Desenho de experiências - estratégicas

O desenvolvimento de produtos e processos pressupõe a realização de experiências que conduzam à sua optimização ao menor custo possível. As estratégias a utilizar na condução das experiências, bem como o tratamento estatístico dos resultados alcançados, deverão conduzir às melhores condições de realização dos ensaios necessários à prossecução deste objectivo. O método de Taguchi permite obter informação relevante, com um número reduzido de experiências, conforme se demonstra nos casos de estudo apresentados

Macrostructural changes of polymer replicated open cell cordierite based foams upon sintering

The goal of this work was to clarify the macrostructural changes that take place upon sintering of open cell cordierite based foams. A methodology, based on optical image analysis, was developed to assess the structure of open-cell foams, which allowed evaluating the macrostructure of both cordierite based foams obtained by the replication process and their polymeric templates. The parameters used to describe the structures were the size of the cell and the window, the window shape factor, the strut thickness and the volume fraction of the material. The experimental evidence gathered opened the way to understand the physical/chemical transformations involved in the polymer burnout and the ceramic sintering processes, as well as their influence on the ceramic final structure. The observed trends provide guidance for tailoring ‘replicated’ cordierite based foams, in view of the required application

Thermal decomposition of δ-MoN and ε-Fe2N synthesized under concentrated solar radiation in NH3 gas stream

ABSTRACT: Decomposition temperatures of δ-MoN and ε-Fe2N synthesized with flowing NH3 gas under concentrated solar radiation heating were evaluated by Differential Scanning Calorimetry (DSC) in Argon (Ar) gas environment. The measured decomposition temperature of δ-MoN and ε-Fe2N were dependent on the solar synthesis conditions, particularly either NH3 or N2 gas flow rate at temperature. Sample containing δ-MoN showed two exothermic peaks around 680 and 900 ◦C, attributed to the reactions of δ-phase into γ-single-phase and (γ+β)-two-phase Mo2N, respectively, attributed to the dissociation reaction of δ-phase into γ-single phase and the dissociation reaction of γ-phase into metallic M saturated with N, respectively. Decomposition of ε-Fe2N took place into γ’-Fe4N in two steps occurring at 606 and 660 ◦C, respectively. When N2 instead of ammonia (NH3) gas was used, complete dissociation of γ’-Fe4N into Fe took place at around 610 ◦C. Full decomposition of γ’-Fe4N into metallic α-Fe(N) was corroborated by X-ray diffraction (XRD) analysis.info:eu-repo/semantics/publishedVersio

Slow pyrolysis of cork granules under nitrogen atmosphere: by-products characterization and their potential valorization

ABSTRACT: Cork granules (Quercus suber L.) were slowly pyrolyzed at temperatures between 400-700 degrees C and under N-2 flow. While preserving its structure, some cells of the cork biochar became interconnected, allowing such carbon residue to be used as templates for manufacturing ceria redox materials. The pyrolytic char morphology was similar to that of the natural precursor. The produced cork biochar belonged to Class 1 (C > 60%) and possessed a high heating value of 32 MJ kg(-1). Other pyrolysis-derived compounds were identified and quantified through GC-FID and GC-MS analyses. The yield of gases released during cork pyrolysis was strongly dependent on the temperature used due to the thermal decomposition reactions involved in the degradation of cork. In particular, rising pyrolysis temperature from 500 to 700 T resulted in reducing the total hydrocarbon gases from 74 to 24 vol%. On the other hand, the yield of H-2 increased from 0 to 58% by increasing the pyrolysis temperature from 400 to 700 T. Due to the presence of suberin in cork, the composition and yield of bio-oil could be regulated by the pyrolysis temperature. Cork bio-oil was found to consist of long-chain hydrocarbons (from C11 to C24). The bio-oil resulting from the slow pyrolysis of cork residues is suitable as an appropriate feedstock for producing aliphatic-rich pyrolytic biofuels or as a source of olefms. Overall, the findings of this study suggest that Quercus suber L. could be a promising feedstock for biochar and biofuel production through the pyrolytic route and could contribute to the environmental and economic sustainability of the cork production industry.info:eu-repo/semantics/publishedVersio

