Replacement of MDA with more oxidatively stable diamines in PMR-polyimides

Studies are performed to investigate the effect of substituting 4,4'-oxydianiline and 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane for the 4,4'-methylenedianiline in PMR polyimide matrix resin. Graphite fiber reinforced composites are fabricated from unsized Celion 6000 and PMR-polyimide matrix resins having formulated molecular weights in the range of 1500 to 2400. The composite processing characteristics are investigated and the initial room temperature and 316 C (600 F) composite mechanical properties are determined. Comparative 316 C composite weight losses and 316 C mechanical properties retention after prolonged 316 C air exposure are also determined

Properties of solid polymer electrolyte fluorocarbon film

The ionic fluorocarbon film used as the solid polymer electrolyte in hydrogen/oxygen fuel cells was found to exhibit delamination failures. Polarized light microscopy of as-received film showed a lined region at the center of the film thickness. It is shown that these lines were not caused by incomplete saponification but probably resulted from the film extrusion process. The film lines could be removed by an annealing process. Chemical, physical, and tensile tests showed that annealing improved or sustained the water contents, spectral properties, thermo-oxidative stability, and tensile properties of the film. The resistivity of the film was significantly decreased by the annealing process

Structure-to-property Relationships in Addition Cured Polymers 2: Resin Tg Composite Initial Mechanical Properties of Norbornenyl Cured Polyimide Resins

PRM (polymerization of monomeric reactants) methodology was used to prepare thirty different polyimide oligomeric resins. Monomeric composition as well as chain length between sites of crosslinks were varied to examine their effects on glass transition temperature (Tg) of the cured/postcured resins. An almost linear correlation of Tg versus molecular distance between the crosslinks was observed. An attempt was made to correlate Tg with initial mechanical properties (flexural strength and interlaminar shear strength) of unidirectional graphite fiber composites prepared with these resins. However, the scatter in mechanical strength data prevented obtaining as clear a correlation as was observed for the structural modification/crosslink distance versus Tg. Instead, only a range of composite mechanical properties was obtained at the test temperatures studied (room temperature, 288 and 316 C). Perhaps more importantly, what did become apparent during the attempted correlation study was: (1) that PMR methodology could be used to prepare composites from resins that contain a wide variety of monomer modifications, and (2) that these composites almost invariably provided satisfactory initial mechanical properties as long as the resins selected were melt processable

Resin/fiber thermo-oxidative interactions in PMR polymide/graphite composites

The amounts of resin weight loss and fiber weight loss in four PMR-polyimide graphite fiber composites were calculated from the composite weight losses and the fiber/resin ratios of the composites after long term thermo-oxidative aging in 600 F air. The accelerating effect of graphite fiber on resin weight loss, compared to neat resin weight loss, indicated the presence of a deleterious resin/fiber thermo-oxidative interaction, presumably due to fiber impurities. Similarly, the decelerating effect of the protective matrix resin on fiber weight loss, compared to bare fiber weight loss, was also demonstrated. The amount of hydrazine-indigestible resin and the amount of loose surface graphite fiber that formed during 600 deg F exposure of the composites were quantitatively determined. The indigestible residual resin was also qualitatively studied by scanning electron microscopy

Effect of substituted phenylnadimides on processing and properties of PMR polyimide composites

Three nitrophenylnadimide cure initiators and two phenylnadimides (without nitros) were evaluated as additives to PMR-15 resins and Celion 6000 graphite fiber composites. The results of a resin screening study eliminated all of the additives except 3-nitrophenylnadimide (NO2PN) for use as a low temperature curing additive for PMR-15. Thus, NO2PN and the two control additives were investigated in PMR-15 formulations from which Celion 6000 graphite fiber/PMR-15 composites were processed both with low temperature (274 C) and normal (316 C) cure cycles. Comparisons of the two processing cycles, the resultant glass transition temperatures (Tg), the ambient, 274 and 316 C composite mechanical properties determined before and after 316 C postcure, the 316 C thermo-oxidative weight losses and the retention of 316 C composite mechanical properties are presented. Empirical correlations of the type and amount of nadimide additives with processing parameters, Tg, composite mechanical properties, composite thermo-oxidative stability and long term retention of 316 C composite mechanical properties are also presented

Ultraviolet and X-ray variability of NGC 4051 over 45 days with XMM-Newton and Swift

