Dichloridobis(2-methoxy­dibenzo[c,e][1,2]oxaphospho­rine-κP)platinum(II) trichloro­methane solvate

The title compound, [PtCl2(C13H11O2P)2]·CHCl3, has a rare PtCl2 bridging of two dibenzooxaphospho­rine ligands through the metal atom. The PtII ion is in a slightly distorted square-planar environment. The trichloro­methane solvent mol­ecule shows rotational disorder (major occupancy is 0.75) and is placed near to the inversion centre at (1/2, 1/2, 0) in channels parallel to the a axis. The solvent mol­ecule is linked to the complex mol­ecule via inter­molecular bifurcated C—H⋯Cl and C—H⋯O hydrogen bonds. The crystal structure is further stabilized by π–π inter­actions involving the benzene rings, with a centroid–centroid distance of 3.658 (8) Å

Preparation and application of highly porous aerogel-based bioactive materials in dentistry

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Use of Hemadsorption in a Case of Pediatric Toxic Shock Syndrome

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Green chemical approaches and tools in the development of environmentally friendly synthetic methods

Addressing the recommendations of the 12 basic lows of green chemistry, the microwave technique was utilized in phospha-Mannich, Diels-Alder and inverse Wittig type reactions, moreover under solventless conditions. In the phase transfer catalysed alkylation of CH-acidic compounds, the quaternary onium salts could be substituted by MW irradiation. The effect of chiral phase transfer catalysts was compared on suitable, potentially enantioselective model reactions. Mono- and bidental P-ligands were developed to make available novel platinum complexes that can be useful as catalysts. Finally, esterifications including diesterifications were studied by in situ Fourier Transform IR spectroscopy

Recurrent intraventricular thrombosis in a child with dilated cardiomyopathy and antithrombin deficiency

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