Phosphorus adsorption on iron‐coated sand under reducing conditions

Mitigation measures are needed to prevent large loads of phosphate originating in agriculture from reaching surface waters. Iron-coated sand (ICS) is a residual product from drinking water production. It has a high phosphate adsorption capacity and can be placed around tile drains, taking no extra space, which increases the farmers’ acceptance. The main concern regarding the use of ICS filters below groundwater level is that limited oxygen supply and high organic matter concentrations may lead to the reduction and dissolution of iron (hydr)oxides present and the release of previously adsorbed phosphate. This study aimed to investigate phosphate adsorption on ICS at the onset of iron reduction. First, we investigated whether simultaneous metal reduction and phosphate adsorption were relevant at two field sites in the Netherlands that use ICS filters around tile drains. Second, the onset of microbially mediated reduction of ICS in drainage water was mimicked in complementary laboratory microcosm experiments by varying the intensity of reduction through controlling the oxygen availability and the concentration of degradable organic matter. After 3 yr, ICS filters in the field removed phosphorus under low redox conditions. Over 45 d, the microbial reduction of manganese and iron oxides did not lead to phosphate release, confirming field observations. Electron microscopy and X-ray absorption spectroscopy did not evince systematic structural or compositional changes; only under strongly reducing conditions did iron sulfides form in small percentages in the outer layer of the iron coating. Our results suggest that detrimental effects only become relevant after long periods of operation

Thallium adsorption onto phyllosilicate minerals

The adsorption of thallium (Tl) onto phyllosilicate minerals plays a critical role in the retention of Tl in soils and sediments and the potential transfer of Tl into plants and groundwater. Especially micaceous minerals are thought to strongly bind monovalent Tl(i), in analogy to their strong binding of Cs. To advance the understanding of Tl(i) adsorption onto phyllosilicate minerals, we studied the adsorption of Tl(i) onto Na- and K-saturated illite and Na-saturated smectite, two muscovites, two vermiculites and a naturally Tl-enriched soil clay mineral fraction. Macroscopic adsorption isotherms were combined with the characterization of the adsorbed Tl by X-ray absorption spectroscopy (XAS). In combination, the results suggest that the adsorption of Tl(i) onto phyllosilicate minerals can be interpreted in terms of three major uptake paths: (i) highest-affinity inner-sphere adsorption of dehydrated Tl(+) on a very low number of adsorption sites at the wedge of frayed particle edges of illite and around collapsed zones in vermiculite interlayers through complexation between two siloxane cavities, (ii) intermediate-affinity inner-sphere adsorption of partially dehydrated Tl(+) on the planar surfaces of illite and muscovite through complexation onto siloxane cavities, (iii) low-affinity adsorption of hydrated Tl(+), especially in the hydrated interlayers of smectite and expanded vermiculite. At the frayed edges of illite particles and in the vermiculite interlayer, Tl uptake can lead to the formation of new wedge sites that enable further adsorption of dehydrated Tl(+). On the soil clay fraction, a shift in Tl(i) uptake from frayed edge sites (on illite) to planar sites (on illite and muscovite) was observed with increasing Tl(i) loading. The results from this study show that the adsorption of Tl(i) onto phyllosilicate minerals follows the same trends as reported for Cs and Rb and thus suggests that concepts to describe the retention of (radio)cesium by different types of phyllosilicate minerals in soils, sediments and rocks are also applicable to Tl(i)

Phosphate burial in aquatic sediments: Rates and mechanisms of vivianite formation from mackinawite