We analyse 15 XMM-Newton observations of the Seyfert galaxy NGC 4051 obtained over 45 days to determine the ultraviolet (UV) light curve variability characteristics and search for correlated UV/X-ray emission. The UV light curve shows variability on all time scales, however with lower fractional rms than the 0.2-10 keV X-rays. On days-weeks timescales the fractional variability of the UV is Fvar ~ 8%, and on short (~ hours) timescales Fvar ~ 2%. The within-observation excess variance in 4 of the 15 UV observations was found be much higher than the remaining 11. This was caused by large systematic uncertainties in the count rate masking the intrinsic source variance. For the four "good" observations we fit an unbroken power-law model to the UV power spectra with slope -2.0 +/- 0.5. We compute the UV/X-ray Cross-correlation function for the "good" observations and find a correlation of ~ 0.5 at time lag of ~ 3 ks, where the UV lags the X-rays. We also compute for the first time the UV/X-ray Cross-spectrum in the range 0-28.5 ks, and find a low coherence and an average time lag of ~ 3 ks. Combining the 15 XMM-Newton and the Swift observations we compute the DCF over +/-40 days but are unable to recover a significant correlation. The magnitude and direction of the lag estimate from the 4 "good" observations indicates a scenario where ~ 25 % of the UV variance is caused by thermal reprocessing of the incident X-ray emission.Comment: 11 pages, 8 figures. Accepted for publication in MNRA

The flux-dependent X-ray time lags in NGC 4051

We present an analysis of the X-ray time lags for the highly variable Seyfert 1 galaxy NGC 4051, based on a series of XMM-Newton observations taken in 2009. We investigate the Fourier frequency dependent time lags in the light curves between the 0.3--1.0 keV and 2.0--5.0 keV energy bands as a function of source flux, including simultaneous modelling of the resulting lag-frequency spectra. We find the shape of the lag-frequency spectra to vary significantly and systematically with source flux. We model the lag-frequency spectra using simple transfer functions, and find that two time lag components are required, one in each energy band. The simplest acceptable fits have only the relative contribution of the lagged component in the hard band varying with flux level, which can be associated with changes in the energy spectrum. We discuss the interpretation of these results in terms of the currently popular models for X-ray time lags.Comment: 9 pages, 4 figures. Accepted for publication in MNRA

Structure-to-glass transition temperature relationships in high temperature stable condensation polyimides

The presence of a hexafluoroisopropylidene (6F) connecting group in aryl dianhydrides used to prepare aromatic condensation polyimides provides high glass transition temperature (T sub g) polyimides with excellent thermo-oxidative stability. The purpose of this study was to determine if a trifluorophenyl-ethylidene (3F) connecting group would have a similar effect on the T sub g of aromatic condensation polyimides. A new dianhydride containing the 3F connecting group was synthesized. This dianhydride and an aromatic diamine also containing the 3F connecting group were used together and in various combinations with known diamines or known dianhydrides, respectively, to prepare new 3F containing condensation polyimides. Known polyimides, including some with the 6F connecting linkage, were also prepared for comparison purposes. The new 3F containing polymers and the comparison polymers were prepared by condensation polymerization via the traditional amic-acid polymerization method in N,N-dimethylacetamide solvent. The solutions were characterized by determining their inherent viscosities and then were thermally converted into polyimide films under nitrogen atmosphere at 300 to 500 C, usually 350 C. The T sub g's of the films and resin discs were then determined by thermomechanical analysis and were correlated as a function of the final processing temperatures of the films and resin discs. The results showed that similarities existed in the T sub g's depending on the nature of the connecting linkage in the monomers used to prepare the condensation polyimides

PMR polyimides with improved high temperature performance

Studies were performed to investigate the effect of substituting a hexafluoro isopropyl idene connecting group for a carbonyl group of a PMR polyimide monomeric reactant on the thermo-mechanical properties processability of graphite fiber reinforced PMR polyimide composites. Composites were fabricated utilizing PMR methodology. Monomeric reactant solutions of various stoichiometric ratios were used to impregnate Hercules HTS graphite fiber. The processing characteristics and elevated temperature (600 F) mechanical properties of the composites are described

Generic advertising without supply control: implications of funding mechanisms for advertising intensities in competitive industries

Producer profit‐maximising rules for generic commodity advertising programs and associated funding levies are derived. Lump‐sum, per unit and ad valorem levies, and government subsidy funding arrangements are compared and contrasted. The initial single‐product competitive market model is extended to incorporate international trade, government price policies, and multiple commodity interactions.Marketing,