Experimental investigation on the ability of macro-encapsulated polyurethane to resist cyclic damaging actions in self-repaired cement-based elements

The use of polymer precursors as repairing agents in capsule-based self-healing systems has been extensively studied in recent years. In particular, the effectiveness of macro-encapsulated polyurethane in restoring both watertightness and mechanical properties has been demonstrated at the laboratory level, and the experimental methods to test the effectiveness have been validated following pre-standard procedures. However, the use of macro-capsules containing polyurethane precursors for field applications has not been sufficiently implemented yet. For these systems to become appealing to the construction industry, it is essential to further characterize the self-healing effect in terms of stability in time, namely, to investigate the behavior of the self-healing system when subjected to recurring actions that can affect structures in time, after cracking and subsequent self-repairing. The goal of this study was to characterize the ability of commercial polyurethane foams to withstand cyclic flexural actions and repeated temperature variations after release from cementitious macro-capsules embedded in mortar specimens. The specimens were tested immediately after pre-cracking and self-repairing to characterize the initial sealing efficiency through a water-flow test. The same test was repeated at prescribed time intervals to analyze the evolution of the sealing efficiency with the applied mechanical and thermal stresses. The results showed that the proposed system has good stability against the selected damaging actions and confirmed the potential of encapsulated polyurethane for self-healing applications

Tissue expression of Squamous Cellular Carcinoma Antigen (SCCA) is inversely correlated to tumor size in HCC

<p>Abstract</p> <p>Background</p> <p>This study aimed to investigate squamous cellular carcinoma antigen (SCCA) in serum and in tumoral and paired peritumoral tissues. We studied 27 patients with liver cirrhosis (LC) and 55 with HCC: 20 with a single nodule < 3 cm (s-HCC) and 35 with a single nodule > 3 cm or multifocal (l-HCC).</p> <p>Methods</p> <p>Serum SCCA was measured by the ELISA kit, and in frozen tissues by immunohistochemistry, quantified with appropriate imaging analysis software and expressed in square microns. Continuous variables are reported as means and 95% confidence intervals. Comparisons between independent groups were performed with a generalized linear model and Tukey grouping. Pearson's correlation coefficients were determined to evaluate relations between markers. Qualitative variables were summarized as count and percentage. Statistical significance was set at p-value < 0.05.</p> <p>Results</p> <p>Serum SCCA values in LC patients were 0.41 (0.31–0.55) ng/ml and statistically different from both HCC groups: 1.6 (1.0–2.6) ng/ml in s-HCC, 2.2 (1.28–2.74) ng/ml in l-HCC. SCCA in hepatic tissue was 263.8 (176.6–394.01) μm²in LC patients, statistically different from values in s-HCC: 1163.2 (863.6–1566.8) μm²and l-HCC: 625.8 (534.5–732.6). All pairwise comparisons between groups yielded statistically significant differences. Tumoral SCCA resulted linearly related with nodule size, showing a statistically significant inverse relation between the two variables (b = -0.099, p = 0.024).</p> <p>Conclusion</p> <p>There was no statistically significant correlation between tissue and serum levels of SCCA. The significantly stronger expression of SCCA in smaller compared to larger HCC could be important for early HCC detection. However, the increased expression in peritumoral tissue could affect the significance of serological detection.</p

An Experimental Validation of Phase-Based Motion Magnification for Structures with Developing Cracks and Time-Varying Configurations

In this study, Computer Vision and Phase-Based Motion Magnification (PBMM) are validated for continuous Structural Health Monitoring (SHM) purposes. The aim is to identify the exact instant of occurrence for damage or abrupt structural changes from video-extracted, very low amplitude (barely visible) vibrations. The study presents three experimental datasets: a box beam with multiple saw cuts of different lengths and angles, a beam with a full rectangular cross section and a mass added at the tip, and the spar of a prototype High-Aspect-Ratio wing. Both mode-shape- and frequency-based approaches are considered, showing the potential to identify the severity and position of the damage as well A high-definition, high-speed camera and a low-cost commercial alternative have been successfully utilised for these video acquisitions. Finally, the technique is also preliminarily tested for outdoor applications with smartphone cameras

Durability of self-healing cementitious systems with encapsulated polyurethane evaluated with a new pre-standard test method