A New Insight into the Role of Silicate-Type Binders on the Crushing Strength of Alumina Foams

ABSTRACT: Semi-closed cell macroporous alumina foams with relative densities ranging from 0.26 to 0.35 have been produced by the well-established replication method based on the coating of a polyurethane (PU) template foam by a ceramic slurry, followed by burnout of the PU template, and sintering of the ceramic skeleton. Collapse of the three-dimensional structure upon the volatilisation of the PU sponge can only be prevented using appropriate binders. Scarce data are available on the slurry formulations of commercial alumina foams. The aim of this study was to investigate the influence of silicate-type binders, namely kaolin and bentonite additives, on the crushing strength of alumina foams. The highest crushing strength of around 10 MPa was observed at a porosity of 66 +/- 2%. The open-cell model is inadequate to fit the crushing strength data of such semi-closed cell type structures. Both microscopic and macroscopic flaws resulting from the foam processing method contribute to the wide scatter of the strength, thereby explaining the Weibull modulus ranging from 4 to 7. Both flaw populations require further improvement to maximise the crushing strength of these foams with high potential for the design of structured catalyst carriers and molten aluminium filters.info:eu-repo/semantics/publishedVersio

Carbide phases synthesised from C/Mo powder compacts at specified sub-stoichiometric ratios by solar radiation heating to temperatures between 1600 C and 2500 C

There are a number of distinguishable carbide phases in the binary Mo-C system depending on C/Mo ratio as well as on temperature. In a preceding work published in this journal, carbide formation performance for graphite/molybdenum powder mixtures at specified levels of substoichiometric C/Mo atom ratio (C/Mo = 1/1, 3/4, 2/3 and 1/2) by exposure to concentrated solar radiation in a solar furnace at PROMESCNRS in Odeillo (France) was reported at a target temperature 1900 C. In the present work, the similar carbide synthesis experiments were carried out at 1600 C as well as at temperature exceeding 2500 C. The target temperature setting was adjusted by controlling the downward deviation of the test piece top surface position from the exact focal spot of the parabolic mirror concentrator located above. In this solar furnace at PROMES-CNRS, temperature of the test piece was raised from ambient temperature to the target temperature within fractions of a second. Reaction products detected were hexagonal -MoC1 x and -Mo2C (high temperature sub-carbide phase) depending on the C/Mo ratio in the starting material as well as on the processing temperature. No evidence of formation of cubic -MoC1 x was detected by X-ray diffraction analysis for any test piece examined

Thermal resistance of solar volumetric absorbers made of mullite, brown alumina and ceria foams under concentrated solar radiation

ABSTRACT: Three semi-closed open cell ceramic foams, namely mullite, brown alumina and ceria-based materials, were subjected to thermal cycles by direct concentrated solar irradiation to study their thermal resistance in view of their potential application as photothermal devices, such as volumetric solar absorbers. After cycling, the extent of the damage in the samples was determined by measuring the retained crushing (compressive) strength. The extent of the damage was found to depend on the composition, the applied surface temperature difference (Delta T) of thermal cycling and the temperature gradient across the foams. It was found that the retained crushing strength gradually decreased with an increase in Delta T and was independent of the number of thermal cycles in the range investigated. The ceria foams displayed the poorest thermal shock resistance. Experimental data fit the Gibson-Ashby model for the thermal shock resistance of ceramic foams, for a constant C = 0.65.info:eu-repo/semantics/publishedVersio

Complicações de aspiração de corpo estranho traqueobrônquico em crianças: relato de 5 casos e revisão da literatura

