Получение биосовместимых пористых сплавов на основе никелида титана методами СВС и спекания

В статье рассматривается проблема получения сплавов на основе никелида титана (TiNi). Значительное внимание уделяется производству пористых проницаемых сплавов на основе TiNi. Существуют различные способы получения сплавов на основе TiNi, но многие из них требуют дорогостоящего оборудования, а также имеют недостатки, такие как продолжительность синтеза и получение недостаточно чистого продукта. Сегодня для получения пористых материалов широко используются методы самораспространяющегося высокотемпературного синтеза (СВС) и спекания, основным преимуществом которого является возможность получения пористых материалов с регулируемыми характеристиками структуры и физико-механическими свойствами. Поэтому целью данной работы является определение параметров СВС и спекания

Study of structural features of porous TiNi-based materials produced by SHS and sintering

Structural properties of porous TiNi-based materials produced by SHS method and sintering have been investigated. The material having different pore wall surface topography, porosity and pore size distribution was shown to be produced depending on the powder metallurgy method for porous TiNi-based alloy. All the materials having porosity of 55-70%, mean pore size 90-150 μm, as well as normal pore size distribution are most preferable. Ultimate strength and breaking point were determined to depend on porosity, pore size distribution, pore intersections and phase chemical composition of the material. Strength properties of the sintered alloy are twice as much compared to the SHS-produced ones due to homogeneity of its macrostructure, low chemical heterogeneity and TiNi3 precipitations strengthening the TiNi matrix.</jats:p

Investigation of the effect of copper addition on physical and mechanical properties of TiNi-Cu porous alloy

This work is devoted to the physical and mechanical properties of porous alloys based on TiNi alloyed with different amounts of Cu additive. We show that by doping a porous TiNi alloy with copper instead of nickel, it is possible to obtain characteristics acceptable for use in implantology and superior to those of known porous TiNi alloys. Cu addition in the range from 1 to 10 at.% is shown to optimize the properties of tested alloys. There is a decrease in the minimal martensitic transformation stress τminMs from 37 to 17 MPa when compared to initial unalloyed TiNi. Alloys with 3 and 6 at.% of Cu are found to be optimal for use in medical practice. Along with a wide temperature range of reversible deformations that cover the range of operating temperatures (273–313 K), such alloys demonstrate their martensitic transformation stress values below 28 MPs. This permits to model implantable structures of complex configuration from such materials under a certain temperature regime

Production of two-dimensional porous TiNi-based powder material by diffusion sintering and electron-beam processing

The paper addresses the study of the surface condition of two-dimensional porous TiNi-based powder materials produced by diffusion sintering and electron-beam processing. Methods of production of two-dimensional TiNibased materials to be used for the purposes of non-destructive testing have been proven. The surface condition of the produced materials is described by scanning electron microscopy and interference profilometry

Preparation of porous TiNi-Ti alloy by diffusion sintering method and study of its composition, structure and martensitic transformations

The study demonstrates a method for controlling not only the phase composition but also the atomic composition of TiNi matrix in porous TiNi-Ti alloys developed for biomedical uses as implants. The alloys were obtained from TiNi powder which was sintered with Ti powder added at as much as 0–10 at%. The structure, phase and chemical composition of the produced TiNi-Ti alloys was investigated with respect to the amount of Ti added into the material. It is shown that in the sintered product containing 5 at% and more of Ti additive, the composition of its TiNi matrix becomes close to equiatomic (with Ti:Ni atomic ratio ~1), and the excessive Ti precipitates as secondary phases Ti2Ni and Ti3Ni4. In parallel, with increase in Ti ad- ditive from 0–10 at%, the structure of the precipitating Ti2Ni type phases changes its morphology from separate spherical or pyramidal precipitates to large dendritic formations. The direct martensitic trans- formation from austenite to martensite in all the samples was found to proceed in two stages and through the R-phase (B2→R→B19′). Thermoresistive analysis demonstrated that TiNi-Ti samples with 5 and more at% of Ti had their characteristic starting temperature of martensite transition stabilizing at ~57 °C (330 K). This implies that the sample with 5 at% of Ti additive exhibited desired martensite transition temperatures, while containing a minimum concentration of secondary-phase precipitates in its matrix which deteriorate its properties. Thus, for the 곙rst time, we show that a very simple preparation approach based on sintering powders of TiNi and Ti is capable of producing porous TiNi-Ti alloys with properties optimized for fabricating bone implants