Excess phosphorus abundance often drives eutrophication and affects surface water quality. Formation of vivianite (Fe$_3$(PO$_4$)$_2$ • 8H$_2$O) in aquatic sediments acts as a significant sink for phosphate (P), crucial for resorting surface waters. Authigenic vivianite formation, however, can be limited by other ferrous iron containing phases, in particular iron sulfides. Although thermodynamically feasible under suitable conditions, the formation of vivianite from mackinawite has been widely disregarded for authigenic phosphate mineral formation. Here we investigated the formation of vivianite from mackinawite (FeS) in batch experiments in which dissolved sulfide was continuously removed, at P levels between 0 – 5 mM in a pH of 6 to 8. Solid characterizations by electron microscopy, X-ray diffraction as well as Mössbauer and X-ray absorption spectroscopy demonstrates that vivianite was formed at all pH values in P amended experiments. The temporal evolution of dissolved Fe(II) concentrations indicates that the transformation proceeds via the release of the dissolved Fe(II) by FeS dissolution and subsequent vivianite precipitation, over time scales of days. The kinetics of the transformation are controlled by the dissolution rates of FeS. Aging and transformation of FeS, however, compete with vivianite formation. Aging is more pronounced at higher pH but is inhibited by P adsorption. Hence, the effect of pH and P concentration on aging is the main reason for the influence on these parameters on the rates and extent of vivianite formation. Our findings demonstrate that FeS can be an effective iron source for vivianite formation in aquatic sediments when sulfide concentrations decrease due to, for example, changes in external forcing or microbial sulfide oxidation. Formation of vivianite from FeS as an Fe source can also open new perspectives in P recovery in water treatment, for example when Fe is added to digesters to bind H$_2$S

Refueling of LH2 Aircraft—Assessment of Turnaround Procedures and Aircraft Design Implication

Green liquid hydrogen (LH2) could play an essential role as a zero-carbon aircraft fuel to reach long-term sustainable aviation. Excluding challenges such as electrolysis, transportation and use of renewable energy in setting up hydrogen (H2) fuel infrastructure, this paper investigates the interface between refueling systems and aircraft, and the impacts on fuel distribution at the airport. Furthermore, it provides an overview of key technology design decisions for LH2 refueling procedures and their effects on the turnaround times as well as on aircraft design. Based on a comparison to Jet A-1 refueling, new LH2 refueling procedures are described and evaluated. Process steps under consideration are connecting/disconnecting, purging, chill-down, and refueling. The actual refueling flow of LH2 is limited to a simplified Reynolds term of v · d = 2.35m2/s. A mass flow rate of 20 kg/s is reached with an inner hose diameter of 152.4mm. The previous and subsequent processes (without refueling) require 9 min with purging and 6 min without purging. For the assessment of impacts on LH2 aircraft operation, process changes on the level of ground support equipment are compared to current procedures with Jet A-1. The technical challenges at the airport for refueling trucks as well as pipeline systems and dispensers are presented. In addition to the technological solutions, explosion protection as applicable safety regulations are analyzed, and the overall refueling process is validated. The thermodynamic properties of LH2 as a real, compressible fluid are considered to derive implications for airport-side infrastructure. The advantages and disadvantages of a subcooled liquid are evaluated, and cost impacts are elaborated. Behind the airport storage tank, LH2 must be cooled to at least 19K to prevent two-phase phenomena and a mass flow reduction during distribution. Implications on LH2 aircraft design are investigated by understanding the thermodynamic properties, including calculation methods for the aircraft tank volume, and problems such as cavitation and two-phase flows. In conclusion, the work presented shows that LH2 refueling procedure is feasible, compliant with the applicable explosion protection standards and hence does not impact the turnaround procedure. A turnaround time comparison shows that refueling with LH2 in most cases takes less time than with Jet A-1. The turnaround at the airport can be performed by a fuel truck or a pipeline dispenser system without generating direct losses, i.e., venting to the atmosphere. © 2022 by the authors.Licensee MDPI, Basel, Switzerland

Ability of 3 Frailty Measures to Predict Short-Term Outcomes in Older Patients Admitted for Post-Acute Inpatient Rehabilitation.

