of energy. Simple, singly-peaked bursts seem consistent with the E^{-0.5} power law expected from an origin in synchrotron radiation, but durations of bursts that exhibit complex temporal structure are not consistent with this prediction. Bursts such as GRB 970828 that show many short spikes of emission at high energies last significantly longer at low energies than the synchrotron cooling law would predict.Comment: 15 pages with 20 figures and 2 tables. In emulateapj format. Accepted by ApJ