363 research outputs found
Macroscopic electrostatic potentials and interactions in self-assembled molecular bilayers: the case of Newton black films
We propose a very simple but 'realistic' model of amphiphilic bilayers,simple
enough to be able to include a large number of molecules in the sample, but
nevertheless detailed enough to include molecular charge distributions,
flexible amphiphilic molecules and a reliable model of water. All these
parameters are essential in a nanoscopic scale study of intermolecular and long
range electrostatic interactions. We also propose a novel, simple and more
accurate macroscopic electrostatic field for model bilayers. This model goes
beyond the total dipole moment of the sample, which on a time average is zero
for this type of symmetrical samples, i. e., it includes higher order moments
of this macroscopic electric field. We show that by representing it with a
superposition of gaussians it can be 'analytically' integrated, and therefore
its calculation is easily implemented in a MD simulation (even in simulations
of non-symmetrical bi- or multi-layers). In this paper we test our model by
molecular dynamics simulations of Newton black films
Adsorption of polymers on a fluctuating surface
We study the adsorption of polymer chains on a fluctuating surface. Physical
examples are provided by polymer adsorption at the rough interface between two
non-miscible liquids, or on a membrane. In a mean-field approach, we find that
the self--avoiding chains undergo an adsorption transition, accompanied by a
stiffening of the fluctuating surface. In particular, adsorption of polymers on
a membrane induces a surface tension and leads to a strong suppression of
roughness.Comment: REVTEX, 9 pages, no figure
Correlated disordered interactions on Potts models
Using a weak-disorder scheme and real-space renormalization-group techniques,
we obtain analytical results for the critical behavior of various q-state Potts
models with correlated disordered exchange interactions along d1 of d spatial
dimensions on hierarchical (Migdal-Kadanoff) lattices. Our results indicate
qualitative differences between the cases d-d1=1 (for which we find nonphysical
random fixed points, suggesting the existence of nonperturbative fixed
distributions) and d-d1>1 (for which we do find acceptable perturbartive random
fixed points), in agreement with previous numerical calculations by Andelman
and Aharony. We also rederive a criterion for relevance of correlated disorder,
which generalizes the usual Harris criterion.Comment: 8 pages, 4 figures, to be published in Physical Review
Fluctuations of a driven membrane in an electrolyte
We develop a model for a driven cell- or artificial membrane in an
electrolyte. The system is kept far from equilibrium by the application of a DC
electric field or by concentration gradients, which causes ions to flow through
specific ion-conducting units (representing pumps, channels or natural pores).
We consider the case of planar geometry and Debye-H\"{u}ckel regime, and obtain
the membrane equation of motion within Stokes hydrodynamics. At steady state,
the applied field causes an accumulation of charges close to the membrane,
which, similarly to the equilibrium case, can be described with renormalized
membrane tension and bending modulus. However, as opposed to the equilibrium
situation, we find new terms in the membrane equation of motion, which arise
specifically in the out-of-equilibrium case. We show that these terms lead in
certain conditions to instabilities.Comment: 7 pages, 2 figures. submitted to Europhys. Let
Topography and instability of monolayers near domain boundaries
We theoretically study the topography of a biphasic surfactant monolayer in
the vicinity of domain boundaries. The differing elastic properties of the two
phases generally lead to a nonflat topography of ``mesas'', where domains of
one phase are elevated with respect to the other phase. The mesas are steep but
low, having heights of up to 10 nm. As the monolayer is laterally compressed,
the mesas develop overhangs and eventually become unstable at a surface tension
of about K(dc)^2 (dc being the difference in spontaneous curvature and K a
bending modulus). In addition, the boundary is found to undergo a
topography-induced rippling instability upon compression, if its line tension
is smaller than about K(dc). The effect of diffuse boundaries on these features
and the topographic behavior near a critical point are also examined. We
discuss the relevance of our findings to several experimental observations
related to surfactant monolayers: (i) small topographic features recently found
near domain boundaries; (ii) folding behavior observed in mixed phospholipid
monolayers and model lung surfactants; (iii) roughening of domain boundaries
seen under lateral compression; (iv) the absence of biphasic structures in
tensionless surfactant films.Comment: 17 pages, 9 figures, using RevTeX and epsf, submitted to Phys Rev
Liquid friction on charged surfaces: from hydrodynamic slippage to electrokinetics
Hydrodynamic behavior at the vicinity of a confining wall is closely related
to the friction properties of the liquid/solid interface. Here we consider,
using Molecular Dynamics simulations, the electric contribution to friction for
charged surfaces, and the induced modification of the hydrodynamic boundary
condition at the confining boundary. The consequences of liquid slippage for
electrokinetic phenomena, through the coupling between hydrodynamics and
electrostatics within the electric double layer, are explored. Strong
amplification of electro-osmotic effects is revealed, and the non-trivial
effect of surface charge is discussed. This work allows to reconsider existing
experimental data, concerning Zeta potentials of hydrophobic surfaces and
suggest the possibility to generate ``giant'' electro-osmotic and
electrophoretic effects, with direct applications in microfluidics
Ecological criteria for evaluation candidate sites for marine reserves
Several schemes have been developed to help select the locations of marine reserves. All of them combine social, economic, and biological criteria, and few offer any guidance as to how to prioritize among the criteria identified. This can imply that the relative weights given to different criteria are unimportant. Where two sites are of equal value ecologically, then socioeconomic criteria should dominate the choice of which should be protected. However, in many cases, socioeconomic criteria are given equal or greater weight than ecological considerations in the choice of sites. This can lead to selection of reserves with little biological value that fail to meet many of the desired objectives. To avoid such a possibility, we develop a series of criteria that allow preliminary evaluation of candidate sites according to their relative biological values in advance of the application of socioeconomic criteria. We include criteria that, while not strictly biological, have a strong influence on the species present or ecological processes. Our scheme enables sites to be assessed according to their biodiversity, the processes which underpin that diversity, and the processes that support fisheries and provide a spectrum of other services important to people. Criteria that capture biodiversity values include biogeographic representation, habitat representation and heterogeneity, and presence of species or populations of special interest (e.g., threatened species). Criteria that capture sustainability of biodiversity and fishery values include the size of reserves necessary to protect viable habitats, presence of exploitable species, vulnerable life stages, connectivity among reserves, links among ecosystems, and provision of ecosystem services to people. Criteria measuring human and natural threats enable candidate sites to be eliminated from consideration if risks are too great, but also help prioritize among sites where threats can be mitigated by protection. While our criteria can be applied to the design of reserve networks, they also enable choice of single reserves to be made in the context of the attributes of existing protected areas. The overall goal of our scheme is to promote the development of reserve networks that will maintain biodiversity and ecosystem functioning at large scales. The values of ecosystem goods and services for people ultimately depend on meeting this objective
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