273 research outputs found

    Mathematic Models for Quality of Service Purposes in Ad Hoc Networks

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    Redox Shuttle Additives for Lithium-Ion Battery

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    SARP: Synchronous Adaptive Routing Protocol for MANETs

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    AbstractThe aim of a routing protocol is to compute valid routes allowing every couple of nodes in the network to communicate at anytime. When the network topology is evolving over time, routing decisions should be constantly reconsidered. The main goal is to ensure a valid routing through time at the lowest possible cost. Conventional proactive routing protocols periodically recompute their routing tables; but due to their inherent nature based on shortest paths, they select longer links that ensure faster routing but are amenable to rapid breakages as nodes move around. Using short periods certainly allows a better tracking of the topology changes; however, it induces a higher control signaling overhead. An adequate trade-off between the routing period size and the traffic overhead should be found.In this paper, we propose a new mechanism that keeps sensing the network mobility level to properly adjust the routing period size. It relies on a distributed algorithm that collects the network cartography which is then used to self-regulate the routing period size. Simulation results show that our proposed scheme correctly tracks changes and properly adjusts the current routing period size leading to much better performances

    Electrochemically primed functional redox mediator generator from the decomposition of solid state electrolyte.

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    Recent works into sulfide-type solid electrolyte materials have attracted much attention among the battery community. Specifically, the oxidative decomposition of phosphorus and sulfur based solid state electrolyte has been considered one of the main hurdles towards practical application. Here we demonstrate that this phenomenon can be leveraged when lithium thiophosphate is applied as an electrochemically "switched-on" functional redox mediator-generator for the activation of commercial bulk lithium sulfide at up to 70 wt.% lithium sulfide electrode content. X-ray adsorption near-edge spectroscopy coupled with electrochemical impedance spectroscopy and Raman indicate a catalytic effect of generated redox mediators on the first charge of lithium sulfide. In contrast to pre-solvated redox mediator species, this design decouples the lithium sulfide activation process from the constraints of low electrolyte content cell operation stemming from pre-solvated redox mediators. Reasonable performance is demonstrated at strict testing conditions

    Median nerve entrapment in a callus fracture following a pediatric both-bone forearm fracture: A case report and literature review

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    Forearm fractures are common injuries in childhood. Median nerve entrapment is a rare complication of forearm fractures, but several cases have been reported in the literature. This case report discusses the diagnosis and management of median nerve entrapment in a 13-year-old male who presented acutely with a both-bone forearm fracture and numbness in the median nerve distribution. Following the delayed diagnosis, surgical exploration revealed complete nerve entrapment and a nerve graft was performed

    A practical phosphorus-based anode material for high-energy lithium-ion batteries

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    State-of-the-art lithium-ion batteries cannot satisfy the increasing energy demand worldwide because of the low specific capacity of the graphite anode. Silicon and phosphorus both show much higher specific capacity; however, their practical use is significantly hindered by their large volume changes during charge/discharge. Although significant efforts have been made to improve their cycle life, the initial coulombic efficiencies of the reported Si-based and P-based anodes are still unsatisfactory (<90%). Here, by using a scalable high-energy ball milling approach, we report a practical hierarchical micro/nanostructured P-based anode material for high-energy lithium-ion batteries, which possesses a high initial coulombic efficiency of 91% and high specific capacity of ~2500 mAh g−1 together with long cycle life and fast charging capability. In situ high-energy X-ray diffraction and in situ single-particle charging/discharging were used to understand its superior lithium storage performance. Moreover, proof-of-concept full-cell lithium-ion batteries using such an anode and a LiNi0.6Co0.2Mn0.2O2 cathode were assembled to show their practical use. The findings presented here can serve as a good guideline for the future design of high-performance anode materials for lithium-ion batteries
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