This work reports on the self-healing capabilities of mortar specimens with polyurethane encapsulated in two types of cementitious macro-capsules, by comparison with the performance of mortar specimens using the same healing agent encapsulated in glass capsules, as tested in an inter-laboratory testing campaign following a pre-standard procedure. This comparison was performed with a twofold objective of checking the robustness of such pre-standard procedure for varying types of capsules and testing the effectiveness of a new type of cementitious capsule that has never been used before in durability tests. The testing procedure was developed in the framework of the EU COST Action SARCOS. First, the specimens were pre-cracked via three-point bending followed by an active crack width control technique. Then, the self-healing effect was characterised in terms of water permeability reduction. The cementitious capsules offered equivalent or better performance compared to the glass capsules used in the inter-laboratory testing. The average sealing efficiency for the specimens containing cementitious capsules ranged from 54 to 74%, while for glass macro-capsules it was equal to 56%. It was also observed that when applying the pre-standard procedure to test specimens containing capsules with comparable size and geometric arrangement, the same results were obtained in different repetitions of the test. The results obtained confirmed the possibility to use the cementitious capsules as a valid macro-encapsulation system, offering additional advantages compared to glass capsules. The repeatability of the results corroborated the robustness of the adopted testing procedure, highlighting its potential for further standardisation

Accelerated carbonation of ordinary Portland cement paste and its effects on microstructure and transport properties

Coupling of carbonation and chlorides ingress mechanisms is very common in concrete under certain exposure conditions such as coastal environments. The aggravation/ mitigation of corrosion by the existence of carbonation lies on the fact that microstructural changes due to carbonation result in changes on the transport properties of the material. In this study we investigate and quantify evolving transport properties of ordinary Portland cement paste, such as porosity, tortuosity and intrinsic permeability. Dual X-ray micro computed tomography (micro CT) is used for the quantification of porosity. Furthermore Dynamic Vapour Sorption (DVS) measurements are carried out to resolve water retention and relative permeability curves. The authors expect to provide insights into the mechanisms of accelerated carbonation in both types of cement paste, as well as data for input and validation of numerical and analytical models on this degradation phenomenon

Evaluation of test methods for self-healing concrete with macrocapsules by inter-laboratory testing

Self-healing of concrete is a promising way to increase the service life of structures. Innovative research is being performed, yet it is difficult to compare results due to a lack of standardised test methods. In the framework of the COST action SARCOS (CA15202) [1] six different interlaboratory tests are being executed, in which different test methods are being evaluated for six self-healing approaches. Here, the results of the inter-laboratory test concerning mortar and concrete with macrocapsules filled with a polyurethane healing agent will be discussed. The specimens were manufactured in one laboratory and then shipped to the other five participating laboratories. All six laboratories evaluated two test methods: a water permeability test and a capillary water absorption test. For the water permeability test, mortar specimens were cracked and afterwards their crack width was controlled using an active control technique. Due to the active crack control, the crack width of 90% of the samples deviated by less than 10 μm from the target of 300 μm. This made it more straightforward to compare the permeability test results, which indicated a similar sealing efficiency for several of the laboratories. For the capillary water absorption test, concrete specimens were cracked in a crack-width-controlled three-point bending test setup without active control after unloading. Compared to the water permeability specimens, there was a lot more variation on the crack width of the capillary water absorption specimens. The variability on the crack width and differences in quality of waterproofing resulted in diverging findings in the capillary water absorption test

Evaluation of Methodologies for Assessing Self-Healing Performance of Concrete with Mineral Expansive Agents: An Interlaboratory Study.

Self-healing concrete has the potential to optimise traditional design approaches; however, commercial uptake requires the ability to harmonize against standardized frameworks. Within EU SARCOS COST Action, different interlaboratory tests were executed on different self-healing techniques. This paper reports on the evaluation of the effectiveness of proposed experimental methodologies suited for self-healing concrete with expansive mineral additions. Concrete prisms and discs with MgO-based healing agents were produced and precracked. Water absorption and water flow tests were executed over a healing period spanning 6 months to assess the sealing efficiency, and the crack width reduction with time was monitored. High variability was reported for both reference (REF) and healing-addition (ADD) series affecting the reproducibility of cracking. However, within each lab, the crack width creation was repeatable. ADD reported larger crack widths. The latter influenced the observed healing making direct comparisons across labs prone to errors. Water absorption tests highlighted were susceptible to application errors. Concurrently, the potential of water flow tests as a facile method for assessment of healing performance was shown across all labs. Overall, the importance of repeatability and reproducibility of testing methods is highlighted in providing a sound basis for incorporation of self-healing concepts in practical applications.EPSR