Origine de la salinité de l'eau dans les schistes profonds dans la région de Marrakach (Maroc)

ORSAY-PARIS 11-BU Sciences (914712101) / SudocSudocFranceF

Origin of Groundwater Salinity in the Draa Sfar Polymetallic Mine Area Using Conservative Elements (Morocco)

In the Marrakech region of Morocco, where water resources are particularly limited, excessive salinity has been measured in the water from some wells intended for human consumption and irrigation. Moreover, the start-up of a mine for the exploitation of a polymetallic sulfide deposit and the progress of the exploitation work have revealed the existence of very saline deep groundwater with a total mineralization of over 80 g/L. The hydrogeochemical study using conservative elements has helped to understand the origin of the groundwater salinity in the Draa Sfar mine and to assess the contribution of the deep salinity source to the high salinities observed in the mine. The groundwater of the shallow aquifer shows almost constant Br−/Cl− and Na+/Cl− ratios, independent of the chloride content. The constant ratios of these conservative elements indicate a single autochthonous origin of Cl−, Br− and Na+, and groundwater salinity is diluted by recharge water containing low concentrations of these elements. Regarding the mine groundwater, the high Li+/Cl− ratio and Br−/Cl− ratios in the range measured on the leachates of the rocks extracted from the mine indicate that the pore water is the reservoir for dissolved chloride and the salinity of the mine’s groundwater results from a mixture between these pore waters and fresh meteoric water that seeps in from the surface and recharges the entire aquifer. This porewater would be a remnant of the hydrothermal fluids that formed the sulfide deposit

Origin and Salinization Processes of Groundwater in the Semi-Arid Area of Zagora Graben, Southeast Morocco

Located in the southeastern region of Morocco, the Zagora area mainly relies on groundwater as a source of water supply. However, this groundwater is often of concern, due to the limited recharge and unfavorable geological conditions for the development of the aquifer. Despite this, private wells in the Zagora ditch reveal relatively rich water resources. Geochemical and isotopic studies were conducted in the area to understand the origin of the groundwater and its salinity, aiding in informed water management strategies to assist in better planning and regulation of well construction, as well as in mitigating the impacts of high salinity on local water supply and agricultural systems. The results show that the water quality varies, with some wells having conductivity values in excess of 5 mS/cm. Most groundwater samples have high salinity and low pH due to the CO2 dissolved in groundwater. Geochemical analysis indicated two chemical facies: chloride–sulfate calcic/magnesic and bicarbonate calcic/magnesic. The presence of Na+ and Cl− indicated that the origin of these two elements in these waters was the dissolution of halite, with some samples showing an enrichment of Na+ compared to Cl−. This could be attributed to cation exchange. The concentration of Ca2+ and HCO3− suggested that their origin is the dissolution of calcite and the weathering of calcium silicate minerals such as plagioclase. The isotopic analysis showed that the δ18O values ranged from −10.98‰ to −8.54‰, and δ2H values ranged from −75.9‰ to −62.3‰. This indicated that the groundwater originated from the High Atlas with a recharge altitude between 2600 m and 2800 m. The groundwater flows into the graben through fissures and regional fault networks