Aspiração de corpo estranho em via áerea é uma das principais causas de morte em crianças, especialmente nas menores que 3 anos de idade. A aspiração do corpo estranho pode causar um amplo espectro de sintomas, e o diagnóstico precoce é altamente associado com o sucesso da retirada do material inalado. Apesar dos grandes avanços nos procedimentos endoscópicos e anestésicos, um grande número de dificuldades e complicações ainda estão presentes nesta situação clínica. Neste estudo, descrevemos 5 casos de sérias complicações agudas, incluindo pneumomediatismo, pneumotórax, atelectasia total, migração do corpo estranho e necessidade de toracotomia, em crianças admitidas em nosso Centro de Terapia Intensiva em 1999 e 2000, situações essas que poderiam ser prevenidas com reconhecimento precoce e rápida intervenção terapêutica.Foreign body aspiration (FBA) is one of leading causes of death in children, especially among those younger than 3 years of age. The inhalation of a foreign body may cause a wide variety of symptoms, and early diagnosis is highly associated with the successful removal of the inhaled foreign material. Despite the great advances in endoscopic procedures and anesthesia, a large number of difficulties and complications still result from foreign body aspiration. We describe 5 cases of serious acute complications following aspiration of foreign bodies that became lodged in the tracheobronchial tree, including pneumomediastinum, pneumothorax, total atelectasis, foreign body dislodgment, and need for thoracotomy in children admitted into our intensive care unit in 1999 and 2000; these were all situations that could have been prevented with early recognition and prompt therapeutic intervention

Nitriding VI-group metals (Cr, Mo and W) in stream of NH3 gas under concentrated solar irradiation in a solar furnace at PSA (Plataforma Solar de Almería)

Carbides and nitrides of d-group transition metals are classified as refractory hard material and their industrial importance has been recognized for long. In recent years, unique functionalities including catalytic function and superconductivity are discovered for this group of materials to raise serious attention of materials researchers and engineers to refractory carbides and nitrides as novel functional materials. Synthesis of refractory carbides and nitrides demands high temperature reaction route to consume considerable amount of electricity or gas in conventional industrial process. In view of saving cost of such conventional energy, feasibility of using concentrated solar beam as heat source for synthesizing carbide and nitride has been investigated by the authors since 1997. After verifying usefulness of concentrated solar beam as heat source for carbide forming reactions, similar attempts of employing concentrated solar beam as heat source for nitride synthesis were initiated recently. After brief experimental verification of nitride synthesis for IVa group metal, Ti, and Vg group metals, V, Nb and Ta, in N2 gas environment under irradiation with concentrated solar beam to 2000 °C, the authors decided to undertake nitride synthesis of VIa group metals, Cr, Mo and W, as well as of Fe in stream of ammonia (NH3) gas as a nitriding medium under irradiation of concentrated solar beam at temperatures not exceeding 1000 °C. NH3 gas with suppressed extent of dissociation by flowing is defined empirically as uncracked NH3 and it is proved to possess very high nitriding power to make synthesis of mono-nitride MoN of Mo coexisting with sub-nitride Mo and higher nitride Fe2N of Fe possible under normal pressure condition that are not possible when chemically stable N2 gas is used as a nitriding agent. VIa-group metals including Cr, Mo and W are known to be highly resistant against nitriding. In the present report, results of nitriding in flowing NH3 gas at a fixed flow rate 10 l/h (˜167 ml/min) under heating with concentrated solar beam for VIa-group metals, Cr, Mo and W, are summarized to demonstrate favorable effect of solar beam heating towards further enhancement of nitriding power of flowing NH3 gas compared with the situation in conventional electric furnace in which visible light components except infra-red (IR) heat wave component are absent in the reaction system.

Epidemiology of Periodontal Disease

848641Made available in DSpace on 2019-09-11T20:51:31Z (GMT). No. of bitstreams: 0 Previous issue date: 2012[No abstract available]Costa, F.O., Federal University of Minas Gerais, Contorno Avenue 4849, 30110031 Belo Horizonte, MG, BrazilSusin, C., Laboratory for Applied Periodontal and Craniofacial Regeneration, College of Dental Medicine, Georgia Health Sciences University, United StatesCortelli, J.R., University of Taubaté, Taubaté, SP, BrazilAlmeida Pordeus, I., Federal University of Minas Gerais, Contorno Avenue 4849, 30110031 Belo Horizonte, MG, Brazi