OBJECTIVES To evaluate the ability of 3 commonly used frailty measures to predict short-term clinical outcomes in older patients admitted for post-acute inpatient rehabilitation. DESIGN Observational cohort study. SETTING AND PARTICIPANTS Consecutive patients (n = 207) admitted to a geriatric inpatient rehabilitation facility. METHODS Frailty on admission was assessed using a frailty index, the physical frailty phenotype, and the Clinical Frailty Scale (CFS). Predictive capacity of the frailty instruments was analyzed for (1) nonhome discharge, (2) readmission to acute care, (3) functional decline, and (4) prolonged length of stay, using multivariate logistic regression models and receiver operating characteristic (ROC) curves. RESULTS The number of patients classified as frail was 91 (44.0%) with the frailty index, 134 (64.7%) using the frailty phenotype, and 151 (73.0%) with the CFS. The 3 frailty measures revealed acceptable discriminatory accuracy for nonhome discharge (area under the curve ≥ 0.7) but differed in their predictive ability: the adjusted odds ratio (OR) for nonhome discharge was highest for the CFS [6.2, 95% confidence interval (CI) 1.8-21.1], compared to the frailty index (4.1, 95% CI 2.0-8.4) and the frailty phenotype (OR 2.9, 95% CI 1.2-6.6). For the other outcomes, discriminatory accuracy based on ROC tended to be lower and predictive ability varied according to frailty measure. Readmission to acute care from inpatient rehabilitation was predicted by all instruments, most pronounced by the frailty phenotype (OR 5.4, 95% CI 1.6-18.8) and the frailty index (OR 2.5, 95% CI 1.1-5.6), and less so by the CFS (OR 1.4, 95% CI 0.5-3.8). CONCLUSIONS AND IMPLICATIONS Frailty measures may contribute to improved prediction of outcomes in geriatric inpatient rehabilitation. The choice of the instrument may depend on the individual outcome of interest and the corresponding discriminatory ability of the frailty measure

Heavy Metal Uptake by Novel Miscanthus Seed-Based Hybrids Cultivated in Heavy Metal Contaminated Soil

When heavy metal contaminated soils are excluded from food production, biomass crops offer an alternative commercial opportunity. Perennial crops have potential for phytoremediation. Whilst the conditions at heavy metal contaminated sites are challenging, successful phytoremediation would bring significant economic and social benefits. Seed-based Miscanthus hybrids were tested alongside the commercial clone Miscanthus ? giganteus on arable land, contaminated with Pb, Cd and Zn near Katowice. Before the randomized experimental plots were established (25m2 plots with plant density 2/m2) ?time-zero? soil samples were taken to determine initial levels of total (aqua regia) and bioavailable (CaCl2 extraction) concentration of Pb, Cd and Zn. After the growing season plant material was sampled during autumn (October, green harvest) and winter (March, brown harvest) to determine differences in heavy metal uptake. Results after the first growing season are presented, including the plot establishment success, biomass yield and heavy metal uptakepublishersversionPeer reviewe

Implementing miscanthus into farming systems:A review of agronomic practices, capital and labour demand

Miscanthus is a promising bioeconomy crop with several biomass utilisation pathways. However, its current cultivation area in Europe is relatively low. This is most likely due to a lack of knowledge about the imple- mentation of miscanthus into farming systems. This study reviews current best practices and suitable land areas for miscanthus cultivation. Biomass production costs and labour requirements were evaluated over the whole 20- year cultivation cycle of four utilisation pathways: combustion, animal bedding, and both conventional and organic biogas production. The assessment was performed for two field sizes (1 and 10 ha), two average annual yield levels (15 and 25 t dry matter ha 1), and both green and brown harvest regimes. The maximum attainable annual gross margins are 1657 € ha 1 for combustion, 13,920 € ha 1 for animal bedding, 2066 € ha 1 for conventional and 2088 € ha 1 for organic biogas production. The combustion pathway has the lowest labour demand (141.5 h ha 1), and animal bedding the highest (317.6 h ha 1) due to additional baling during harvest. Suitable cultivation areas include depleted soils, erosion-prone slopes, heavy clay soils and ecological focus areas such as riparian buffer zones and groundwater protection areas. On such sites, miscanthus would (i) improve soil and water quality, and (ii) enable viable agricultural land utilisation even on scattered patches and strips. Due to its low demands and perennial nature, miscanthus is suitable for sustainable intensification of indus- trial crop cultivation in a growing bioeconomy, benefiting soil and water quality, while providing large amounts of biomass for several utilisation pathways