Aнализ бинарных диаграмм состояний на основе Ti-Ni-Mo

В статье проводится анализ диаграмм двойных систем Ti-Ni, Ti-Mo, Ni-Mo с целью создания коррозионно-устойчивых материалов на основе системы Ti-Ni-Mo для применения в технике. Рассмотрены фазовые продукты реакционного синтеза на основе порошковой системы Ti, Ni и Mo. Установлено, что к основным интерметаллическим соединениям относятся фазы: а-, в -Ti, Ti2Ni, Ti4Ni2O, TiNi, TiNi3, Ti3Ni4, Ti2Ni3, y-Ni, Мо (в], в2, а', а", ю-фазы), MoNi(S), MoNi3(y), MoNi4(e)

Fabrication and study of double sintered TiNi-based porous alloys

Double-sintered porous TiNi-based alloys were fabricated and their structural characteristics and physico-mechanical properties were investigated. A fabrication technology of powder mixtures is elaborated in this article. Sintering conditions were chosen experimentally to ensure good structure and properties. The porous alloys were synthesized by solid-state double diffusion sintering (DDS) of Ti–Ni powder and prepare to obtain dense, crack-free, and homogeneous samples. The Ti–Ni compound sintered at various temperatures was investigated by scanning electron microscopy. Phase composition of the sintered alloys was determined by x-ray diffraction. Analysis of the data confirmed the morphology and structural parameters. Mechanical and physical properties of the sintered alloys were evaluated. DDS at 1250 °C was found to be optimal to produce porous samples with a porosity of 56% and mean pore size of 90 μm. Pore size distribution was unimodal within the narrow range of values. The alloys present enhanced strength and ductility, owing to both the homogeneity of the macrostructure and relative elasticity of the bulk, which is hardened by the Ni-rich precipitates. These results suggest the possibility to manufacture porous TiNi-based alloys for application as a new class of dental implants

The effect of mechano-chemical treatment on structural properties of the drawn TiNi-based alloy wire

The rapid development of the biomedical materials with the advanced functional characteristics is a challenging task because of the growing demands for better material properties in-clinically employed. Modern medical devices that can be implanted into humans have evolved steadily by replacing TiNi-based alloys for titanium and stainless steel. In this study, the effect of the mechano-chemical treatment on structural properties of the matrix and surface layer of the drawn TiNi-based alloy wire was assessed. A range of samples have been prepared using different drawing and etching procedures. It is clear from the results obtained that the fabricated samples show a composite structure comprising the complex matrix and textured oxycarbonitride spitted surface layer. The suggested method of surface treatment is a concept to increase the surface roughness for the enhanced bio-performance and better in-vivo integratio

Fabrication and study of double sintered TiNi-based porous alloys

Double-sintered porous TiNi-based alloys were fabricated and their structural characteristics and physico-mechanical properties were investigated. A fabrication technology of powder mixtures is elaborated in this article. Sintering conditions were chosen experimentally to ensure good structure and properties. The porous alloys were synthesized by solid-state double diffusion sintering (DDS) of Ti–Ni powder and prepare to obtain dense, crack-free, and homogeneous samples. The Ti–Ni compound sintered at various temperatures was investigated by scanning electron microscopy. Phase composition of the sintered alloys was determined by x-ray diffraction. Analysis of the data confirmed the morphology and structural parameters. Mechanical and physical properties of the sintered alloys were evaluated. DDS at 1250 °C was found to be optimal to produce porous samples with a porosity of 56% and mean pore size of 90 μm. Pore size distribution was unimodal within the narrow range of values. The alloys present enhanced strength and ductility, owing to both the homogeneity of the macrostructure and relative elasticity of the bulk, which is hardened by the Ni-rich precipitates. These results suggest the possibility to manufacture porous TiNi-based alloys for application as a new class of dental implants