Effect of chlorine purification on oxidation resistance of some mechanical carbons

Oxidation experiments were conducted with some experimental and commercial mechanical carbons at 650 C in dry air flowing at 28 cc/sec (STP). In general, purification of these carbon-graphites with chlorine at 2800 C improved oxidation resistance. Additional improvements in oxidation resistance were obtained from purification followed by an antioxidant (zinc phosphate) treatment. For the commercial materials, purification alone gave greater oxidation resistance than the antioxidant treatment alone. The reverse, however, was the case for the experimental materials

Wear and friction of oxidation-resistant mechanical carbon graphites at 650 C in air

Studies were conducted to determine the friction and wear properties of experimental carbon-graphites. Hemispherically tipped carbon-graphite rider specimens were tested in sliding contact with rotating Inconel X-750 disks in air. A surface speed of 1.33 m/sec, a load of 500 g, and a specimen temperature of 650 C were used. Results indicate: (1) hardness is not a major factor in determining friction and wear under the conditions of these studies. (2) Friction and wear as low as or lower than those observed for a good commercial seal material were attained with some of the experimental materials studied. (3) The inclusion of boron carbide (as an oxidation inhibitor) has a strong influence on wear rate. (4) Phosphate treatment reduces the friction coefficient when boron carbide is not present in the base material

The hydrogen sulfide emissions abatement program at the Geysers Geothermal Power Plant

The scope of the hydrogen sulfide (H2S) abatement program at The Geysers Geothermal Power Plant and the measures currently under way to reduce these emissions are discussed. The Geysers steam averages 223 ppm H2S by weight and after passing through the turbines leaves the plant both through the gas ejector system and by air-stripping in the cooling towers. The sulfide dissolved in the cooling water is controlled by the use of an oxidation catalyst such as an iron salt. The H2S in the low Btu ejector off gases may be burned to sulfur dioxide and scrubbed directly into the circulating water and reinjected into the steam field with the excess condensate. Details are included concerning the disposal of the impure sulfur, design requirements for retrofitting existing plants and modified plant operating procedures. Discussion of future research aimed at improving the H2S abatement system is also included

Transition metal impurities in semiconductors

Crystal field theory applied transition metal impurities in semiconductor

Compressible flow across narrow passages: Comparison of theory and experiment for face seals

Computer calculation for determining compressible flow across radial face seals were compared with measured results obtained in a seal simulator rig at pressure ratios to 0.9 (ambient pressure/sealed pressure). In general, the measured and calculated leakages across the seal dam agreed within 3 percent. The resultant loss coefficient, dependent upon the pressure ratio, ranged from 0.47 to 0.68. The calculated pressures were within 2.5 N/cu um of the measured values

BRST quantization of the massless minimally coupled scalar field in de Sitter space (zero modes, euclideanization and quantization)

We consider the massless scalar field on the four-dimensional sphere $S^4$. Its classical action $S={1\over 2}\int_{S^4} dV (\nabla \phi)^2$ is degenerate under the global invariance $\phi \to \phi + \hbox{constant}$. We then quantize the massless scalar field as a gauge theory by constructing a BRST-invariant quantum action. The corresponding gauge-breaking term is a non-local one of the form $S^{\rm GB}={1\over {2\alpha V}}\bigl(\int_{S^4} dV \phi \bigr)^2$ where $\alpha$ is a gauge parameter and $V$ is the volume of $S^4$. It allows us to correctly treat the zero mode problem. The quantum theory is invariant under SO(5), the symmetry group of $S^4$, and the associated two-point functions have no infrared divergence. The well-known infrared divergence which appears by taking the massless limit of the massive scalar field propagator is therefore a gauge artifact. By contrast, the massless scalar field theory on de Sitter space $dS^4$ - the lorentzian version of $S^4$ - is not invariant under the symmetry group of that spacetime SO(1,4). Here, the infrared divergence is real. Therefore, the massless scalar quantum field theories on $S^4$ and $dS^4$ cannot be linked by analytic continuation. In this case, because of zero modes, the euclidean approach to quantum field theory does not work. Similar considerations also apply to massive scalar field theories for exceptional values of the mass parameter (corresponding to the discrete series of the de Sitter group).Comment: This paper has been published under the title "Zero modes, euclideanization and quantization" [Phys. Rev. D46, 2553 (1992)

Comparison of two parallel/series flow turbofan propulsion concepts for supersonic V/STOL

The thrust, specific fuel consumption, and relative merits of the tandem fan and the dual reverse flow front fan propulsion systems for a supersonic V/STOL aircraft are discussed. Consideration is given to: fan pressure ratio, fan air burning, and variable core supercharging. The special propulsion system components required are described, namely: the deflecting front inlet/nozzle, the aft subsonic inlet, the reverse pitch fan, the variable core supercharger and the low pressure forward burner. The potential benefits for these unconventional systems are indicated

Charge ordering induces a smectic phase in oblate ionic liquid crystals

We report a computer simulation study of an electroneutral mixture of oppositely charged oblate ellipsoids of revolution with aspect ratio A = 1/3. In contrast to hard or soft repulsive ellipsoids, which are purely nematic, this system exhibits a smectic-A phase in which charges of equal sign are counterintuitively packed in layers perpendicular to the nematic director

Transport on complex networks: Flow, jamming and optimization

Many transport processes on networks depend crucially on the underlying network geometry, although the exact relationship between the structure of the network and the properties of transport processes remain elusive. In this paper we address this question by using numerical models in which both structure and dynamics are controlled systematically. We consider the traffic of information packets that include driving, searching and queuing. We present the results of extensive simulations on two classes of networks; a correlated cyclic scale-free network and an uncorrelated homogeneous weakly clustered network. By measuring different dynamical variables in the free flow regime we show how the global statistical properties of the transport are related to the temporal fluctuations at individual nodes (the traffic noise) and the links (the traffic flow). We then demonstrate that these two network classes appear as representative topologies for optimal traffic flow in the regimes of low density and high density traffic, respectively. We also determine statistical indicators of the pre-jamming regime on different network geometries and discuss the role of queuing and dynamical betweenness for the traffic congestion. The transition to the jammed traffic regime at a critical posting rate on different network topologies is studied as a phase transition with an appropriate order parameter. We also address several open theoretical problems related to the network dynamics